Synthesis and structures of calcium and strontium 2,4-di-tert-butylphenolates and their reactivity towards the amine co-initiated ring-opening polymerisation of rac-lactide.
Authors of publication
Clark, Lawrence; Deacon, Glen B.; Forsyth, Craig M.; Junk, Peter C.; Mountford, Philip; Townley, Josh P.; Wang, Jun
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2013
Journal volume
42
Journal issue
25
Pages of publication
9294 - 9312
a
21.738 ± 0.003 Å
b
21.738 ± 0.003 Å
c
40.897 ± 0.008 Å
α
90°
β
90°
γ
120°
Cell volume
16736 ± 5 Å3
Cell temperature
173 ± 2 K
Ambient diffraction temperature
173 ± 2 K
Number of distinct elements
4
Space group number
167
Hermann-Mauguin space group symbol
R -3 c :H
Hall space group symbol
-R 3 2"c
Residual factor for all reflections
0.0539
Residual factor for significantly intense reflections
0.0521
Weighted residual factors for significantly intense reflections
0.1238
Weighted residual factors for all reflections included in the refinement
0.125
Goodness-of-fit parameter for all reflections included in the refinement
