#------------------------------------------------------------------------------
#$Date: 2016-03-25 14:42:56 +0100 (Fri 25 de Mar de 2016) $
#$Revision: 179932 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/27/7022778.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7022778
loop_
_publ_author_name
'Feng, Xun'
'Feng, Yu-Quan'
'Liu, Lang'
'Wang, Li-Ya'
'Song, Hong-Liang'
'Ng, Seik-Weng'
_publ_section_title
;
 A series of Zn-4f heterometallic coordination polymers and a zinc complex
 containing a flexible mixed donor dicarboxylate ligand.
;
_journal_issue                   21
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7741
_journal_page_last               7754
_journal_paper_doi               10.1039/c3dt33002h
_journal_volume                  42
_journal_year                    2013
_chemical_formula_sum            'C26 H16 Cl Eu N2 O11 Zn'
_chemical_formula_weight         785.19
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                107.155(2)
_cell_angle_beta                 104.306(2)
_cell_angle_gamma                92.829(2)
_cell_formula_units_Z            2
_cell_length_a                   8.3739(14)
_cell_length_b                   12.876(2)
_cell_length_c                   13.413(2)
_cell_measurement_reflns_used    5986
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.17
_cell_measurement_theta_min      2.62
_cell_volume                     1327.3(4)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0213
_diffrn_reflns_av_sigmaI/netI    0.0314
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            9854
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         2.53
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    3.412
_exptl_absorpt_correction_T_max  0.6113
_exptl_absorpt_correction_T_min  0.4825
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.965
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             768
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.16
_refine_diff_density_max         0.909
_refine_diff_density_min         -0.966
_refine_diff_density_rms         0.090
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.021
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     379
_refine_ls_number_reflns         4886
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.021
_refine_ls_R_factor_all          0.0266
_refine_ls_R_factor_gt           0.0239
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0370P)²+0.2727P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0598
_refine_ls_wR_factor_ref         0.0616
_reflns_number_gt                4531
_reflns_number_total             4886
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt33002h.txt
_cod_data_source_block           a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7022778
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.247014(17) 0.488500(12) 0.490733(11) 0.01735(6) Uani 1 1 d .
Zn1 Zn 0.32510(5) 0.22161(3) 0.66278(3) 0.02577(10) Uani 1 1 d .
Cl1 Cl 0.22989(12) 0.13020(8) 0.75746(8) 0.0387(2) Uani 1 1 d .
O1 O -0.2870(3) 0.31952(18) 0.38636(18) 0.0266(5) Uani 1 1 d .
O2 O -0.0251(2) 0.39283(16) 0.44545(17) 0.0212(5) Uani 1 1 d .
O3 O 0.3017(3) 0.30369(18) 0.47665(18) 0.0258(5) Uani 1 1 d .
O4 O 0.1550(3) 0.18568(19) 0.52224(18) 0.0299(5) Uani 1 1 d .
O5 O 0.2687(3) 0.0658(2) 0.2941(2) 0.0373(6) Uani 1 1 d .
O6 O 0.7725(3) 0.61816(19) 0.70244(18) 0.0276(5) Uani 1 1 d .
O7 O 0.5318(2) 0.51709(18) 0.60767(16) 0.0214(5) Uani 1 1 d .
O8 O 0.2209(2) 0.45751(17) 0.65621(16) 0.0221(5) Uani 1 1 d .
O9 O 0.4039(3) 0.37671(18) 0.75064(18) 0.0300(5) Uani 1 1 d .
O10 O 0.2607(3) 0.5466(2) 0.9180(2) 0.0384(6) Uani 1 1 d .
O11 O 0.1250(3) 0.5877(2) 0.36863(18) 0.0313(5) Uani 1 1 d .
H1W H 0.0221 0.5925 0.3606 0.047 Uiso 1 1 d R
H2W H 0.1556 0.5835 0.3118 0.047 Uiso 1 1 d R
N1 N 0.4710(4) -0.1514(2) 0.3668(2) 0.0320(7) Uani 1 1 d .
N2 N 0.1428(4) 0.6035(3) 1.1696(2) 0.0384(8) Uani 1 1 d .
C1 C -0.0901(4) 0.2168(3) 0.3109(3) 0.0226(7) Uani 1 1 d .
C2 C 0.0665(4) 0.1832(2) 0.3415(2) 0.0223(7) Uani 1 1 d .
C3 C 0.1096(4) 0.0972(3) 0.2667(3) 0.0267(7) Uani 1 1 d .
C4 C 0.0068(5) 0.0485(3) 0.1639(3) 0.0376(9) Uani 1 1 d .
H4 H 0.0404 -0.0072 0.1144 0.045 Uiso 1 1 calc R
C5 C -0.1471(5) 0.0827(3) 0.1341(3) 0.0379(9) Uani 1 1 d .
H5 H -0.2171 0.0503 0.0645 0.045 Uiso 1 1 calc R
C6 C -0.1959(4) 0.1656(3) 0.2089(3) 0.0304(8) Uani 1 1 d .
H6 H -0.3008 0.1868 0.1900 0.036 Uiso 1 1 calc R
C7 C -0.1383(4) 0.3138(2) 0.3851(2) 0.0199(6) Uani 1 1 d .
C8 C 0.1836(4) 0.2299(3) 0.4548(3) 0.0231(7) Uani 1 1 d .
C9 C 0.4295(4) -0.0690(3) 0.3266(3) 0.0321(8) Uani 1 1 d .
H9 H 0.4979 -0.0444 0.2908 0.039 Uiso 1 1 calc R
C10 C 0.2889(4) -0.0199(3) 0.3369(3) 0.0266(7) Uani 1 1 d .
C11 C 0.1859(4) -0.0545(3) 0.3903(3) 0.0338(8) Uani 1 1 d .
H11 H 0.0897 -0.0232 0.3969 0.041 Uiso 1 1 calc R
C12 C 0.2307(5) -0.1373(3) 0.4334(3) 0.0408(9) Uani 1 1 d .
H12 H 0.1650 -0.1622 0.4705 0.049 Uiso 1 1 calc R
C13 C 0.3744(5) -0.1831(3) 0.4213(3) 0.0387(9) Uani 1 1 d .
H13 H 0.4045 -0.2377 0.4521 0.046 Uiso 1 1 calc R
C14 C 0.5598(4) 0.6299(3) 0.7923(2) 0.0204(6) Uani 1 1 d .
C15 C 0.4324(4) 0.5695(3) 0.8101(2) 0.0197(6) Uani 1 1 d .
C16 C 0.3849(4) 0.6120(3) 0.9051(3) 0.0264(7) Uani 1 1 d .
C17 C 0.4606(4) 0.7117(3) 0.9816(3) 0.0326(8) Uani 1 1 d .
H17 H 0.4295 0.7381 1.0455 0.039 Uiso 1 1 calc R
C18 C 0.5841(4) 0.7714(3) 0.9606(3) 0.0338(8) Uani 1 1 d .
H18 H 0.6331 0.8395 1.0102 0.041 Uiso 1 1 calc R
C19 C 0.6355(4) 0.7320(3) 0.8681(3) 0.0283(7) Uani 1 1 d .
H19 H 0.7196 0.7725 0.8559 0.034 Uiso 1 1 calc R
C20 C 0.6259(4) 0.5876(3) 0.6968(2) 0.0207(6) Uani 1 1 d .
C21 C 0.3455(4) 0.4591(3) 0.7317(2) 0.0207(6) Uani 1 1 d .
C22 C 0.2143(4) 0.5640(3) 1.0903(3) 0.0335(8) Uani 1 1 d .
H22 H 0.2883 0.5134 1.0972 0.040 Uiso 1 1 calc R
C23 C 0.1828(4) 0.5955(3) 0.9983(3) 0.0302(8) Uani 1 1 d .
C24 C 0.0736(5) 0.6683(3) 0.9840(3) 0.0441(10) Uani 1 1 d .
H24 H 0.0491 0.6883 0.9212 0.053 Uiso 1 1 calc R
C25 C 0.0002(5) 0.7114(4) 1.0671(3) 0.0465(10) Uani 1 1 d .
H25 H -0.0722 0.7633 1.0623 0.056 Uiso 1 1 calc R
C26 C 0.0364(5) 0.6762(3) 1.1563(3) 0.0406(9) Uani 1 1 d .
H26 H -0.0154 0.7043 1.2105 0.049 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 Eu1 O3 77.61(7) . .
O2 Eu1 O8 74.59(7) . .
O3 Eu1 O8 73.20(7) . .
O2 Eu1 O11 86.15(7) . .
O3 Eu1 O11 137.21(8) . .
O8 Eu1 O11 139.59(7) . .
O2 Eu1 O7 144.89(7) . .
O3 Eu1 O7 77.80(7) . .
O8 Eu1 O7 74.56(7) . .
O11 Eu1 O7 128.68(8) . .
O2 Eu1 O1 114.87(7) . 2_566
O3 Eu1 O1 145.52(8) . 2_566
O8 Eu1 O1 79.37(7) . 2_566
O11 Eu1 O1 77.14(8) . 2_566
O7 Eu1 O1 75.03(7) . 2_566
O2 Eu1 O6 82.28(7) . 2_666
O3 Eu1 O6 69.80(8) . 2_666
O8 Eu1 O6 139.67(7) . 2_666
O11 Eu1 O6 68.93(8) . 2_666
O7 Eu1 O6 111.84(7) . 2_666
O1 Eu1 O6 140.88(8) 2_566 2_666
O2 Eu1 O7 134.20(7) . 2_666
O3 Eu1 O7 82.48(7) . 2_666
O8 Eu1 O7 136.95(7) . 2_666
O11 Eu1 O7 81.19(7) . 2_666
O7 Eu1 O7 65.78(8) . 2_666
O1 Eu1 O7 104.86(7) 2_566 2_666
O6 Eu1 O7 52.08(7) 2_666 2_666
O2 Eu1 O2 64.49(8) . 2_566
O3 Eu1 O2 134.44(7) . 2_566
O8 Eu1 O2 73.09(7) . 2_566
O11 Eu1 O2 66.55(7) . 2_566
O7 Eu1 O2 120.60(7) . 2_566
O1 Eu1 O2 50.99(7) 2_566 2_566
O6 Eu1 O2 125.10(7) 2_666 2_566
O7 Eu1 O2 142.45(7) 2_666 2_566
O2 Eu1 C20 107.56(8) . 2_666
O3 Eu1 C20 73.72(8) . 2_666
O8 Eu1 C20 145.45(8) . 2_666
O11 Eu1 C20 74.03(8) . 2_666
O7 Eu1 C20 88.99(8) . 2_666
O1 Eu1 C20 126.06(8) 2_566 2_666
O6 Eu1 C20 25.42(7) 2_666 2_666
O7 Eu1 C20 26.68(7) 2_666 2_666
O2 Eu1 C20 140.04(7) 2_566 2_666
O2 Eu1 C7 89.84(8) . 2_566
O3 Eu1 C7 146.53(8) . 2_566
O8 Eu1 C7 73.57(8) . 2_566
O11 Eu1 C7 71.15(8) . 2_566
O7 Eu1 C7 97.15(8) . 2_566
O1 Eu1 C7 25.18(7) 2_566 2_566
O6 Eu1 C7 139.70(8) 2_666 2_566
O7 Eu1 C7 126.04(8) 2_666 2_566
O2 Eu1 C7 25.86(7) 2_566 2_566
C20 Eu1 C7 139.69(8) 2_666 2_566
O2 Eu1 C8 57.88(7) . .
O3 Eu1 C8 19.73(7) . .
O8 Eu1 C8 69.63(8) . .
O11 Eu1 C8 128.10(8) . .
O7 Eu1 C8 95.56(7) . .
O1 Eu1 C8 148.99(8) 2_566 .
O6 Eu1 C8 70.12(8) 2_666 .
O7 Eu1 C8 97.55(7) 2_666 .
O2 Eu1 C8 117.12(7) 2_566 .
C20 Eu1 C8 82.34(8) 2_666 .
C7 Eu1 C8 135.99(8) 2_566 .
O4 Zn1 O9 119.78(9) . .
O4 Zn1 N1 107.22(11) . 2_656
O9 Zn1 N1 106.84(11) . 2_656
O4 Zn1 Cl1 106.19(7) . .
O9 Zn1 Cl1 111.07(8) . .
N1 Zn1 Cl1 104.71(9) 2_656 .
C7 O1 Eu1 97.38(18) . 2_566
C7 O2 Eu1 151.0(2) . .
C7 O2 Eu1 90.97(17) . 2_566
Eu1 O2 Eu1 115.51(8) . 2_566
C8 O3 Eu1 119.77(18) . .
C8 O4 Zn1 117.0(2) . .
C10 O5 C3 119.0(3) . .
C20 O6 Eu1 94.94(18) . 2_666
C20 O7 Eu1 138.93(19) . .
C20 O7 Eu1 93.08(17) . 2_666
Eu1 O7 Eu1 114.22(8) . 2_666
C21 O8 Eu1 122.09(18) . .
C21 O9 Zn1 126.4(2) . .
C16 O10 C23 117.0(3) . .
Eu1 O11 H1W 115.5 . .
Eu1 O11 H2W 121.3 . .
H1W O11 H2W 113.5 . .
C13 N1 C9 118.1(3) . .
C13 N1 Zn1 124.4(2) . 2_656
C9 N1 Zn1 117.5(2) . 2_656
C22 N2 C26 116.9(3) . .
C6 C1 C2 120.3(3) . .
C6 C1 C7 119.3(3) . .
C2 C1 C7 120.3(3) . .
C3 C2 C1 118.0(3) . .
C3 C2 C8 118.8(3) . .
C1 C2 C8 123.0(3) . .
C4 C3 C2 121.8(3) . .
C4 C3 O5 119.2(3) . .
C2 C3 O5 118.8(3) . .
C3 C4 C5 119.8(3) . .
C3 C4 H4 120.1 . .
C5 C4 H4 120.1 . .
C4 C5 C6 119.5(3) . .
C4 C5 H5 120.2 . .
C6 C5 H5 120.2 . .
C1 C6 C5 120.5(3) . .
C1 C6 H6 119.7 . .
C5 C6 H6 119.7 . .
O1 C7 O2 120.4(3) . .
O1 C7 C1 121.2(3) . .
O2 C7 C1 118.4(3) . .
O1 C7 Eu1 57.45(15) . 2_566
O2 C7 Eu1 63.16(15) . 2_566
C1 C7 Eu1 173.6(2) . 2_566
O3 C8 O4 123.9(3) . .
O3 C8 C2 121.5(3) . .
O4 C8 C2 114.6(3) . .
O3 C8 Eu1 40.50(14) . .
O4 C8 Eu1 126.7(2) . .
C2 C8 Eu1 104.07(18) . .
N1 C9 C10 122.1(3) . .
N1 C9 H9 119.0 . .
C10 C9 H9 119.0 . .
C9 C10 O5 114.3(3) . .
C9 C10 C11 120.0(3) . .
O5 C10 C11 125.6(3) . .
C12 C11 C10 117.7(3) . .
C12 C11 H11 121.1 . .
C10 C11 H11 121.1 . .
C11 C12 C13 119.8(4) . .
C11 C12 H12 120.1 . .
C13 C12 H12 120.1 . .
N1 C13 C12 122.2(4) . .
N1 C13 H13 118.9 . .
C12 C13 H13 118.9 . .
C15 C14 C19 120.3(3) . .
C15 C14 C20 122.1(3) . .
C19 C14 C20 117.5(3) . .
C16 C15 C14 118.6(3) . .
C16 C15 C21 118.5(3) . .
C14 C15 C21 123.0(3) . .
O10 C16 C15 115.2(3) . .
O10 C16 C17 123.0(3) . .
C15 C16 C17 121.8(3) . .
C18 C17 C16 118.5(3) . .
C18 C17 H17 120.8 . .
C16 C17 H17 120.8 . .
C19 C18 C17 121.5(3) . .
C19 C18 H18 119.2 . .
C17 C18 H18 119.2 . .
C18 C19 C14 119.3(3) . .
C18 C19 H19 120.3 . .
C14 C19 H19 120.3 . .
O6 C20 O7 119.8(3) . .
O6 C20 C14 120.0(3) . .
O7 C20 C14 120.1(3) . .
O6 C20 Eu1 59.64(16) . 2_666
O7 C20 Eu1 60.24(15) . 2_666
C14 C20 Eu1 178.2(2) . 2_666
O8 C21 O9 126.0(3) . .
O8 C21 C15 118.1(3) . .
O9 C21 C15 115.9(3) . .
N2 C22 C23 122.4(3) . .
N2 C22 H22 118.8 . .
C23 C22 H22 118.8 . .
C24 C23 C22 120.8(3) . .
C24 C23 O10 121.2(3) . .
C22 C23 O10 118.0(3) . .
C23 C24 C25 117.3(4) . .
C23 C24 H24 121.4 . .
C25 C24 H24 121.4 . .
C26 C25 C24 118.9(4) . .
C26 C25 H25 120.5 . .
C24 C25 H25 120.5 . .
N2 C26 C25 123.6(4) . .
N2 C26 H26 118.2 . .
C25 C26 H26 118.2 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O2 2.383(2) .
Eu1 O3 2.407(2) .
Eu1 O8 2.426(2) .
Eu1 O11 2.428(2) .
Eu1 O7 2.451(2) .
Eu1 O1 2.486(2) 2_566
Eu1 O6 2.509(2) 2_666
Eu1 O7 2.518(2) 2_666
Eu1 O2 2.611(2) 2_566
Eu1 C20 2.897(3) 2_666
Eu1 C7 2.925(3) 2_566
Eu1 C8 3.217(3) .
Zn1 O4 1.972(2) .
Zn1 O9 1.977(2) .
Zn1 N1 2.041(3) 2_656
Zn1 Cl1 2.2189(10) .
O1 C7 1.255(4) .
O1 Eu1 2.486(2) 2_566
O2 C7 1.276(4) .
O2 Eu1 2.611(2) 2_566
O3 C8 1.251(4) .
O4 C8 1.264(4) .
O5 C10 1.384(4) .
O5 C3 1.404(4) .
O6 C20 1.248(4) .
O6 Eu1 2.509(2) 2_666
O7 C20 1.303(4) .
O7 Eu1 2.518(2) 2_666
O8 C21 1.256(4) .
O9 C21 1.257(4) .
O10 C16 1.382(4) .
O10 C23 1.403(4) .
O11 H1W 0.8500 .
O11 H2W 0.8500 .
N1 C13 1.338(5) .
N1 C9 1.349(4) .
N1 Zn1 2.041(3) 2_656
N2 C22 1.332(4) .
N2 C26 1.344(5) .
C1 C6 1.379(4) .
C1 C2 1.404(4) .
C1 C7 1.494(4) .
C2 C3 1.387(4) .
C2 C8 1.517(4) .
C3 C4 1.373(5) .
C4 C5 1.385(5) .
C4 H4 0.9300 .
C5 C6 1.388(5) .
C5 H5 0.9300 .
C6 H6 0.9300 .
C7 Eu1 2.925(3) 2_566
C9 C10 1.382(5) .
C9 H9 0.9300 .
C10 C11 1.383(5) .
C11 C12 1.381(5) .
C11 H11 0.9300 .
C12 C13 1.391(5) .
C12 H12 0.9300 .
C13 H13 0.9300 .
C14 C15 1.398(4) .
C14 C19 1.405(4) .
C14 C20 1.487(4) .
C15 C16 1.393(4) .
C15 C21 1.515(4) .
C16 C17 1.388(5) .
C17 C18 1.390(5) .
C17 H17 0.9300 .
C18 C19 1.378(5) .
C18 H18 0.9300 .
C19 H19 0.9300 .
C20 Eu1 2.897(3) 2_666
C22 C23 1.379(5) .
C22 H22 0.9300 .
C23 C24 1.362(5) .
C24 C25 1.392(5) .
C24 H24 0.9300 .
C25 C26 1.372(5) .
C25 H25 0.9300 .
C26 H26 0.9300 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O11 H1W O8 0.85 2.04 2.843(3) 157.2 2_566
O11 H2W N2 0.85 1.98 2.776(4) 156.1 1_554
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O3 Eu1 O2 C7 -51.9(4) . .
O8 Eu1 O2 C7 -127.6(4) . .
O11 Eu1 O2 C7 88.2(4) . .
O7 Eu1 O2 C7 -98.4(4) . .
O1 Eu1 O2 C7 162.2(4) 2_566 .
O6 Eu1 O2 C7 19.0(4) 2_666 .
O7 Eu1 O2 C7 14.5(4) 2_666 .
O2 Eu1 O2 C7 154.1(4) 2_566 .
C20 Eu1 O2 C7 16.3(4) 2_666 .
C7 Eu1 O2 C7 159.4(4) 2_566 .
C8 Eu1 O2 C7 -52.3(4) . .
O3 Eu1 O2 Eu1 154.04(10) . 2_566
O8 Eu1 O2 Eu1 78.30(9) . 2_566
O11 Eu1 O2 Eu1 -65.81(9) . 2_566
O7 Eu1 O2 Eu1 107.57(12) . 2_566
O1 Eu1 O2 Eu1 8.10(11) 2_566 2_566
O6 Eu1 O2 Eu1 -135.04(10) 2_666 2_566
O7 Eu1 O2 Eu1 -139.57(8) 2_666 2_566
O2 Eu1 O2 Eu1 0.0 2_566 2_566
C20 Eu1 O2 Eu1 -137.71(9) 2_666 2_566
C7 Eu1 O2 Eu1 5.31(10) 2_566 2_566
C8 Eu1 O2 Eu1 153.62(12) . 2_566
O2 Eu1 O3 C8 -1.0(2) . .
O8 Eu1 O3 C8 76.4(2) . .
O11 Eu1 O3 C8 -71.3(3) . .
O7 Eu1 O3 C8 153.7(2) . .
O1 Eu1 O3 C8 115.1(2) 2_566 .
O6 Eu1 O3 C8 -87.3(2) 2_666 .
O7 Eu1 O3 C8 -139.5(2) 2_666 .
O2 Eu1 O3 C8 32.6(3) 2_566 .
C20 Eu1 O3 C8 -113.7(2) 2_666 .
C7 Eu1 O3 C8 69.2(3) 2_566 .
O9 Zn1 O4 C8 52.9(3) . .
N1 Zn1 O4 C8 -68.9(2) 2_656 .
Cl1 Zn1 O4 C8 179.6(2) . .
O2 Eu1 O7 C20 -99.1(3) . .
O3 Eu1 O7 C20 -145.6(3) . .
O8 Eu1 O7 C20 -69.9(3) . .
O11 Eu1 O7 C20 72.4(3) . .
O1 Eu1 O7 C20 13.0(3) 2_566 .
O6 Eu1 O7 C20 152.3(3) 2_666 .
O7 Eu1 O7 C20 127.3(3) 2_666 .
O2 Eu1 O7 C20 -10.8(3) 2_566 .
C20 Eu1 O7 C20 140.9(3) 2_666 .
C7 Eu1 O7 C20 0.8(3) 2_566 .
C8 Eu1 O7 C20 -136.9(3) . .
O2 Eu1 O7 Eu1 133.58(10) . 2_666
O3 Eu1 O7 Eu1 87.16(9) . 2_666
O8 Eu1 O7 Eu1 162.86(10) . 2_666
O11 Eu1 O7 Eu1 -54.89(13) . 2_666
O1 Eu1 O7 Eu1 -114.28(10) 2_566 2_666
O6 Eu1 O7 Eu1 25.01(11) 2_666 2_666
O7 Eu1 O7 Eu1 0.0 2_666 2_666
O2 Eu1 O7 Eu1 -138.07(8) 2_566 2_666
C20 Eu1 O7 Eu1 13.60(10) 2_666 2_666
C7 Eu1 O7 Eu1 -126.43(9) 2_566 2_666
C8 Eu1 O7 Eu1 95.80(9) . 2_666
O2 Eu1 O8 C21 158.7(2) . .
O3 Eu1 O8 C21 77.2(2) . .
O11 Eu1 O8 C21 -136.9(2) . .
O7 Eu1 O8 C21 -4.4(2) . .
O1 Eu1 O8 C21 -81.6(2) 2_566 .
O6 Eu1 O8 C21 101.3(2) 2_666 .
O7 Eu1 O8 C21 18.8(3) 2_666 .
O2 Eu1 O8 C21 -133.9(2) 2_566 .
C20 Eu1 O8 C21 59.9(3) 2_666 .
C7 Eu1 O8 C21 -106.8(2) 2_566 .
C8 Eu1 O8 C21 97.7(2) . .
O4 Zn1 O9 C21 7.2(3) . .
N1 Zn1 O9 C21 129.2(3) 2_656 .
Cl1 Zn1 O9 C21 -117.2(2) . .
C6 C1 C2 C3 -0.6(5) . .
C7 C1 C2 C3 -175.8(3) . .
C6 C1 C2 C8 -175.3(3) . .
C7 C1 C2 C8 9.5(5) . .
C1 C2 C3 C4 2.8(5) . .
C8 C2 C3 C4 177.8(3) . .
C1 C2 C3 O5 177.1(3) . .
C8 C2 C3 O5 -7.9(4) . .
C10 O5 C3 C4 -90.1(4) . .
C10 O5 C3 C2 95.4(4) . .
C2 C3 C4 C5 -2.4(5) . .
O5 C3 C4 C5 -176.7(3) . .
C3 C4 C5 C6 -0.3(6) . .
C2 C1 C6 C5 -2.0(5) . .
C7 C1 C6 C5 173.2(3) . .
C4 C5 C6 C1 2.5(6) . .
Eu1 O1 C7 O2 5.3(3) 2_566 .
Eu1 O1 C7 C1 -172.7(2) 2_566 .
Eu1 O2 C7 O1 -161.7(3) . .
Eu1 O2 C7 O1 -5.0(3) 2_566 .
Eu1 O2 C7 C1 16.3(6) . .
Eu1 O2 C7 C1 173.0(2) 2_566 .
Eu1 O2 C7 Eu1 -156.7(4) . 2_566
C6 C1 C7 O1 35.8(4) . .
C2 C1 C7 O1 -149.0(3) . .
C6 C1 C7 O2 -142.2(3) . .
C2 C1 C7 O2 33.0(4) . .
C6 C1 C7 Eu1 -40(2) . 2_566
C2 C1 C7 Eu1 135.4(18) . 2_566
Eu1 O3 C8 O4 -108.9(3) . .
Eu1 O3 C8 C2 73.9(3) . .
Zn1 O4 C8 O3 -8.7(4) . .
Zn1 O4 C8 C2 168.77(19) . .
Zn1 O4 C8 Eu1 -58.8(3) . .
C3 C2 C8 O3 86.4(4) . .
C1 C2 C8 O3 -98.9(4) . .
C3 C2 C8 O4 -91.1(4) . .
C1 C2 C8 O4 83.6(4) . .
C3 C2 C8 Eu1 126.5(3) . .
C1 C2 C8 Eu1 -58.8(3) . .
O2 Eu1 C8 O3 178.8(3) . .
O8 Eu1 C8 O3 -97.0(2) . .
O11 Eu1 C8 O3 125.2(2) . .
O7 Eu1 C8 O3 -25.8(2) . .
O1 Eu1 C8 O3 -95.8(3) 2_566 .
O6 Eu1 C8 O3 85.5(2) 2_666 .
O7 Eu1 C8 O3 40.5(2) 2_666 .
O2 Eu1 C8 O3 -154.4(2) 2_566 .
C20 Eu1 C8 O3 62.4(2) 2_666 .
C7 Eu1 C8 O3 -132.1(2) 2_566 .
O2 Eu1 C8 O4 -79.8(3) . .
O3 Eu1 C8 O4 101.4(4) . .
O8 Eu1 C8 O4 4.4(2) . .
O11 Eu1 C8 O4 -133.4(2) . .
O7 Eu1 C8 O4 75.6(3) . .
O1 Eu1 C8 O4 5.6(3) 2_566 .
O6 Eu1 C8 O4 -173.2(3) 2_666 .
O7 Eu1 C8 O4 141.8(3) 2_666 .
O2 Eu1 C8 O4 -53.0(3) 2_566 .
C20 Eu1 C8 O4 163.8(3) 2_666 .
C7 Eu1 C8 O4 -30.7(3) 2_566 .
O2 Eu1 C8 C2 56.44(18) . .
O3 Eu1 C8 C2 -122.4(3) . .
O8 Eu1 C8 C2 140.6(2) . .
O11 Eu1 C8 C2 2.8(2) . .
O7 Eu1 C8 C2 -148.15(19) . .
O1 Eu1 C8 C2 141.84(18) 2_566 .
O6 Eu1 C8 C2 -36.91(18) 2_666 .
O7 Eu1 C8 C2 -81.90(19) 2_666 .
O2 Eu1 C8 C2 83.2(2) 2_566 .
C20 Eu1 C8 C2 -59.92(19) 2_666 .
C7 Eu1 C8 C2 105.6(2) 2_566 .
C13 N1 C9 C10 -2.3(5) . .
Zn1 N1 C9 C10 176.4(3) 2_656 .
N1 C9 C10 O5 177.9(3) . .
N1 C9 C10 C11 0.4(5) . .
C3 O5 C10 C9 158.9(3) . .
C3 O5 C10 C11 -23.7(5) . .
C9 C10 C11 C12 1.1(5) . .
O5 C10 C11 C12 -176.2(3) . .
C10 C11 C12 C13 -0.6(6) . .
C9 N1 C13 C12 2.8(6) . .
Zn1 N1 C13 C12 -175.8(3) 2_656 .
C11 C12 C13 N1 -1.4(6) . .
C19 C14 C15 C16 -1.1(4) . .
C20 C14 C15 C16 175.9(3) . .
C19 C14 C15 C21 179.9(3) . .
C20 C14 C15 C21 -3.0(4) . .
C23 O10 C16 C15 -165.8(3) . .
C23 O10 C16 C17 15.6(5) . .
C14 C15 C16 O10 -178.7(3) . .
C21 C15 C16 O10 0.3(4) . .
C14 C15 C16 C17 -0.1(5) . .
C21 C15 C16 C17 178.9(3) . .
O10 C16 C17 C18 -179.8(3) . .
C15 C16 C17 C18 1.7(5) . .
C16 C17 C18 C19 -2.1(6) . .
C17 C18 C19 C14 1.0(5) . .
C15 C14 C19 C18 0.6(5) . .
C20 C14 C19 C18 -176.5(3) . .
Eu1 O6 C20 O7 3.2(3) 2_666 .
Eu1 O6 C20 C14 -177.9(2) 2_666 .
Eu1 O7 C20 O6 -136.6(3) . .
Eu1 O7 C20 O6 -3.2(3) 2_666 .
Eu1 O7 C20 C14 44.6(4) . .
Eu1 O7 C20 C14 177.9(2) 2_666 .
Eu1 O7 C20 Eu1 -133.4(3) . 2_666
C15 C14 C20 O6 -152.0(3) . .
C19 C14 C20 O6 25.1(4) . .
C15 C14 C20 O7 26.9(4) . .
C19 C14 C20 O7 -156.0(3) . .
C15 C14 C20 Eu1 128(7) . 2_666
C19 C14 C20 Eu1 -54(7) . 2_666
Eu1 O8 C21 O9 -100.9(3) . .
Eu1 O8 C21 C15 81.0(3) . .
Zn1 O9 C21 O8 3.7(5) . .
Zn1 O9 C21 C15 -178.14(19) . .
C16 C15 C21 O8 92.8(4) . .
C14 C15 C21 O8 -88.3(4) . .
C16 C15 C21 O9 -85.5(4) . .
C14 C15 C21 O9 93.5(4) . .
C26 N2 C22 C23 0.2(6) . .
N2 C22 C23 C24 -0.9(6) . .
N2 C22 C23 O10 -178.1(3) . .
C16 O10 C23 C24 73.4(5) . .
C16 O10 C23 C22 -109.4(4) . .
C22 C23 C24 C25 1.9(6) . .
O10 C23 C24 C25 179.0(4) . .
C23 C24 C25 C26 -2.2(7) . .
C22 N2 C26 C25 -0.5(6) . .
C24 C25 C26 N2 1.6(7) . .
