#------------------------------------------------------------------------------
#$Date: 2016-03-25 14:34:24 +0100 (Fri 25 de Mar de 2016) $
#$Revision: 179925 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/20/7022012.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7022012
loop_
_publ_author_name
'Chauhan, Rohit Singh'
'Kedarnath, G.'
'Wadawale, Amey'
'Slawin, Alexandra M. Z.'
'Jain, Vimal K.'
_publ_section_title
;
 Reactivity of 2-chalcogenopyridines with palladium-phosphine complexes:
 isolation of different complexes depending on the nature of chalcogen
 atom and phosphine ligand.
;
_journal_issue                   1
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              259
_journal_page_last               269
_journal_paper_doi               10.1039/c2dt30535f
_journal_volume                  42
_journal_year                    2013
_chemical_formula_moiety         'C66 H64 N2 P4 Pd2 Te2,Cl2,3(H2 O)'
_chemical_formula_sum            'C66 H70 Cl2 N2 O3 P4 Pd2 Te2'
_chemical_formula_weight         1602.02
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                114.084(2)
_cell_angle_beta                 99.385(4)
_cell_angle_gamma                111.686(5)
_cell_formula_units_Z            1
_cell_length_a                   11.934(6)
_cell_length_b                   13.083(7)
_cell_length_c                   13.460(7)
_cell_measurement_reflns_used    4185
_cell_measurement_temperature    93(2)
_cell_measurement_theta_max      27.6
_cell_measurement_theta_min      1.9
_cell_volume                     1656.3(15)
_computing_cell_refinement       'CrystalClear (Rigaku Corp., 2004)'
_computing_data_collection       'CrystalClear (Rigaku Corp., 2004)'
_computing_data_reduction        'CrystalClear (Rigaku Corp., 2004)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      93(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  CCD
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  confocal
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1030
_diffrn_reflns_av_sigmaI/netI    0.1567
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            16863
_diffrn_reflns_theta_full        25.30
_diffrn_reflns_theta_max         25.39
_diffrn_reflns_theta_min         1.85
_exptl_absorpt_coefficient_mu    1.629
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.745
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.606
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             794
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.324
_refine_diff_density_min         -1.163
_refine_diff_density_rms         0.183
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.100
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     365
_refine_ls_number_reflns         6038
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.100
_refine_ls_R_factor_all          0.0945
_refine_ls_R_factor_gt           0.0657
_refine_ls_shift/su_max          0.013
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0495P)²+2.9187P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1577
_refine_ls_wR_factor_ref         0.1727
_reflns_number_gt                4541
_reflns_number_total             6038
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt30535f.txt
_cod_data_source_block           5.3H2O.
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7022012
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pd1 Pd 0.01969(6) 0.09638(5) -0.08143(5) 0.02541(19) Uani 1 1 d .
Te1 Te 0.05103(5) 0.14119(4) 0.13296(4) 0.02939(18) Uani 1 1 d .
C1 C 0.2460(8) 0.1710(8) 0.1777(7) 0.0382(19) Uani 1 1 d .
N2 N 0.2525(7) 0.0640(7) 0.1138(6) 0.0451(18) Uani 1 1 d .
C3 C 0.3695(10) 0.0708(9) 0.1395(9) 0.054(3) Uani 1 1 d .
H3A H 0.3766 -0.0026 0.0938 0.065 Uiso 1 1 calc R
C4 C 0.4811(10) 0.1802(9) 0.2299(9) 0.054(2) Uani 1 1 d .
H4A H 0.5623 0.1816 0.2468 0.065 Uiso 1 1 calc R
C5 C 0.4690(9) 0.2868(9) 0.2940(8) 0.048(2) Uani 1 1 d .
H5A H 0.5434 0.3620 0.3569 0.058 Uiso 1 1 calc R
C6 C 0.3528(8) 0.2874(8) 0.2694(7) 0.0368(19) Uani 1 1 d .
C7 C 0.3413(9) 0.4025(8) 0.3366(7) 0.046(2) Uani 1 1 d .
H7A H 0.4265 0.4727 0.3957 0.069 Uiso 1 1 calc R
H7B H 0.2802 0.3836 0.3753 0.069 Uiso 1 1 calc R
H7C H 0.3095 0.4274 0.2832 0.069 Uiso 1 1 calc R
P1 P 0.0639(2) 0.30152(19) -0.02403(16) 0.0283(5) Uani 1 1 d .
C8 C 0.0321(8) 0.3348(7) -0.1405(7) 0.0337(19) Uani 1 1 d .
H8A H -0.0629 0.2901 -0.1832 0.040 Uiso 1 1 calc R
H8B H 0.0635 0.4278 -0.1055 0.040 Uiso 1 1 calc R
C9 C 0.0958(8) 0.2942(7) -0.2273(6) 0.0317(18) Uani 1 1 d .
H9A H 0.1846 0.3165 -0.1839 0.038 Uiso 1 1 calc R
H9B H 0.1034 0.3426 -0.2686 0.038 Uiso 1 1 calc R
C10 C 0.0204(8) 0.1508(7) -0.3179(7) 0.0338(19) Uani 1 1 d .
H10A H 0.0532 0.1351 -0.3827 0.041 Uiso 1 1 calc R
H10B H -0.0720 0.1263 -0.3510 0.041 Uiso 1 1 calc R
P2 P 0.0300(2) 0.04679(19) -0.26282(16) 0.0279(5) Uani 1 1 d .
C11 C 0.2317(7) 0.4191(7) 0.0637(6) 0.0278(17) Uani 1 1 d .
C12 C 0.3286(8) 0.3825(7) 0.0557(7) 0.0351(19) Uani 1 1 d .
H12A H 0.3045 0.2944 0.0116 0.042 Uiso 1 1 calc R
C13 C 0.4587(8) 0.4736(8) 0.1116(7) 0.040(2) Uani 1 1 d .
H13A H 0.5233 0.4480 0.1045 0.048 Uiso 1 1 calc R
C14 C 0.4944(8) 0.6004(8) 0.1769(7) 0.042(2) Uani 1 1 d .
H14A H 0.5837 0.6627 0.2148 0.050 Uiso 1 1 calc R
C15 C 0.4012(8) 0.6383(8) 0.1881(7) 0.042(2) Uani 1 1 d .
H15A H 0.4271 0.7263 0.2359 0.050 Uiso 1 1 calc R
C16 C 0.2706(8) 0.5496(8) 0.1305(7) 0.0367(19) Uani 1 1 d .
H16A H 0.2073 0.5771 0.1361 0.044 Uiso 1 1 calc R
C17 C -0.0359(8) 0.3409(7) 0.0577(6) 0.0308(18) Uani 1 1 d .
C18 C -0.1674(8) 0.2902(7) -0.0036(7) 0.0356(19) Uani 1 1 d .
H18A H -0.2016 0.2431 -0.0868 0.043 Uiso 1 1 calc R
C19 C -0.2476(9) 0.3086(8) 0.0569(8) 0.047(2) Uani 1 1 d .
H19A H -0.3370 0.2752 0.0152 0.057 Uiso 1 1 calc R
C20 C -0.1976(10) 0.3765(9) 0.1794(9) 0.050(3) Uani 1 1 d .
H20A H -0.2537 0.3874 0.2206 0.060 Uiso 1 1 calc R
C21 C -0.0696(9) 0.4270(8) 0.2398(7) 0.043(2) Uani 1 1 d .
H21A H -0.0361 0.4744 0.3230 0.051 Uiso 1 1 calc R
C22 C 0.0122(9) 0.4096(8) 0.1805(7) 0.039(2) Uani 1 1 d .
H22A H 0.1015 0.4444 0.2233 0.047 Uiso 1 1 calc R
C23 C -0.0901(8) -0.1120(7) -0.3839(6) 0.0289(17) Uani 1 1 d .
C24 C -0.0580(8) -0.2109(7) -0.4305(6) 0.0308(17) Uani 1 1 d .
H24A H 0.0272 -0.1963 -0.3983 0.037 Uiso 1 1 calc R
C25 C -0.1540(8) -0.3308(8) -0.5247(7) 0.0364(19) Uani 1 1 d .
H25A H -0.1339 -0.3983 -0.5563 0.044 Uiso 1 1 calc R
C26 C -0.2757(9) -0.3520(8) -0.5716(7) 0.042(2) Uani 1 1 d .
H26A H -0.3382 -0.4326 -0.6383 0.050 Uiso 1 1 calc R
C27 C -0.3102(9) -0.2565(8) -0.5230(7) 0.044(2) Uani 1 1 d .
H27A H -0.3966 -0.2732 -0.5539 0.053 Uiso 1 1 calc R
C28 C -0.2169(8) -0.1378(7) -0.4297(6) 0.0314(17) Uani 1 1 d .
H28A H -0.2397 -0.0726 -0.3961 0.038 Uiso 1 1 calc R
C29 C 0.1861(8) 0.0507(7) -0.2551(7) 0.0318(18) Uani 1 1 d .
C30 C 0.2590(7) 0.0536(7) -0.1615(6) 0.0303(17) Uani 1 1 d .
H30A H 0.2301 0.0580 -0.0989 0.036 Uiso 1 1 calc R
C31 C 0.3743(8) 0.0501(7) -0.1594(7) 0.0379(19) Uani 1 1 d .
H31A H 0.4256 0.0548 -0.0941 0.045 Uiso 1 1 calc R
C32 C 0.4148(9) 0.0398(7) -0.2527(8) 0.043(2) Uani 1 1 d .
H32A H 0.4918 0.0341 -0.2525 0.051 Uiso 1 1 calc R
C33 C 0.3425(8) 0.0380(8) -0.3465(7) 0.042(2) Uani 1 1 d .
H33A H 0.3722 0.0339 -0.4086 0.051 Uiso 1 1 calc R
C34 C 0.2268(8) 0.0422(7) -0.3497(6) 0.0343(19) Uani 1 1 d .
H34A H 0.1765 0.0394 -0.4142 0.041 Uiso 1 1 calc R
Cl1 Cl 0.6922(2) 0.1116(2) 0.66995(18) 0.0465(6) Uani 1 1 d .
O1 O 0.5522(7) 0.1800(7) 0.5047(6) 0.072(2) Uani 1 1 d .
O2 O 0.2361(16) 0.6608(15) 0.5223(14) 0.086(5) Uiso 0.50 1 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Te Te -0.5308 1.6751 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
P1 Pd1 P2 95.32(7) .
P1 Pd1 Te1 91.20(5) .
P2 Pd1 Te1 167.01(6) .
P1 Pd1 Te1 172.79(5) 2
P2 Pd1 Te1 90.54(5) 2
Te1 Pd1 Te1 83.89(2) 2
C1 Te1 Pd1 95.5(2) .
C1 Te1 Pd1 85.7(2) 2
Pd1 Te1 Pd1 96.11(2) 2
N2 C1 C6 124.5(8) .
N2 C1 Te1 112.5(6) .
C6 C1 Te1 122.9(6) .
C3 N2 C1 117.1(8) .
N2 C3 C4 123.2(9) .
N2 C3 H3A 118.4 .
C4 C3 H3A 118.4 .
C5 C4 C3 117.5(9) .
C5 C4 H4A 121.3 .
C3 C4 H4A 121.3 .
C6 C5 C4 122.1(9) .
C6 C5 H5A 118.9 .
C4 C5 H5A 118.9 .
C5 C6 C1 115.6(8) .
C5 C6 C7 121.8(8) .
C1 C6 C7 122.6(8) .
C6 C7 H7A 109.5 .
C6 C7 H7B 109.5 .
H7A C7 H7B 109.5 .
C6 C7 H7C 109.5 .
H7A C7 H7C 109.5 .
H7B C7 H7C 109.5 .
C11 P1 C8 102.2(3) .
C11 P1 C17 109.0(3) .
C8 P1 C17 105.6(3) .
C11 P1 Pd1 114.1(2) .
C8 P1 Pd1 116.0(2) .
C17 P1 Pd1 109.3(2) .
C9 C8 P1 113.7(5) .
C9 C8 H8A 108.8 .
P1 C8 H8A 108.8 .
C9 C8 H8B 108.8 .
P1 C8 H8B 108.8 .
H8A C8 H8B 107.7 .
C8 C9 C10 113.0(6) .
C8 C9 H9A 109.0 .
C10 C9 H9A 109.0 .
C8 C9 H9B 109.0 .
C10 C9 H9B 109.0 .
H9A C9 H9B 107.8 .
C9 C10 P2 115.3(6) .
C9 C10 H10A 108.4 .
P2 C10 H10A 108.4 .
C9 C10 H10B 108.4 .
P2 C10 H10B 108.4 .
H10A C10 H10B 107.5 .
C23 P2 C10 103.1(4) .
C23 P2 C29 104.8(3) .
C10 P2 C29 106.9(4) .
C23 P2 Pd1 116.5(2) .
C10 P2 Pd1 117.8(2) .
C29 P2 Pd1 106.7(3) .
C16 C11 C12 118.3(7) .
C16 C11 P1 121.6(6) .
C12 C11 P1 119.7(5) .
C13 C12 C11 120.6(7) .
C13 C12 H12A 119.7 .
C11 C12 H12A 119.7 .
C14 C13 C12 120.1(7) .
C14 C13 H13A 120.0 .
C12 C13 H13A 120.0 .
C13 C14 C15 120.3(8) .
C13 C14 H14A 119.8 .
C15 C14 H14A 119.8 .
C14 C15 C16 120.7(8) .
C14 C15 H15A 119.6 .
C16 C15 H15A 119.6 .
C15 C16 C11 119.9(7) .
C15 C16 H16A 120.0 .
C11 C16 H16A 120.0 .
C18 C17 C22 119.0(7) .
C18 C17 P1 118.7(6) .
C22 C17 P1 122.0(6) .
C19 C18 C17 119.8(8) .
C19 C18 H18A 120.1 .
C17 C18 H18A 120.1 .
C18 C19 C20 120.1(9) .
C18 C19 H19A 120.0 .
C20 C19 H19A 120.0 .
C21 C20 C19 120.5(7) .
C21 C20 H20A 119.8 .
C19 C20 H20A 119.8 .
C20 C21 C22 120.1(8) .
C20 C21 H21A 119.9 .
C22 C21 H21A 119.9 .
C21 C22 C17 120.4(9) .
C21 C22 H22A 119.8 .
C17 C22 H22A 119.8 .
C28 C23 C24 119.3(7) .
C28 C23 P2 119.4(5) .
C24 C23 P2 121.3(6) .
C25 C24 C23 118.8(8) .
C25 C24 H24A 120.6 .
C23 C24 H24A 120.6 .
C26 C25 C24 120.9(8) .
C26 C25 H25A 119.6 .
C24 C25 H25A 119.6 .
C25 C26 C27 120.9(8) .
C25 C26 H26A 119.6 .
C27 C26 H26A 119.6 .
C28 C27 C26 119.0(9) .
C28 C27 H27A 120.5 .
C26 C27 H27A 120.5 .
C27 C28 C23 121.1(7) .
C27 C28 H28A 119.5 .
C23 C28 H28A 119.5 .
C30 C29 C34 120.7(7) .
C30 C29 P2 120.4(5) .
C34 C29 P2 118.8(6) .
C29 C30 C31 119.9(7) .
C29 C30 H30A 120.0 .
C31 C30 H30A 120.0 .
C30 C31 C32 120.1(8) .
C30 C31 H31A 120.0 .
C32 C31 H31A 120.0 .
C31 C32 C33 120.2(8) .
C31 C32 H32A 119.9 .
C33 C32 H32A 119.9 .
C34 C33 C32 120.5(7) .
C34 C33 H33A 119.7 .
C32 C33 H33A 119.7 .
C33 C34 C29 118.6(8) .
C33 C34 H34A 120.7 .
C29 C34 H34A 120.7 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pd1 P1 2.282(2) .
Pd1 P2 2.294(2) .
Pd1 Te1 2.6299(15) .
Pd1 Te1 2.6391(17) 2
Te1 C1 2.148(8) .
Te1 Pd1 2.6391(17) 2
C1 N2 1.350(10) .
C1 C6 1.409(11) .
N2 C3 1.343(11) .
C3 C4 1.394(13) .
C3 H3A 0.9500 .
C4 C5 1.385(12) .
C4 H4A 0.9500 .
C5 C6 1.376(11) .
C5 H5A 0.9500 .
C6 C7 1.478(10) .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C7 H7C 0.9800 .
P1 C11 1.800(8) .
P1 C8 1.811(8) .
P1 C17 1.820(6) .
C8 C9 1.519(8) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C9 C10 1.531(10) .
C9 H9A 0.9900 .
C9 H9B 0.9900 .
C10 P2 1.824(7) .
C10 H10A 0.9900 .
C10 H10B 0.9900 .
P2 C23 1.817(8) .
P2 C29 1.830(8) .
C11 C16 1.401(10) .
C11 C12 1.411(10) .
C12 C13 1.384(11) .
C12 H12A 0.9500 .
C13 C14 1.368(11) .
C13 H13A 0.9500 .
C14 C15 1.381(11) .
C14 H14A 0.9500 .
C15 C16 1.382(11) .
C15 H15A 0.9500 .
C16 H16A 0.9500 .
C17 C18 1.395(11) .
C17 C22 1.402(10) .
C18 C19 1.379(10) .
C18 H18A 0.9500 .
C19 C20 1.399(13) .
C19 H19A 0.9500 .
C20 C21 1.357(13) .
C20 H20A 0.9500 .
C21 C22 1.382(10) .
C21 H21A 0.9500 .
C22 H22A 0.9500 .
C23 C28 1.390(11) .
C23 C24 1.414(9) .
C24 C25 1.398(10) .
C24 H24A 0.9500 .
C25 C26 1.358(12) .
C25 H25A 0.9500 .
C26 C27 1.400(11) .
C26 H26A 0.9500 .
C27 C28 1.380(11) .
C27 H27A 0.9500 .
C28 H28A 0.9500 .
C29 C30 1.387(11) .
C29 C34 1.413(9) .
C30 C31 1.390(10) .
C30 H30A 0.9500 .
C31 C32 1.392(10) .
C31 H31A 0.9500 .
C32 C33 1.394(12) .
C32 H32A 0.9500 .
C33 C34 1.395(10) .
C33 H33A 0.9500 .
C34 H34A 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
P1 Pd1 Te1 C1 -99.0(2) . .
P2 Pd1 Te1 C1 21.2(3) . .
Te1 Pd1 Te1 C1 86.3(2) 2 .
P1 Pd1 Te1 Pd1 174.71(6) . 2
P2 Pd1 Te1 Pd1 -65.1(3) . 2
Te1 Pd1 Te1 Pd1 0.0 2 2
Pd1 Te1 C1 N2 -65.4(6) . .
Pd1 Te1 C1 N2 30.3(6) 2 .
Pd1 Te1 C1 C6 118.7(6) . .
Pd1 Te1 C1 C6 -145.6(7) 2 .
C6 C1 N2 C3 -0.7(13) . .
Te1 C1 N2 C3 -176.5(7) . .
C1 N2 C3 C4 2.0(14) . .
N2 C3 C4 C5 -1.1(15) . .
C3 C4 C5 C6 -1.2(14) . .
C4 C5 C6 C1 2.3(13) . .
C4 C5 C6 C7 -178.6(8) . .
N2 C1 C6 C5 -1.4(12) . .
Te1 C1 C6 C5 174.0(6) . .
N2 C1 C6 C7 179.5(8) . .
Te1 C1 C6 C7 -5.0(11) . .
P2 Pd1 P1 C11 -96.9(2) . .
Te1 Pd1 P1 C11 71.9(2) . .
Te1 Pd1 P1 C11 118.8(5) 2 .
P2 Pd1 P1 C8 21.5(3) . .
Te1 Pd1 P1 C8 -169.7(3) . .
Te1 Pd1 P1 C8 -122.8(5) 2 .
P2 Pd1 P1 C17 140.8(3) . .
Te1 Pd1 P1 C17 -50.4(3) . .
Te1 Pd1 P1 C17 -3.5(6) 2 .
C11 P1 C8 C9 72.3(6) . .
C17 P1 C8 C9 -173.7(5) . .
Pd1 P1 C8 C9 -52.5(6) . .
P1 C8 C9 C10 80.0(8) . .
C8 C9 C10 P2 -73.0(8) . .
C9 C10 P2 C23 170.5(5) . .
C9 C10 P2 C29 -79.4(6) . .
C9 C10 P2 Pd1 40.7(7) . .
P1 Pd1 P2 C23 -140.1(3) . .
Te1 Pd1 P2 C23 100.1(4) . .
Te1 Pd1 P2 C23 35.7(3) 2 .
P1 Pd1 P2 C10 -16.7(3) . .
Te1 Pd1 P2 C10 -136.5(4) . .
Te1 Pd1 P2 C10 159.1(3) 2 .
P1 Pd1 P2 C29 103.4(3) . .
Te1 Pd1 P2 C29 -16.4(4) . .
Te1 Pd1 P2 C29 -80.8(3) 2 .
C8 P1 C11 C16 70.3(6) . .
C17 P1 C11 C16 -41.1(7) . .
Pd1 P1 C11 C16 -163.6(5) . .
C8 P1 C11 C12 -102.4(6) . .
C17 P1 C11 C12 146.2(6) . .
Pd1 P1 C11 C12 23.7(6) . .
C16 C11 C12 C13 -0.7(11) . .
P1 C11 C12 C13 172.3(6) . .
C11 C12 C13 C14 1.1(12) . .
C12 C13 C14 C15 0.3(13) . .
C13 C14 C15 C16 -2.2(13) . .
C14 C15 C16 C11 2.7(12) . .
C12 C11 C16 C15 -1.2(11) . .
P1 C11 C16 C15 -174.0(6) . .
C11 P1 C17 C18 159.7(6) . .
C8 P1 C17 C18 50.5(7) . .
Pd1 P1 C17 C18 -75.0(6) . .
C11 P1 C17 C22 -26.9(7) . .
C8 P1 C17 C22 -136.0(7) . .
Pd1 P1 C17 C22 98.5(6) . .
C22 C17 C18 C19 0.3(11) . .
P1 C17 C18 C19 173.9(6) . .
C17 C18 C19 C20 -0.8(12) . .
C18 C19 C20 C21 1.3(14) . .
C19 C20 C21 C22 -1.2(13) . .
C20 C21 C22 C17 0.7(12) . .
C18 C17 C22 C21 -0.2(12) . .
P1 C17 C22 C21 -173.6(6) . .
C10 P2 C23 C28 -54.6(6) . .
C29 P2 C23 C28 -166.3(6) . .
Pd1 P2 C23 C28 76.0(6) . .
C10 P2 C23 C24 127.1(6) . .
C29 P2 C23 C24 15.4(7) . .
Pd1 P2 C23 C24 -102.2(6) . .
C28 C23 C24 C25 2.6(10) . .
P2 C23 C24 C25 -179.1(6) . .
C23 C24 C25 C26 0.5(11) . .
C24 C25 C26 C27 -3.4(12) . .
C25 C26 C27 C28 3.1(12) . .
C26 C27 C28 C23 0.1(12) . .
C24 C23 C28 C27 -2.9(11) . .
P2 C23 C28 C27 178.8(6) . .
C23 P2 C29 C30 -110.8(6) . .
C10 P2 C29 C30 140.2(6) . .
Pd1 P2 C29 C30 13.3(7) . .
C23 P2 C29 C34 65.1(7) . .
C10 P2 C29 C34 -43.8(7) . .
Pd1 P2 C29 C34 -170.8(5) . .
C34 C29 C30 C31 1.0(12) . .
P2 C29 C30 C31 176.8(6) . .
C29 C30 C31 C32 -1.9(11) . .
C30 C31 C32 C33 2.5(12) . .
C31 C32 C33 C34 -2.1(13) . .
C32 C33 C34 C29 1.2(12) . .
C30 C29 C34 C33 -0.6(12) . .
P2 C29 C34 C33 -176.5(6) . .
