#------------------------------------------------------------------------------
#$Date: 2016-02-16 02:10:39 +0100 (Tue 16 de Feb de 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/14/7021476.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7021476
loop_
_publ_author_name
'Zhu, Yan'
'Luo, Feng'
'Luo, Ming-Biao'
'Feng, Xue-Feng'
'Batten, Stuart R.'
'Sun, Gong-Ming'
'Liu, Shu-Juan'
'Xu, Wen-Yuan'
_publ_section_title
;
 Solvent-induced reversible single-crystal-to-single-crystal
 transformations observed in lanthanide complexes.
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8545
_journal_page_last               8548
_journal_paper_doi               10.1039/c3dt50737h
_journal_volume                  42
_journal_year                    2013
_chemical_formula_sum            'C74 H63 Dy2 N4 O13.5'
_chemical_formula_weight         1549.28
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                99.4190(10)
_cell_angle_beta                 95.7620(10)
_cell_angle_gamma                107.4490(10)
_cell_formula_units_Z            2
_cell_length_a                   12.04920(10)
_cell_length_b                   12.33190(10)
_cell_length_c                   23.7314(4)
_cell_measurement_reflns_used    9883
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      24.50
_cell_measurement_theta_min      2.31
_cell_volume                     3276.50(7)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0372
_diffrn_reflns_av_unetI/netI     0.0326
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            46997
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         0.88
_exptl_absorpt_coefficient_mu    2.332
_exptl_absorpt_correction_T_max  0.8003
_exptl_absorpt_correction_T_min  0.7211
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.570
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1550
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.738
_refine_diff_density_min         -0.556
_refine_diff_density_rms         0.078
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     734
_refine_ls_number_reflns         11538
_refine_ls_number_restraints     23
_refine_ls_restrained_S_all      1.044
_refine_ls_R_factor_all          0.0399
_refine_ls_R_factor_gt           0.0310
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0363P)²+3.9765P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0749
_refine_ls_wR_factor_ref         0.0792
_reflns_number_gt                9688
_reflns_number_total             11538
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt50737h.txt
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_original_formula_sum        'C74 H63 Dy2 N4 O13.50'
_cod_database_code               7021476
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.4480(4) 0.9259(4) 0.59762(18) 0.0420(10) Uani 1 1 d .
C2 C 0.4207(3) 0.8824(3) 0.65167(12) 0.0541(12) Uani 1 1 d G
C3 C 0.5054(3) 0.9094(3) 0.70062(15) 0.0676(15) Uani 1 1 d G
C4 C 0.4750(5) 0.8686(4) 0.75004(13) 0.105(3) Uani 1 1 d G
H4 H 0.5316 0.8867 0.7828 0.126 Uiso 1 1 calc R
C5 C 0.3600(5) 0.8007(4) 0.75050(16) 0.124(3) Uani 1 1 d G
H5 H 0.3397 0.7733 0.7836 0.149 Uiso 1 1 calc R
C6 C 0.2753(4) 0.7736(4) 0.7016(2) 0.120(3) Uani 1 1 d G
H6 H 0.1984 0.7282 0.7019 0.144 Uiso 1 1 calc R
C7 C 0.3057(3) 0.8145(3) 0.65213(16) 0.0826(19) Uani 1 1 d G
H7 H 0.2491 0.7964 0.6194 0.099 Uiso 1 1 calc R
C8 C 0.6299(6) 0.9793(6) 0.7022(3) 0.097(2) Uani 1 1 d .
H8A H 0.6350 1.0583 0.7017 0.145 Uiso 1 1 calc R
H8B H 0.6586 0.9482 0.6690 0.145 Uiso 1 1 calc R
H8C H 0.6766 0.9765 0.7368 0.145 Uiso 1 1 calc R
C9 C 0.6712(4) 0.9142(4) 0.50587(19) 0.0408(10) Uani 1 1 d .
C10 C 0.7932(2) 0.9150(2) 0.52401(12) 0.0412(10) Uani 1 1 d G
C11 C 0.8470(3) 0.9715(3) 0.58015(12) 0.0574(12) Uani 1 1 d G
H11 H 0.8087 1.0113 0.6038 0.069 Uiso 1 1 calc R
C12 C 0.9578(3) 0.9685(3) 0.60098(13) 0.0842(19) Uani 1 1 d G
H12 H 0.9937 1.0063 0.6385 0.101 Uiso 1 1 calc R
C13 C 1.0149(2) 0.9089(3) 0.56566(19) 0.086(2) Uani 1 1 d G
H13 H 1.0890 0.9069 0.5796 0.103 Uiso 1 1 calc R
C14 C 0.9612(3) 0.8524(3) 0.50951(18) 0.0720(16) Uani 1 1 d G
H14 H 0.9994 0.8126 0.4859 0.086 Uiso 1 1 calc R
C15 C 0.8503(3) 0.8555(2) 0.48869(12) 0.0528(12) Uani 1 1 d G
C16 C 0.7983(5) 0.7989(4) 0.4256(2) 0.0714(16) Uani 1 1 d .
H16A H 0.8584 0.7819 0.4056 0.107 Uiso 1 1 calc R
H16B H 0.7683 0.8510 0.4076 0.107 Uiso 1 1 calc R
H16C H 0.7354 0.7282 0.4238 0.107 Uiso 1 1 calc R
C17 C 0.1761(4) 0.7374(4) 0.4010(2) 0.0490(11) Uani 1 1 d .
C18 C 0.0537(3) 0.6815(3) 0.36711(17) 0.0670(16) Uani 1 1 d G
C19 C 0.0260(4) 0.7230(4) 0.31835(18) 0.113(3) Uani 1 1 d G
H19 H 0.0817 0.7841 0.3082 0.136 Uiso 1 1 calc R
C20 C -0.0850(4) 0.6733(5) 0.28480(18) 0.150(4) Uani 1 1 d GU
H20 H -0.1035 0.7011 0.2522 0.180 Uiso 1 1 calc R
C21 C -0.1682(3) 0.5821(5) 0.3000(2) 0.151(4) Uani 1 1 d GU
H21 H -0.2425 0.5488 0.2776 0.181 Uiso 1 1 calc R
C22 C -0.1405(3) 0.5405(4) 0.3488(3) 0.134(4) Uani 1 1 d GU
H22 H -0.1962 0.4794 0.3589 0.161 Uiso 1 1 calc R
C23 C -0.0296(4) 0.5902(4) 0.3823(2) 0.096(2) Uani 1 1 d G
C24 C -0.0092(7) 0.5467(7) 0.4313(4) 0.116(3) Uani 1 1 d .
H24A H -0.0751 0.4799 0.4318 0.173 Uiso 1 1 calc R
H24B H 0.0007 0.6052 0.4652 0.173 Uiso 1 1 calc R
H24C H 0.0608 0.5249 0.4307 0.173 Uiso 1 1 calc R
N3 N 0.4606(2) 0.7036(2) 0.36834(10) 0.0459(9) Uani 1 1 d G
C25 C 0.4981(3) 0.7435(2) 0.31976(13) 0.0641(13) Uani 1 1 d G
H25 H 0.5017 0.8181 0.3156 0.077 Uiso 1 1 calc R
C26 C 0.5302(3) 0.6719(3) 0.27741(11) 0.0770(17) Uani 1 1 d G
H26 H 0.5552 0.6986 0.2449 0.092 Uiso 1 1 calc R
C27 C 0.5248(3) 0.5604(3) 0.28363(13) 0.0768(17) Uani 1 1 d G
H27 H 0.5462 0.5124 0.2553 0.092 Uiso 1 1 calc R
C28 C 0.4873(3) 0.52046(19) 0.33221(15) 0.0608(14) Uani 1 1 d GD
C29 C 0.4552(2) 0.5921(2) 0.37456(11) 0.0478(11) Uani 1 1 d G
C73 C 0.8509(8) 1.0063(8) 0.2403(5) 0.147(4) Uani 1 1 d .
H73A H 0.8172 1.0232 0.2052 0.177 Uiso 1 1 calc R
H73B H 0.8896 1.0792 0.2676 0.177 Uiso 1 1 calc R
C74 C 0.7536(8) 0.9283(8) 0.2662(4) 0.151(4) Uani 1 1 d .
H74A H 0.7126 0.8583 0.2382 0.227 Uiso 1 1 calc R
H74B H 0.6991 0.9684 0.2766 0.227 Uiso 1 1 calc R
H74C H 0.7878 0.9094 0.3000 0.227 Uiso 1 1 calc R
N4 N 0.3752(2) 0.62560(16) 0.46007(11) 0.0436(8) Uani 1 1 d G
C30 C 0.4123(2) 0.5525(2) 0.42079(11) 0.0457(10) Uani 1 1 d G
C31 C 0.3984(3) 0.4394(2) 0.42738(14) 0.0624(14) Uani 1 1 d GD
C34 C 0.3475(3) 0.39955(18) 0.47325(16) 0.0739(17) Uani 1 1 d G
H34 H 0.3382 0.3239 0.4777 0.089 Uiso 1 1 calc R
C35 C 0.3104(3) 0.4727(3) 0.51253(13) 0.0700(15) Uani 1 1 d G
H35 H 0.2763 0.4460 0.5432 0.084 Uiso 1 1 calc R
C36 C 0.3242(3) 0.5857(2) 0.50594(11) 0.0575(12) Uani 1 1 d G
H36 H 0.2994 0.6346 0.5322 0.069 Uiso 1 1 calc R
C32 C 0.4367(5) 0.3666(5) 0.3866(3) 0.086(2) Uani 1 1 d D
H32 H 0.4330 0.2924 0.3916 0.103 Uiso 1 1 calc R
C33 C 0.4796(5) 0.4065(4) 0.3392(3) 0.0812(19) Uani 1 1 d D
H33 H 0.5035 0.3585 0.3119 0.097 Uiso 1 1 calc R
C37 C 0.1682(4) 0.1769(4) 0.1779(2) 0.0497(11) Uani 1 1 d .
C38 C 0.1710(3) 0.2601(2) 0.23235(12) 0.0518(11) Uani 1 1 d G
C39 C 0.1383(3) 0.2132(2) 0.27996(15) 0.0713(15) Uani 1 1 d G
H39 H 0.1215 0.1340 0.2782 0.086 Uiso 1 1 calc R
C40 C 0.1309(4) 0.2849(4) 0.33017(12) 0.092(2) Uani 1 1 d G
H40 H 0.1091 0.2535 0.3620 0.110 Uiso 1 1 calc R
C41 C 0.1560(4) 0.4033(4) 0.33276(14) 0.091(2) Uani 1 1 d G
H41 H 0.1510 0.4513 0.3663 0.109 Uiso 1 1 calc R
C42 C 0.1886(3) 0.4502(2) 0.28515(18) 0.0828(19) Uani 1 1 d G
H42 H 0.2055 0.5295 0.2869 0.099 Uiso 1 1 calc R
C43 C 0.1961(3) 0.3786(3) 0.23494(14) 0.0616(13) Uani 1 1 d G
C44 C 0.2308(7) 0.4357(5) 0.1860(3) 0.099(2) Uani 1 1 d .
H44A H 0.2403 0.5169 0.1966 0.148 Uiso 1 1 calc R
H44B H 0.1706 0.4007 0.1527 0.148 Uiso 1 1 calc R
H44C H 0.3038 0.4264 0.1771 0.148 Uiso 1 1 calc R
C45 C -0.0924(4) 0.1508(4) 0.0441(2) 0.0434(10) Uani 1 1 d .
C46 C -0.0940(3) 0.2576(2) 0.08322(12) 0.0457(10) Uani 1 1 d G
C47 C -0.0824(3) 0.2601(3) 0.14233(13) 0.0638(14) Uani 1 1 d G
H47 H -0.0734 0.1966 0.1563 0.077 Uiso 1 1 calc R
C48 C -0.0843(3) 0.3576(4) 0.18055(11) 0.087(2) Uani 1 1 d G
H48 H -0.0765 0.3593 0.2201 0.105 Uiso 1 1 calc R
C49 C -0.0977(4) 0.4526(3) 0.15967(17) 0.101(2) Uani 1 1 d G
H49 H -0.0990 0.5179 0.1852 0.121 Uiso 1 1 calc R
C50 C -0.1093(4) 0.4501(2) 0.10056(19) 0.090(2) Uani 1 1 d G
H50 H -0.1183 0.5137 0.0866 0.108 Uiso 1 1 calc R
C51 C -0.1075(3) 0.3526(3) 0.06233(12) 0.0606(13) Uani 1 1 d G
C52 C -0.1222(7) 0.3549(5) -0.0015(3) 0.090(2) Uani 1 1 d .
H52A H -0.1983 0.3029 -0.0201 0.135 Uiso 1 1 calc R
H52B H -0.0621 0.3309 -0.0185 0.135 Uiso 1 1 calc R
H52C H -0.1154 0.4323 -0.0063 0.135 Uiso 1 1 calc R
C53 C 0.1357(4) 0.1769(4) -0.03993(19) 0.0432(10) Uani 1 1 d .
C54 C 0.2135(2) 0.2792(2) -0.06006(13) 0.0478(11) Uani 1 1 d G
C55 C 0.2196(3) 0.2671(3) -0.11884(12) 0.0615(13) Uani 1 1 d G
H55 H 0.1732 0.1993 -0.1444 0.074 Uiso 1 1 calc R
C56 C 0.2948(3) 0.3561(4) -0.13935(13) 0.0777(17) Uani 1 1 d G
H56 H 0.2989 0.3480 -0.1787 0.093 Uiso 1 1 calc R
C57 C 0.3641(3) 0.4574(3) -0.10108(19) 0.092(2) Uani 1 1 d G
H57 H 0.4144 0.5170 -0.1148 0.110 Uiso 1 1 calc R
C58 C 0.3580(3) 0.4696(2) -0.04230(18) 0.086(2) Uani 1 1 d G
H58 H 0.4044 0.5373 -0.0167 0.104 Uiso 1 1 calc R
C59 C 0.2828(3) 0.3805(3) -0.02179(12) 0.0646(14) Uani 1 1 d G
C60 C 0.2750(6) 0.4046(5) 0.0419(3) 0.094(2) Uani 1 1 d .
H60A H 0.3176 0.3640 0.0617 0.141 Uiso 1 1 calc R
H60B H 0.1939 0.3788 0.0470 0.141 Uiso 1 1 calc R
H60C H 0.3085 0.4865 0.0573 0.141 Uiso 1 1 calc R
N1 N 0.35756(18) 0.0726(2) 0.07485(13) 0.0490(9) Uani 1 1 d G
C61 C 0.4269(3) 0.1632(2) 0.05295(15) 0.0687(14) Uani 1 1 d G
H61 H 0.3950 0.2170 0.0408 0.082 Uiso 1 1 calc R
C62 C 0.5438(3) 0.1732(3) 0.04922(17) 0.089(2) Uani 1 1 d G
H62 H 0.5902 0.2338 0.0346 0.107 Uiso 1 1 calc R
C63 C 0.59142(19) 0.0928(4) 0.06741(17) 0.088(2) Uani 1 1 d G
H63 H 0.6697 0.0995 0.0649 0.106 Uiso 1 1 calc R
C64 C 0.5221(3) 0.0022(3) 0.08931(16) 0.0721(16) Uani 1 1 d GD
C65 C 0.4052(2) -0.0078(2) 0.09304(13) 0.0518(12) Uani 1 1 d G
C67 C 0.4963(6) -0.1715(7) 0.1280(4) 0.109(3) Uani 1 1 d D
H67 H 0.5252 -0.2291 0.1378 0.131 Uiso 1 1 calc R
C66 C 0.5665(6) -0.0830(7) 0.1058(3) 0.103(2) Uani 1 1 d D
H66 H 0.6433 -0.0798 0.1018 0.123 Uiso 1 1 calc R
N2 N 0.2232(2) -0.0935(2) 0.12366(12) 0.0498(9) Uani 1 1 d G
C68 C 0.3367(2) -0.0926(3) 0.11692(14) 0.0559(12) Uani 1 1 d G
C69 C 0.3802(3) -0.1749(3) 0.13603(18) 0.0806(18) Uani 1 1 d G
C70 C 0.3101(4) -0.2581(3) 0.1619(2) 0.108(3) Uani 1 1 d G
H70 H 0.3392 -0.3132 0.1747 0.130 Uiso 1 1 calc R
C71 C 0.1966(3) -0.2590(3) 0.16860(19) 0.102(2) Uani 1 1 d G
H71 H 0.1497 -0.3147 0.1859 0.123 Uiso 1 1 calc R
C72 C 0.1531(2) -0.1767(3) 0.14950(15) 0.0683(15) Uani 1 1 d G
H72 H 0.0772 -0.1773 0.1540 0.082 Uiso 1 1 calc R
Dy1 Dy 0.409524(16) 0.836245(14) 0.451870(8) 0.03448(6) Uani 1 1 d .
Dy2 Dy 0.133343(15) 0.031429(15) 0.070313(8) 0.03651(6) Uani 1 1 d .
O1 O 0.2547(3) 0.7801(3) 0.37243(14) 0.0582(8) Uani 1 1 d .
O2 O 0.2002(3) 0.7435(3) 0.45417(16) 0.0574(8) Uani 1 1 d .
O3 O 0.4173(3) 0.8503(2) 0.55134(12) 0.0479(7) Uani 1 1 d .
O4 O 0.6447(3) 1.0040(3) 0.52191(15) 0.0580(8) Uani 1 1 d .
O5 O 0.4945(3) 1.0330(2) 0.60154(13) 0.0485(7) Uani 1 1 d .
O6 O 0.5979(3) 0.8231(3) 0.47648(14) 0.0510(8) Uani 1 1 d .
O7 O 0.2288(3) 0.2088(3) 0.13977(15) 0.0617(9) Uani 1 1 d .
O8 O 0.1024(3) 0.0729(3) 0.17019(14) 0.0557(8) Uani 1 1 d .
O9 O -0.0170(3) 0.1047(3) 0.05836(17) 0.0645(9) Uani 1 1 d .
O10 O 0.1807(3) 0.1454(3) 0.00215(13) 0.0510(8) Uani 1 1 d .
O11 O 0.0334(2) 0.1294(2) -0.06718(13) 0.0490(7) Uani 1 1 d .
O12 O -0.1648(3) 0.1118(3) -0.00147(13) 0.0518(8) Uani 1 1 d .
O13 O 0.4814(15) 0.3355(13) 0.1716(8) 0.199(7) Uani 0.50 1 d P
O14 O 0.9335(6) 0.9489(5) 0.2278(3) 0.138(2) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 C1 O3 125.6(4) . .
O5 C1 C2 118.3(4) . .
O3 C1 C2 116.0(3) . .
C3 C2 C7 120.0 . .
C3 C2 C1 122.3(3) . .
C7 C2 C1 117.7(3) . .
C4 C3 C2 120.0 . .
C4 C3 C8 117.7(4) . .
C2 C3 C8 122.3(4) . .
C3 C4 C5 120.0 . .
C6 C5 C4 120.0 . .
C7 C6 C5 120.0 . .
C6 C7 C2 120.0 . .
O6 C9 O4 122.2(4) . .
O6 C9 C10 118.8(3) . .
O4 C9 C10 119.0(4) . .
C11 C10 C15 120.0 . .
C11 C10 C9 117.3(3) . .
C15 C10 C9 122.6(3) . .
C12 C11 C10 120.0 . .
C11 C12 C13 120.0 . .
C14 C13 C12 120.0 . .
C13 C14 C15 120.0 . .
C14 C15 C10 120.0 . .
C14 C15 C16 118.1(3) . .
C10 C15 C16 121.8(3) . .
O2 C17 O1 121.0(4) . .
O2 C17 C18 123.5(4) . .
O1 C17 C18 115.5(4) . .
O2 C17 Dy1 62.3(2) . .
O1 C17 Dy1 58.7(2) . .
C18 C17 Dy1 173.7(3) . .
C19 C18 C23 120.0 . .
C19 C18 C17 117.5(3) . .
C23 C18 C17 122.5(3) . .
C20 C19 C18 120.0 . .
C19 C20 C21 120.0 . .
C22 C21 C20 120.0 . .
C21 C22 C23 120.0 . .
C24 C23 C22 116.9(5) . .
C24 C23 C18 123.1(5) . .
C22 C23 C18 120.0 . .
C25 N3 C29 120.0 . .
C25 N3 Dy1 121.70(14) . .
C29 N3 Dy1 118.22(14) . .
C26 C25 N3 120.0 . .
C25 C26 C27 120.0 . .
C28 C27 C26 120.0 . .
C27 C28 C29 120.0 . .
C27 C28 C33 121.1(3) . .
C29 C28 C33 118.9(3) . .
C30 C29 C28 120.8(2) . .
C30 C29 N3 119.1(2) . .
C28 C29 N3 120.0 . .
O14 C73 C74 109.0(8) . .
C30 N4 C36 120.0 . .
C30 N4 Dy1 120.50(13) . .
C36 N4 Dy1 119.42(13) . .
C29 C30 C31 121.5(2) . .
C29 C30 N4 118.4(2) . .
C31 C30 N4 120.0 . .
C30 C31 C34 120.0 . .
C30 C31 C32 118.8(3) . .
C34 C31 C32 121.2(3) . .
C35 C34 C31 120.0 . .
C36 C35 C34 120.0 . .
C35 C36 N4 120.0 . .
C33 C32 C31 119.7(5) . .
C32 C33 C28 120.1(5) . .
O7 C37 O8 119.4(4) . .
O7 C37 C38 121.7(4) . .
O8 C37 C38 118.9(4) . .
O7 C37 Dy2 59.3(2) . .
O8 C37 Dy2 60.8(2) . .
C38 C37 Dy2 171.1(3) . .
C39 C38 C43 120.0 . .
C39 C38 C37 117.3(3) . .
C43 C38 C37 122.5(3) . .
C40 C39 C38 120.0 . .
C39 C40 C41 120.0 . .
C42 C41 C40 120.0 . .
C41 C42 C43 120.0 . .
C42 C43 C38 120.0 . .
C42 C43 C44 116.5(3) . .
C38 C43 C44 123.5(3) . .
O12 C45 O9 122.9(4) . .
O12 C45 C46 118.9(4) . .
O9 C45 C46 118.3(4) . .
C47 C46 C51 120.0 . .
C47 C46 C45 117.9(3) . .
C51 C46 C45 122.1(3) . .
C48 C47 C46 120.0 . .
C47 C48 C49 120.0 . .
C50 C49 C48 120.0 . .
C49 C50 C51 120.0 . .
C50 C51 C46 120.0 . .
C50 C51 C52 117.3(3) . .
C46 C51 C52 122.6(3) . .
O11 C53 O10 125.8(4) . .
O11 C53 C54 117.3(4) . .
O10 C53 C54 116.9(4) . .
C55 C54 C59 120.0 . .
C55 C54 C53 117.6(3) . .
C59 C54 C53 122.3(3) . .
C54 C55 C56 120.0 . .
C57 C56 C55 120.0 . .
C56 C57 C58 120.0 . .
C57 C58 C59 120.0 . .
C58 C59 C54 120.0 . .
C58 C59 C60 116.4(3) . .
C54 C59 C60 123.4(3) . .
C61 N1 C65 120.0 . .
C61 N1 Dy2 121.80(14) . .
C65 N1 Dy2 117.67(14) . .
C62 C61 N1 120.0 . .
C61 C62 C63 120.0 . .
C64 C63 C62 120.0 . .
C65 C64 C63 120.0 . .
C65 C64 C66 118.7(4) . .
C63 C64 C66 121.2(4) . .
C68 C65 C64 121.2(2) . .
C68 C65 N1 118.7(2) . .
C64 C65 N1 120.0 . .
C66 C67 C69 120.2(6) . .
C67 C66 C64 120.2(5) . .
C68 N2 C72 120.0 . .
C68 N2 Dy2 118.47(15) . .
C72 N2 Dy2 120.39(15) . .
C65 C68 C69 121.0(2) . .
C65 C68 N2 118.9(2) . .
C69 C68 N2 120.0 . .
C68 C69 C70 120.0 . .
C68 C69 C67 118.3(4) . .
C70 C69 C67 121.7(4) . .
C71 C70 C69 120.0 . .
C70 C71 C72 120.0 . .
C71 C72 N2 120.0 . .
O4 Dy1 O5 75.10(11) 2_676 2_676
O4 Dy1 O3 78.02(11) 2_676 .
O5 Dy1 O3 131.18(10) 2_676 .
O4 Dy1 O6 125.46(12) 2_676 .
O5 Dy1 O6 83.53(11) 2_676 .
O3 Dy1 O6 79.96(11) . .
O4 Dy1 O1 86.58(12) 2_676 .
O5 Dy1 O1 83.80(11) 2_676 .
O3 Dy1 O1 134.24(11) . .
O6 Dy1 O1 140.52(11) . .
O4 Dy1 O2 80.10(12) 2_676 .
O5 Dy1 O2 131.88(11) 2_676 .
O3 Dy1 O2 80.95(11) . .
O6 Dy1 O2 143.30(11) . .
O1 Dy1 O2 53.87(11) . .
O4 Dy1 N4 145.24(10) 2_676 .
O5 Dy1 N4 139.21(9) 2_676 .
O3 Dy1 N4 78.73(9) . .
O6 Dy1 N4 74.70(9) . .
O1 Dy1 N4 91.49(10) . .
O2 Dy1 N4 71.00(10) . .
O4 Dy1 N3 146.18(10) 2_676 .
O5 Dy1 N3 77.11(9) 2_676 .
O3 Dy1 N3 135.60(9) . .
O6 Dy1 N3 69.22(10) . .
O1 Dy1 N3 71.55(10) . .
O2 Dy1 N3 105.26(10) . .
N4 Dy1 N3 63.09(8) . .
O4 Dy1 C17 83.42(13) 2_676 .
O5 Dy1 C17 108.73(14) 2_676 .
O3 Dy1 C17 107.72(14) . .
O6 Dy1 C17 151.06(12) . .
O1 Dy1 C17 27.00(13) . .
O2 Dy1 C17 26.89(12) . .
N4 Dy1 C17 79.48(11) . .
N3 Dy1 C17 87.63(11) . .
O9 Dy2 O10 75.31(12) . .
O9 Dy2 O11 77.15(11) . 2
O10 Dy2 O11 129.49(10) . 2
O9 Dy2 O12 124.39(12) . 2
O10 Dy2 O12 83.86(11) . 2
O11 Dy2 O12 77.99(11) 2 2
O9 Dy2 O7 84.82(13) . .
O10 Dy2 O7 84.86(11) . .
O11 Dy2 O7 133.39(11) 2 .
O12 Dy2 O7 144.26(11) 2 .
O9 Dy2 O8 80.22(12) . .
O10 Dy2 O8 133.31(11) . .
O11 Dy2 O8 80.98(11) 2 .
O12 Dy2 O8 142.04(11) 2 .
O7 Dy2 O8 53.54(11) . .
O9 Dy2 N2 146.78(11) . .
O10 Dy2 N2 137.88(10) . .
O11 Dy2 N2 78.85(9) 2 .
O12 Dy2 N2 71.57(10) 2 .
O7 Dy2 N2 95.42(11) . .
O8 Dy2 N2 73.59(10) . .
O9 Dy2 N1 145.36(11) . .
O10 Dy2 N1 76.49(10) . .
O11 Dy2 N1 137.21(9) 2 .
O12 Dy2 N1 71.45(10) 2 .
O7 Dy2 N1 72.96(10) . .
O8 Dy2 N1 105.64(10) . .
N2 Dy2 N1 63.62(9) . .
O9 Dy2 C37 79.26(13) . .
O10 Dy2 C37 108.48(13) . .
O11 Dy2 C37 106.84(13) 2 .
O12 Dy2 C37 156.03(12) 2 .
O7 Dy2 C37 26.82(12) . .
O8 Dy2 C37 26.92(12) . .
N2 Dy2 C37 86.14(12) . .
N1 Dy2 C37 91.08(11) . .
C17 O1 Dy1 94.3(3) . .
C17 O2 Dy1 90.8(3) . .
C1 O3 Dy1 140.1(3) . .
C9 O4 Dy1 177.7(3) . 2_676
C1 O5 Dy1 140.3(3) . 2_676
C9 O6 Dy1 114.5(3) . .
C37 O7 Dy2 93.9(3) . .
C37 O8 Dy2 92.3(3) . .
C45 O9 Dy2 169.7(3) . .
C53 O10 Dy2 142.6(3) . .
C53 O11 Dy2 139.9(3) . 2
C45 O12 Dy2 117.2(3) . 2
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O5 1.254(5) .
C1 O3 1.261(5) .
C1 C2 1.499(5) .
C2 C3 1.3900 .
C2 C7 1.3900 .
C3 C4 1.3900 .
C3 C8 1.482(8) .
C4 C5 1.3900 .
C5 C6 1.3900 .
C6 C7 1.3900 .
C9 O6 1.247(5) .
C9 O4 1.254(5) .
C9 C10 1.486(5) .
C10 C11 1.3900 .
C10 C15 1.3900 .
C11 C12 1.3900 .
C12 C13 1.3900 .
C13 C14 1.3900 .
C14 C15 1.3900 .
C15 C16 1.527(6) .
C17 O2 1.250(6) .
C17 O1 1.258(6) .
C17 C18 1.506(5) .
C17 Dy1 2.763(4) .
C18 C19 1.3900 .
C18 C23 1.3900 .
C19 C20 1.3900 .
C20 C21 1.3900 .
C21 C22 1.3900 .
C22 C23 1.3900 .
C23 C24 1.387(9) .
N3 C25 1.3900 .
N3 C29 1.3900 .
N3 Dy1 2.6022(19) .
C25 C26 1.3900 .
C26 C27 1.3900 .
C27 C28 1.3900 .
C28 C29 1.3900 .
C28 C33 1.418(5) .
C29 C30 1.359(3) .
C73 O14 1.412(10) .
C73 C74 1.529(11) .
N4 C30 1.3900 .
N4 C36 1.3900 .
N4 Dy1 2.5483(18) .
C30 C31 1.3900 .
C31 C34 1.3900 .
C31 C32 1.418(6) .
C34 C35 1.3900 .
C35 C36 1.3900 .
C32 C33 1.385(7) .
C37 O7 1.259(5) .
C37 O8 1.261(5) .
C37 C38 1.503(5) .
C37 Dy2 2.784(5) .
C38 C39 1.3900 .
C38 C43 1.3900 .
C39 C40 1.3900 .
C40 C41 1.3900 .
C41 C42 1.3900 .
C42 C43 1.3900 .
C43 C44 1.485(7) .
C45 O12 1.244(5) .
C45 O9 1.256(5) .
C45 C46 1.489(5) .
C46 C47 1.3900 .
C46 C51 1.3900 .
C47 C48 1.3900 .
C48 C49 1.3900 .
C49 C50 1.3900 .
C50 C51 1.3900 .
C51 C52 1.513(7) .
C53 O11 1.251(5) .
C53 O10 1.259(5) .
C53 C54 1.509(5) .
C54 C55 1.3900 .
C54 C59 1.3900 .
C55 C56 1.3900 .
C56 C57 1.3900 .
C57 C58 1.3900 .
C58 C59 1.3900 .
C59 C60 1.509(7) .
N1 C61 1.3900 .
N1 C65 1.3900 .
N1 Dy2 2.582(2) .
C61 C62 1.3900 .
C62 C63 1.3900 .
C63 C64 1.3900 .
C64 C65 1.3900 .
C64 C66 1.405(6) .
C65 C68 1.366(4) .
C67 C66 1.382(7) .
C67 C69 1.420(7) .
N2 C68 1.3900 .
N2 C72 1.3900 .
N2 Dy2 2.552(2) .
C68 C69 1.3900 .
C69 C70 1.3900 .
C70 C71 1.3900 .
C71 C72 1.3900 .
Dy1 O4 2.270(3) 2_676
Dy1 O5 2.321(3) 2_676
Dy1 O3 2.329(3) .
Dy1 O6 2.346(3) .
Dy1 O1 2.368(3) .
Dy1 O2 2.447(3) .
Dy2 O9 2.267(3) .
Dy2 O10 2.317(3) .
Dy2 O11 2.346(3) 2
Dy2 O12 2.348(3) 2
Dy2 O7 2.399(3) .
Dy2 O8 2.432(3) .
O4 Dy1 2.270(3) 2_676
O5 Dy1 2.321(3) 2_676
O11 Dy2 2.346(3) 2
O12 Dy2 2.348(3) 2
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O5 C1 C2 C3 -53.6(5) . .
O3 C1 C2 C3 129.1(4) . .
O5 C1 C2 C7 125.3(4) . .
O3 C1 C2 C7 -52.0(4) . .
C7 C2 C3 C4 0.0 . .
C1 C2 C3 C4 178.8(3) . .
C7 C2 C3 C8 178.6(5) . .
C1 C2 C3 C8 -2.5(5) . .
C2 C3 C4 C5 0.0 . .
C8 C3 C4 C5 -178.7(4) . .
C3 C4 C5 C6 0.0 . .
C4 C5 C6 C7 0.0 . .
C5 C6 C7 C2 0.0 . .
C3 C2 C7 C6 0.0 . .
C1 C2 C7 C6 -178.9(3) . .
O6 C9 C10 C11 -138.5(3) . .
O4 C9 C10 C11 39.6(5) . .
O6 C9 C10 C15 37.0(5) . .
O4 C9 C10 C15 -144.9(3) . .
C15 C10 C11 C12 0.0 . .
C9 C10 C11 C12 175.6(3) . .
C10 C11 C12 C13 0.0 . .
C11 C12 C13 C14 0.0 . .
C12 C13 C14 C15 0.0 . .
C13 C14 C15 C10 0.0 . .
C13 C14 C15 C16 176.1(3) . .
C11 C10 C15 C14 0.0 . .
C9 C10 C15 C14 -175.3(3) . .
C11 C10 C15 C16 -176.0(4) . .
C9 C10 C15 C16 8.7(4) . .
O2 C17 C18 C19 151.3(4) . .
O1 C17 C18 C19 -27.7(5) . .
Dy1 C17 C18 C19 -50(3) . .
O2 C17 C18 C23 -29.9(5) . .
O1 C17 C18 C23 151.0(3) . .
Dy1 C17 C18 C23 129(3) . .
C23 C18 C19 C20 0.0 . .
C17 C18 C19 C20 178.8(3) . .
C18 C19 C20 C21 0.0 . .
C19 C20 C21 C22 0.0 . .
C20 C21 C22 C23 0.0 . .
C21 C22 C23 C24 178.2(5) . .
C21 C22 C23 C18 0.0 . .
C19 C18 C23 C24 -178.0(6) . .
C17 C18 C23 C24 3.2(6) . .
C19 C18 C23 C22 0.0 . .
C17 C18 C23 C22 -178.8(4) . .
C29 N3 C25 C26 0.0 . .
Dy1 N3 C25 C26 176.78(18) . .
N3 C25 C26 C27 0.0 . .
C25 C26 C27 C28 0.0 . .
C26 C27 C28 C29 0.0 . .
C26 C27 C28 C33 179.2(4) . .
C27 C28 C29 C30 176.4(3) . .
C33 C28 C29 C30 -2.8(4) . .
C27 C28 C29 N3 0.0 . .
C33 C28 C29 N3 -179.2(4) . .
C25 N3 C29 C30 -176.5(3) . .
Dy1 N3 C29 C30 6.6(3) . .
C25 N3 C29 C28 0.0 . .
Dy1 N3 C29 C28 -176.89(17) . .
C28 C29 C30 C31 -0.3(3) . .
N3 C29 C30 C31 176.16(17) . .
C28 C29 C30 N4 -176.33(17) . .
N3 C29 C30 N4 0.1(3) . .
C36 N4 C30 C29 176.1(3) . .
Dy1 N4 C30 C29 -7.1(3) . .
C36 N4 C30 C31 0.0 . .
Dy1 N4 C30 C31 176.77(18) . .
C29 C30 C31 C34 -176.0(3) . .
N4 C30 C31 C34 0.0 . .
C29 C30 C31 C32 3.8(4) . .
N4 C30 C31 C32 179.8(4) . .
C30 C31 C34 C35 0.0 . .
C32 C31 C34 C35 -179.8(4) . .
C31 C34 C35 C36 0.0 . .
C34 C35 C36 N4 0.0 . .
C30 N4 C36 C35 0.0 . .
Dy1 N4 C36 C35 -176.81(17) . .
C30 C31 C32 C33 -4.2(7) . .
C34 C31 C32 C33 175.6(4) . .
C31 C32 C33 C28 1.2(8) . .
C27 C28 C33 C32 -176.9(4) . .
C29 C28 C33 C32 2.3(7) . .
O7 C37 C38 C39 -157.2(4) . .
O8 C37 C38 C39 23.6(5) . .
Dy2 C37 C38 C39 109(2) . .
O7 C37 C38 C43 27.5(6) . .
O8 C37 C38 C43 -151.6(3) . .
Dy2 C37 C38 C43 -66(2) . .
C43 C38 C39 C40 0.0 . .
C37 C38 C39 C40 -175.4(3) . .
C38 C39 C40 C41 0.0 . .
C39 C40 C41 C42 0.0 . .
C40 C41 C42 C43 0.0 . .
C41 C42 C43 C38 0.0 . .
C41 C42 C43 C44 179.6(4) . .
C39 C38 C43 C42 0.0 . .
C37 C38 C43 C42 175.1(3) . .
C39 C38 C43 C44 -179.6(5) . .
C37 C38 C43 C44 -4.5(5) . .
O12 C45 C46 C47 137.0(3) . .
O9 C45 C46 C47 -43.6(5) . .
O12 C45 C46 C51 -42.5(5) . .
O9 C45 C46 C51 136.9(3) . .
C51 C46 C47 C48 0.0 . .
C45 C46 C47 C48 -179.5(3) . .
C46 C47 C48 C49 0.0 . .
C47 C48 C49 C50 0.0 . .
C48 C49 C50 C51 0.0 . .
C49 C50 C51 C46 0.0 . .
C49 C50 C51 C52 179.2(4) . .
C47 C46 C51 C50 0.0 . .
C45 C46 C51 C50 179.5(3) . .
C47 C46 C51 C52 -179.2(4) . .
C45 C46 C51 C52 0.4(5) . .
O11 C53 C54 C55 -48.5(4) . .
O10 C53 C54 C55 130.1(3) . .
O11 C53 C54 C59 135.2(3) . .
O10 C53 C54 C59 -46.2(5) . .
C59 C54 C55 C56 0.0 . .
C53 C54 C55 C56 -176.4(3) . .
C54 C55 C56 C57 0.0 . .
C55 C56 C57 C58 0.0 . .
C56 C57 C58 C59 0.0 . .
C57 C58 C59 C54 0.0 . .
C57 C58 C59 C60 -175.5(4) . .
C55 C54 C59 C58 0.0 . .
C53 C54 C59 C58 176.2(3) . .
C55 C54 C59 C60 175.2(4) . .
C53 C54 C59 C60 -8.6(5) . .
C65 N1 C61 C62 0.0 . .
Dy2 N1 C61 C62 -171.48(19) . .
N1 C61 C62 C63 0.0 . .
C61 C62 C63 C64 0.0 . .
C62 C63 C64 C65 0.0 . .
C62 C63 C64 C66 177.4(5) . .
C63 C64 C65 C68 -176.8(3) . .
C66 C64 C65 C68 5.7(5) . .
C63 C64 C65 N1 0.0 . .
C66 C64 C65 N1 -177.4(5) . .
C61 N1 C65 C68 176.9(3) . .
Dy2 N1 C65 C68 -11.3(3) . .
C61 N1 C65 C64 0.0 . .
Dy2 N1 C65 C64 171.83(19) . .
C69 C67 C66 C64 -2.0(12) . .
C65 C64 C66 C67 -3.2(9) . .
C63 C64 C66 C67 179.4(6) . .
C64 C65 C68 C69 -2.9(3) . .
N1 C65 C68 C69 -179.7(2) . .
C64 C65 C68 N2 175.1(2) . .
N1 C65 C68 N2 -1.7(4) . .
C72 N2 C68 C65 -178.0(3) . .
Dy2 N2 C68 C65 14.2(3) . .
C72 N2 C68 C69 0.0 . .
Dy2 N2 C68 C69 -167.8(2) . .
C65 C68 C69 C70 178.0(3) . .
N2 C68 C69 C70 0.0 . .
C65 C68 C69 C67 -2.4(5) . .
N2 C68 C69 C67 179.6(5) . .
C66 C67 C69 C68 4.8(10) . .
C66 C67 C69 C70 -175.6(6) . .
C68 C69 C70 C71 0.0 . .
C67 C69 C70 C71 -179.6(5) . .
C69 C70 C71 C72 0.0 . .
C70 C71 C72 N2 0.0 . .
C68 N2 C72 C71 0.0 . .
Dy2 N2 C72 C71 167.6(2) . .
C30 N4 Dy1 O4 161.7(2) . 2_676
C36 N4 Dy1 O4 -21.5(3) . 2_676
C30 N4 Dy1 O5 -6.6(2) . 2_676
C36 N4 Dy1 O5 170.16(17) . 2_676
C30 N4 Dy1 O3 -149.46(17) . .
C36 N4 Dy1 O3 27.34(16) . .
C30 N4 Dy1 O6 -66.91(16) . .
C36 N4 Dy1 O6 109.88(16) . .
C30 N4 Dy1 O1 75.59(17) . .
C36 N4 Dy1 O1 -107.61(16) . .
C30 N4 Dy1 O2 126.34(18) . .
C36 N4 Dy1 O2 -56.87(16) . .
C30 N4 Dy1 N3 7.20(15) . .
C36 N4 Dy1 N3 -176.01(17) . .
C30 N4 Dy1 C17 99.90(18) . .
C36 N4 Dy1 C17 -83.31(18) . .
C25 N3 Dy1 O4 22.3(3) . 2_676
C29 N3 Dy1 O4 -160.83(19) . 2_676
C25 N3 Dy1 O5 -13.01(16) . 2_676
C29 N3 Dy1 O5 163.82(17) . 2_676
C25 N3 Dy1 O3 -150.05(17) . .
C29 N3 Dy1 O3 26.8(2) . .
C25 N3 Dy1 O6 -100.91(17) . .
C29 N3 Dy1 O6 75.92(16) . .
C25 N3 Dy1 O1 74.67(17) . .
C29 N3 Dy1 O1 -108.50(18) . .
C25 N3 Dy1 O2 117.33(16) . .
C29 N3 Dy1 O2 -65.84(17) . .
C25 N3 Dy1 N4 176.21(17) . .
C29 N3 Dy1 N4 -6.96(14) . .
C25 N3 Dy1 C17 96.81(18) . .
C29 N3 Dy1 C17 -86.36(18) . .
O2 C17 Dy1 O4 -81.1(3) . 2_676
O1 C17 Dy1 O4 95.4(3) . 2_676
C18 C17 Dy1 O4 119(3) . 2_676
O2 C17 Dy1 O5 -152.9(2) . 2_676
O1 C17 Dy1 O5 23.6(3) . 2_676
C18 C17 Dy1 O5 47(3) . 2_676
O2 C17 Dy1 O3 -5.9(3) . .
O1 C17 Dy1 O3 170.5(2) . .
C18 C17 Dy1 O3 -166(3) . .
O2 C17 Dy1 O6 95.6(3) . .
O1 C17 Dy1 O6 -87.9(4) . .
C18 C17 Dy1 O6 -65(3) . .
O2 C17 Dy1 O1 -176.5(4) . .
C18 C17 Dy1 O1 23(3) . .
O1 C17 Dy1 O2 176.5(4) . .
C18 C17 Dy1 O2 -160(3) . .
O2 C17 Dy1 N4 68.5(3) . .
O1 C17 Dy1 N4 -115.0(3) . .
C18 C17 Dy1 N4 -92(3) . .
O2 C17 Dy1 N3 131.6(3) . .
O1 C17 Dy1 N3 -51.9(3) . .
C18 C17 Dy1 N3 -29(3) . .
C68 N2 Dy2 O9 -170.3(2) . .
C72 N2 Dy2 O9 21.9(3) . .
C68 N2 Dy2 O10 6.8(2) . .
C72 N2 Dy2 O10 -161.0(2) . .
C68 N2 Dy2 O11 145.27(19) . 2
C72 N2 Dy2 O11 -22.52(19) . 2
C68 N2 Dy2 O12 64.35(18) . 2
C72 N2 Dy2 O12 -103.4(2) . 2
C68 N2 Dy2 O7 -81.52(18) . .
C72 N2 Dy2 O7 110.69(19) . .
C68 N2 Dy2 O8 -130.96(19) . .
C72 N2 Dy2 O8 61.25(19) . .
C68 N2 Dy2 N1 -13.58(17) . .
C72 N2 Dy2 N1 178.6(2) . .
C68 N2 Dy2 C37 -106.71(19) . .
C72 N2 Dy2 C37 85.5(2) . .
C61 N1 Dy2 O9 -18.1(3) . .
C65 N1 Dy2 O9 170.3(2) . .
C61 N1 Dy2 O10 18.20(17) . .
C65 N1 Dy2 O10 -153.47(18) . .
C61 N1 Dy2 O11 152.90(18) . 2
C65 N1 Dy2 O11 -18.8(2) . 2
C61 N1 Dy2 O12 106.17(18) . 2
C65 N1 Dy2 O12 -65.50(17) . 2
C61 N1 Dy2 O7 -70.50(18) . .
C65 N1 Dy2 O7 117.83(19) . .
C61 N1 Dy2 O8 -113.50(17) . .
C65 N1 Dy2 O8 74.82(17) . .
C61 N1 Dy2 N2 -175.70(19) . .
C65 N1 Dy2 N2 12.62(16) . .
C61 N1 Dy2 C37 -90.55(19) . .
C65 N1 Dy2 C37 97.77(18) . .
O7 C37 Dy2 O9 -99.9(3) . .
O8 C37 Dy2 O9 89.5(3) . .
C38 C37 Dy2 O9 -1(2) . .
O7 C37 Dy2 O10 -29.5(3) . .
O8 C37 Dy2 O10 159.9(3) . .
C38 C37 Dy2 O10 69(2) . .
O7 C37 Dy2 O11 -172.8(3) . 2
O8 C37 Dy2 O11 16.6(3) . 2
C38 C37 Dy2 O11 -74(2) . 2
O7 C37 Dy2 O12 88.8(4) . 2
O8 C37 Dy2 O12 -81.8(4) . 2
C38 C37 Dy2 O12 -172.5(19) . 2
O8 C37 Dy2 O7 -170.6(5) . .
C38 C37 Dy2 O7 99(2) . .
O7 C37 Dy2 O8 170.6(5) . .
C38 C37 Dy2 O8 -91(2) . .
O7 C37 Dy2 N2 110.1(3) . .
O8 C37 Dy2 N2 -60.5(3) . .
C38 C37 Dy2 N2 -151(2) . .
O7 C37 Dy2 N1 46.6(3) . .
O8 C37 Dy2 N1 -124.0(3) . .
C38 C37 Dy2 N1 145(2) . .
O2 C17 O1 Dy1 3.7(5) . .
C18 C17 O1 Dy1 -177.3(3) . .
O4 Dy1 O1 C17 -82.2(3) 2_676 .
O5 Dy1 O1 C17 -157.6(3) 2_676 .
O3 Dy1 O1 C17 -12.6(3) . .
O6 Dy1 O1 C17 130.5(3) . .
O2 Dy1 O1 C17 -2.0(2) . .
N4 Dy1 O1 C17 63.0(3) . .
N3 Dy1 O1 C17 124.0(3) . .
O1 C17 O2 Dy1 -3.5(4) . .
C18 C17 O2 Dy1 177.5(4) . .
O4 Dy1 O2 C17 95.0(3) 2_676 .
O5 Dy1 O2 C17 35.5(3) 2_676 .
O3 Dy1 O2 C17 174.3(3) . .
O6 Dy1 O2 C17 -126.3(3) . .
O1 Dy1 O2 C17 2.0(2) . .
N4 Dy1 O2 C17 -104.6(3) . .
N3 Dy1 O2 C17 -50.8(3) . .
O5 C1 O3 Dy1 -2.9(8) . .
C2 C1 O3 Dy1 174.2(3) . .
O4 Dy1 O3 C1 -39.4(4) 2_676 .
O5 Dy1 O3 C1 18.3(5) 2_676 .
O6 Dy1 O3 C1 90.4(4) . .
O1 Dy1 O3 C1 -112.4(4) . .
O2 Dy1 O3 C1 -121.1(4) . .
N4 Dy1 O3 C1 166.6(5) . .
N3 Dy1 O3 C1 136.3(4) . .
C17 Dy1 O3 C1 -118.4(4) . .
O6 C9 O4 Dy1 -20(8) . 2_676
C10 C9 O4 Dy1 162(8) . 2_676
O3 C1 O5 Dy1 -17.0(8) . 2_676
C2 C1 O5 Dy1 166.0(3) . 2_676
O4 C9 O6 Dy1 1.7(5) . .
C10 C9 O6 Dy1 179.7(2) . .
O4 Dy1 O6 C9 -0.8(3) 2_676 .
O5 Dy1 O6 C9 65.7(3) 2_676 .
O3 Dy1 O6 C9 -68.2(3) . .
O1 Dy1 O6 C9 137.7(3) . .
O2 Dy1 O6 C9 -127.9(3) . .
N4 Dy1 O6 C9 -149.1(3) . .
N3 Dy1 O6 C9 144.3(3) . .
C17 Dy1 O6 C9 -176.8(3) . .
O8 C37 O7 Dy2 9.4(5) . .
C38 C37 O7 Dy2 -169.7(3) . .
O9 Dy2 O7 C37 76.4(3) . .
O10 Dy2 O7 C37 152.0(3) . .
O11 Dy2 O7 C37 9.5(3) 2 .
O12 Dy2 O7 C37 -135.9(3) 2 .
O8 Dy2 O7 C37 -5.3(3) . .
N2 Dy2 O7 C37 -70.3(3) . .
N1 Dy2 O7 C37 -130.5(3) . .
O7 C37 O8 Dy2 -9.3(4) . .
C38 C37 O8 Dy2 169.9(3) . .
O9 Dy2 O8 C37 -85.5(3) . .
O10 Dy2 O8 C37 -26.6(3) . .
O11 Dy2 O8 C37 -163.9(3) 2 .
O12 Dy2 O8 C37 139.2(3) 2 .
O7 Dy2 O8 C37 5.3(3) . .
N2 Dy2 O8 C37 115.2(3) . .
N1 Dy2 O8 C37 59.5(3) . .
O12 C45 O9 Dy2 67(2) . .
C46 C45 O9 Dy2 -112.4(18) . .
O10 Dy2 O9 C45 11.5(18) . .
O11 Dy2 O9 C45 -125.7(19) 2 .
O12 Dy2 O9 C45 -60.2(19) 2 .
O7 Dy2 O9 C45 97.6(19) . .
O8 Dy2 O9 C45 151.4(19) . .
N2 Dy2 O9 C45 -170.5(17) . .
N1 Dy2 O9 C45 48.0(19) . .
C37 Dy2 O9 C45 124.1(19) . .
O11 C53 O10 Dy2 -15.6(8) . .
C54 C53 O10 Dy2 165.9(3) . .
O9 Dy2 O10 C53 -35.6(5) . .
O11 Dy2 O10 C53 23.5(5) 2 .
O12 Dy2 O10 C53 92.4(5) 2 .
O7 Dy2 O10 C53 -121.6(5) . .
O8 Dy2 O10 C53 -96.3(5) . .
N2 Dy2 O10 C53 146.0(4) . .
N1 Dy2 O10 C53 164.8(5) . .
C37 Dy2 O10 C53 -108.7(5) . .
O10 C53 O11 Dy2 -3.6(7) . 2
C54 C53 O11 Dy2 174.9(3) . 2
O9 C45 O12 Dy2 -11.9(6) . 2
C46 C45 O12 Dy2 167.4(2) . 2
