Information card for entry 7022043

Structure parameters

• Formula: C35 H61 N2 O Rh
• Calculated formula: C35 H61 N2 O Rh
• SMILES: [Rh]123(O)(=C4N(C=CN4C4CCCCCCCCCCC4)C4CCCCCCCCCCC4)[CH]4=[CH]1CC[CH]2=[CH]3CC4
• Title of publication: Well-defined NHC-rhodium hydroxide complexes as alkene hydrosilylation and dehydrogenative silylation catalysts.
• Authors of publication: Truscott, Byron J.; Slawin, Alexandra M. Z.; Nolan, Steven P.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2013
• Journal volume: 42
• Journal issue: 1
• Pages of publication: 270 - 276
• a: 29.075 ± 0.007 Å
• b: 15.582 ± 0.003 Å
• c: 14.62 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 6624 ± 2 ų
• Cell temperature: 93 ± 2 K
• Ambient diffraction temperature: 93 ± 2 K
• Number of distinct elements: 5
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.1134
• Residual factor for significantly intense reflections: 0.1109
• Weighted residual factors for significantly intense reflections: 0.2333
• Weighted residual factors for all reflections included in the refinement: 0.2345
• Goodness-of-fit parameter for all reflections included in the refinement: 1.331
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No