Rare-earth dichloro and bis(alkyl) complexes supported by bulky amido-imino ligand. Synthesis, structure, reactivity and catalytic activity in isoprene polymerization.
Authors of publication
Kissel, Alexander A.; Lyubov, Dmitry M.; Mahrova, Tatyana V.; Fukin, Georgy K.; Cherkasov, Anton V.; Glukhova, Tatyana A.; Cui, Dongmei; Trifonov, Alexander A.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2013
Journal volume
42
Journal issue
25
Pages of publication
9211 - 9225
a
12.8326 ± 0.0006 Å
b
20.5123 ± 0.001 Å
c
13.8751 ± 0.0007 Å
α
90°
β
109.973 ± 0.001°
γ
90°
Cell volume
3432.6 ± 0.3 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
100 ± 2 K
Number of distinct elements
6
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for all reflections
0.0687
Residual factor for significantly intense reflections
0.0465
Weighted residual factors for significantly intense reflections
0.116
Weighted residual factors for all reflections included in the refinement
0.1247
Goodness-of-fit parameter for all reflections included in the refinement
