#------------------------------------------------------------------------------
#$Date: 2025-08-21 14:03:24 +0200 (Thu 21 de Aug de 2025) $
#$Revision: 301848 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/38/7023854.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7023854
loop_
_publ_author_name
'Liu, Baolin'
'Liu, Qingxia'
'Xiao, Hongping'
'Zhang, Wu'
'Tao, Ruojie'
_publ_section_title
;
 Family of dumbbell Ni4Ln2 (Ln = Pr, Sm, Eu, Gd, Tb, Ho, Er) complexes:
 syntheses, structures, luminescent and magnetic properties.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5047
_journal_page_last               5055
_journal_paper_doi               10.1039/c3dt32935f
_journal_volume                  42
_journal_year                    2013
_chemical_formula_moiety         'C60 H58 Eu2 N8 Ni4 O24, 9(H2 O)'
_chemical_formula_sum            'C60 H76 Eu2 N8 Ni4 O33'
_chemical_formula_weight         1976.05
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 98.101(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   12.703(3)
_cell_length_b                   18.339(5)
_cell_length_c                   15.578(4)
_cell_measurement_reflns_used    2215
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      25.25
_cell_measurement_theta_min      2.22
_cell_volume                     3592.8(16)
_computing_cell_refinement       'APEX 2'
_computing_data_collection       'APEX 2 (Bruker, 2009)'
_computing_data_reduction        'SAINT (Bruker, 2009)'
_computing_molecular_graphics    'SHELXTL (Bruker, 2009)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker Smart APEX II CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0452
_diffrn_reflns_av_sigmaI/netI    0.0529
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            17947
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.73
_exptl_absorpt_coefficient_mu    2.842
_exptl_absorpt_correction_T_max  0.7451
_exptl_absorpt_correction_T_min  0.6437
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker, 2009)'
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.827
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1988
_exptl_crystal_size_max          0.17
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.11
_refine_diff_density_max         1.935
_refine_diff_density_min         -1.419
_refine_diff_density_rms         0.234
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.064
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     487
_refine_ls_number_reflns         6331
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.064
_refine_ls_R_factor_all          0.0540
_refine_ls_R_factor_gt           0.0415
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0812P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1191
_refine_ls_wR_factor_ref         0.1300
_reflns_number_gt                5156
_reflns_number_total             6331
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt32935f.txt
_cod_data_source_block           1
_cod_original_cell_volume        3592.9(16)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7023854
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ni1 Ni 0.15540(6) 0.89262(4) 0.70755(5) 0.0353(2) Uani 1 1 d .
Ni2 Ni 0.30926(6) 1.04742(4) 0.70947(5) 0.03202(19) Uani 1 1 d .
Eu1 Eu 0.08134(2) 1.055429(13) 0.597304(17) 0.02785(12) Uani 1 1 d .
C1 C -0.1671(4) 0.9789(3) 0.6583(4) 0.0359(13) Uani 1 1 d .
C2 C -0.2628(5) 0.9723(4) 0.6930(5) 0.0585(19) Uani 1 1 d .
H2 H -0.3222 0.9977 0.6668 0.070 Uiso 1 1 calc R
C3 C -0.2722(6) 0.9299(5) 0.7640(6) 0.073(3) Uani 1 1 d .
H3 H -0.3362 0.9279 0.7864 0.088 Uiso 1 1 calc R
C4 C -0.1866(6) 0.8906(5) 0.8016(5) 0.071(2) Uani 1 1 d .
H4 H -0.1942 0.8596 0.8476 0.085 Uiso 1 1 calc R
C5 C -0.0871(5) 0.8960(3) 0.7718(4) 0.0483(16) Uani 1 1 d .
C6 C -0.0745(5) 0.9434(3) 0.7004(4) 0.0357(14) Uani 1 1 d .
C7 C -0.1727(4) 1.0204(3) 0.5750(4) 0.0323(12) Uani 1 1 d .
C8 C -0.0032(6) 0.8503(4) 0.8164(5) 0.0579(19) Uani 1 1 d .
H8 H -0.0217 0.8217 0.8613 0.070 Uiso 1 1 calc R
C9 C 0.1619(6) 0.7886(4) 0.8513(5) 0.064(2) Uani 1 1 d .
H9A H 0.1476 0.7410 0.8252 0.076 Uiso 1 1 calc R
H9B H 0.1465 0.7866 0.9105 0.076 Uiso 1 1 calc R
C10 C 0.2763(6) 0.8083(4) 0.8509(5) 0.062(2) Uani 1 1 d .
H10A H 0.3207 0.7665 0.8688 0.075 Uiso 1 1 calc R
H10B H 0.2958 0.8474 0.8921 0.075 Uiso 1 1 calc R
C11 C 0.3982(5) 0.8708(3) 0.7655(4) 0.0480(16) Uani 1 1 d .
H11A H 0.4030 0.8901 0.7082 0.058 Uiso 1 1 calc R
H11B H 0.4548 0.8353 0.7786 0.058 Uiso 1 1 calc R
C12 C 0.4183(6) 0.9336(4) 0.8314(5) 0.061(2) Uani 1 1 d .
H12A H 0.4257 0.9142 0.8899 0.073 Uiso 1 1 calc R
H12B H 0.4840 0.9583 0.8241 0.073 Uiso 1 1 calc R
C13 C 0.2787(7) 0.9979(4) 0.8832(5) 0.075(3) Uani 1 1 d .
H13 H 0.3061 0.9756 0.9352 0.090 Uiso 1 1 calc R
C14 C 0.1824(8) 1.0427(5) 0.8845(5) 0.074(3) Uani 1 1 d .
C15 C 0.1364(12) 1.0453(6) 0.9627(7) 0.137(6) Uani 1 1 d .
H15 H 0.1701 1.0204 1.0109 0.165 Uiso 1 1 calc R
C16 C 0.0478(12) 1.0815(7) 0.9702(8) 0.130(5) Uani 1 1 d .
H16 H 0.0233 1.0846 1.0235 0.156 Uiso 1 1 calc R
C17 C -0.0069(8) 1.1142(5) 0.8992(6) 0.091(3) Uani 1 1 d .
H17 H -0.0702 1.1384 0.9042 0.109 Uiso 1 1 calc R
C18 C 0.0299(6) 1.1122(3) 0.8197(5) 0.0524(18) Uani 1 1 d .
C19 C 0.1283(5) 1.0776(3) 0.8115(4) 0.0453(15) Uani 1 1 d .
C20 C -0.0405(5) 1.1451(4) 0.7448(5) 0.0570(19) Uani 1 1 d .
C21 C 0.2955(6) 0.7677(3) 0.7054(5) 0.0592(19) Uani 1 1 d .
H21A H 0.2534 0.7294 0.7269 0.071 Uiso 1 1 calc R
H21B H 0.3677 0.7498 0.7075 0.071 Uiso 1 1 calc R
C22 C 0.2512(6) 0.7848(4) 0.6141(5) 0.0569(18) Uani 1 1 d .
H22A H 0.2479 0.7407 0.5794 0.068 Uiso 1 1 calc R
H22B H 0.2970 0.8194 0.5902 0.068 Uiso 1 1 calc R
C24 C 0.4151(4) 1.1099(3) 0.5357(4) 0.0381(13) Uani 1 1 d .
C25 C 0.4679(5) 1.1392(4) 0.4699(5) 0.0546(17) Uani 1 1 d .
H25 H 0.5387 1.1268 0.4692 0.066 Uiso 1 1 calc R
C26 C 0.4202(5) 1.1844(4) 0.4078(5) 0.060(2) Uani 1 1 d .
H26 H 0.4581 1.2043 0.3666 0.073 Uiso 1 1 calc R
C27 C 0.3123(5) 1.2007(3) 0.4071(4) 0.0474(16) Uani 1 1 d .
H27 H 0.2788 1.2312 0.3640 0.057 Uiso 1 1 calc R
C28 C 0.2532(5) 1.1728(3) 0.4687(4) 0.0341(12) Uani 1 1 d .
C29 C 0.3057(4) 1.1289(3) 0.5370(4) 0.0305(12) Uani 1 1 d .
C30 C 0.1383(5) 1.1929(3) 0.4618(4) 0.0370(13) Uani 1 1 d .
N1 N 0.0931(4) 0.8444(3) 0.8015(4) 0.0513(15) Uani 1 1 d .
N2 N 0.2956(4) 0.8324(3) 0.7622(4) 0.0466(13) Uani 1 1 d .
N3 N 0.3292(4) 0.9860(3) 0.8187(3) 0.0460(13) Uani 1 1 d .
N4 N 0.1422(4) 0.8163(3) 0.6115(4) 0.0557(15) Uani 1 1 d .
H4A H 0.0953 0.7815 0.6211 0.067 Uiso 1 1 calc R
H4B H 0.1205 0.8370 0.5596 0.067 Uiso 1 1 calc R
C31 C 0.4729(5) 1.0594(3) 0.5940(4) 0.0419(15) Uani 1 1 d .
H31 H 0.5413 1.0493 0.5826 0.050 Uiso 1 1 calc R
O1 O 0.0197(3) 0.95372(19) 0.6760(3) 0.0346(9) Uani 1 1 d .
O2 O -0.0914(3) 1.0169(2) 0.5326(2) 0.0320(8) Uani 1 1 d .
O3 O -0.2552(3) 1.0538(2) 0.5447(3) 0.0448(11) Uani 1 1 d .
O4 O 0.1657(3) 1.0787(2) 0.7385(2) 0.0379(9) Uani 1 1 d .
O5 O -0.1131(5) 1.1865(5) 0.7604(5) 0.131(3) Uani 1 1 d .
O6 O -0.0277(3) 1.1297(2) 0.6678(3) 0.0514(11) Uani 1 1 d .
O7 O 0.4462(3) 1.0268(2) 0.6576(3) 0.0420(10) Uani 1 1 d .
O8 O 0.2574(3) 1.1070(2) 0.6019(2) 0.0338(9) Uani 1 1 d .
O9 O 0.0753(3) 1.1553(2) 0.5009(3) 0.0442(10) Uani 1 1 d .
O10 O 0.1053(4) 1.2465(3) 0.4164(3) 0.0615(14) Uani 1 1 d .
O1W O 0.3891(3) 1.1331(2) 0.7791(3) 0.0537(11) Uani 1 1 d .
H1WA H 0.3877 1.1230 0.8322 0.064 Uiso 1 1 d R
H1WB H 0.4543 1.1297 0.7728 0.064 Uiso 1 1 d R
O12 O 0.2228(3) 0.96722(19) 0.6397(2) 0.0302(8) Uani 1 1 d .
H12 H 0.2558 0.9475 0.5914 0.036 Uiso 1 1 calc R
O2W O 0.7178(5) 0.1897(3) 0.6368(4) 0.0913(19) Uani 1 1 d .
H2WA H 0.6677 0.1752 0.6634 0.110 Uiso 1 1 d R
H2WB H 0.7710 0.1939 0.6761 0.110 Uiso 1 1 d R
O3W O 0.5770(6) 0.1855(5) 0.7533(6) 0.162(5) Uani 1 1 d .
H3WA H 0.6037 0.1985 0.7086 0.194 Uiso 1 1 d R
H3WB H 0.5218 0.2118 0.7523 0.194 Uiso 1 1 d R
O4W O 0.5840(8) 0.7738(4) 0.9226(5) 0.149(4) Uani 1 1 d .
H4WA H 0.6358 0.7467 0.9430 0.179 Uiso 1 1 d R
H4WB H 0.5846 0.7734 0.8682 0.179 Uiso 1 1 d R
O5W O 0.4565(8) 0.1332(6) 0.9589(5) 0.182(5) Uani 1 1 d .
H5WA H 0.4374 0.1654 0.9206 0.218 Uiso 1 1 d R
H5WB H 0.4015 0.1070 0.9598 0.218 Uiso 1 1 d R
O6W O 0.7106(15) 0.1135(8) 0.9155(11) 0.144(7) Uani 0.50 1 d P
H6WA H 0.7702 0.1205 0.9467 0.173 Uiso 0.50 1 d PR
H6WB H 0.6648 0.1224 0.9490 0.173 Uiso 0.50 1 d PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ni1 O12 161.8(2) . . y
N1 Ni1 N4 103.7(2) . . y
O12 Ni1 N4 94.5(2) . . y
N1 Ni1 O1 90.64(18) . . y
O12 Ni1 O1 84.68(15) . . y
N4 Ni1 O1 102.7(2) . . y
N1 Ni1 N2 82.7(2) . . y
O12 Ni1 N2 99.65(17) . . y
N4 Ni1 N2 85.2(2) . . y
O1 Ni1 N2 170.78(19) . . y
O4 Ni2 N3 88.84(19) . . y
O4 Ni2 O8 80.44(15) . . y
N3 Ni2 O8 168.35(19) . . y
O4 Ni2 O12 83.64(15) . . y
N3 Ni2 O12 92.33(19) . . y
O8 Ni2 O12 82.03(15) . . y
O4 Ni2 O7 168.66(16) . . y
N3 Ni2 O7 102.43(19) . . y
O8 Ni2 O7 88.23(15) . . y
O12 Ni2 O7 94.57(16) . . y
O4 Ni2 O1W 93.31(17) . . y
N3 Ni2 O1W 89.3(2) . . y
O8 Ni2 O1W 95.80(17) . . y
O12 Ni2 O1W 176.50(16) . . y
O7 Ni2 O1W 88.09(18) . . y
O4 Ni2 Eu1 47.71(11) . . y
N3 Ni2 Eu1 119.03(16) . . y
O8 Ni2 Eu1 49.82(10) . . y
O12 Ni2 Eu1 50.34(10) . . y
O7 Ni2 Eu1 123.42(12) . . y
O1W Ni2 Eu1 126.20(13) . . y
O6 Eu1 O9 82.99(15) . . y
O6 Eu1 O2 78.45(14) . . y
O9 Eu1 O2 90.89(14) . . y
O6 Eu1 O8 111.50(14) . . y
O9 Eu1 O8 70.32(13) . . y
O2 Eu1 O8 156.67(13) . . y
O6 Eu1 O1 87.45(14) . . y
O9 Eu1 O1 159.20(14) . . y
O2 Eu1 O1 69.05(14) . . y
O8 Eu1 O1 130.49(13) . . y
O6 Eu1 O2 144.59(14) . 3_576 y
O9 Eu1 O2 83.97(13) . 3_576 y
O2 Eu1 O2 68.98(13) . 3_576 y
O8 Eu1 O2 94.63(12) . 3_576 y
O1 Eu1 O2 93.43(13) . 3_576 y
O6 Eu1 O12 136.54(15) . . y
O9 Eu1 O12 130.02(13) . . y
O2 Eu1 O12 121.04(12) . . y
O8 Eu1 O12 66.96(12) . . y
O1 Eu1 O12 68.31(12) . . y
O2 Eu1 O12 74.98(12) 3_576 . y
O6 Eu1 Ni2 109.00(12) . . y
O9 Eu1 Ni2 109.38(10) . . y
O2 Eu1 Ni2 158.89(9) . . y
O8 Eu1 Ni2 39.87(9) . . y
O1 Eu1 Ni2 91.18(10) . . y
O2 Eu1 Ni2 106.37(9) 3_576 . y
O12 Eu1 Ni2 40.41(8) . . y
O6 Eu1 Eu1 112.28(12) . 3_576 y
O9 Eu1 Eu1 86.85(11) . 3_576 y
O2 Eu1 Eu1 34.88(8) . 3_576 y
O8 Eu1 Eu1 126.94(9) . 3_576 y
O1 Eu1 Eu1 79.74(10) . 3_576 y
O2 Eu1 Eu1 34.10(8) 3_576 3_576 y
O12 Eu1 Eu1 98.68(8) . 3_576 y
Ni2 Eu1 Eu1 137.133(17) . 3_576 y
C2 C1 C6 119.2(6) . . ?
C2 C1 C7 116.1(5) . . ?
C6 C1 C7 124.6(5) . . ?
C3 C2 C1 122.5(7) . . ?
C3 C2 H2 118.7 . . ?
C1 C2 H2 118.7 . . ?
C4 C3 C2 119.5(6) . . ?
C4 C3 H3 120.3 . . ?
C2 C3 H3 120.3 . . ?
C3 C4 C5 121.2(7) . . ?
C3 C4 H4 119.4 . . ?
C5 C4 H4 119.4 . . ?
C4 C5 C6 120.0(6) . . ?
C4 C5 C8 115.7(6) . . ?
C6 C5 C8 124.3(5) . . ?
O1 C6 C1 121.7(5) . . ?
O1 C6 C5 121.0(5) . . ?
C1 C6 C5 117.3(5) . . ?
O3 C7 O2 121.0(5) . . ?
O3 C7 C1 120.8(5) . . ?
O2 C7 C1 118.0(5) . . ?
N1 C8 C5 128.1(6) . . ?
N1 C8 H8 116.0 . . ?
C5 C8 H8 116.0 . . ?
N1 C9 C10 109.3(5) . . ?
N1 C9 H9A 109.8 . . ?
C10 C9 H9A 109.8 . . ?
N1 C9 H9B 109.8 . . ?
C10 C9 H9B 109.8 . . ?
H9A C9 H9B 108.3 . . ?
C9 C10 N2 111.0(6) . . ?
C9 C10 H10A 109.4 . . ?
N2 C10 H10A 109.4 . . ?
C9 C10 H10B 109.4 . . ?
N2 C10 H10B 109.4 . . ?
H10A C10 H10B 108.0 . . ?
N2 C11 C12 116.3(5) . . ?
N2 C11 H11A 108.2 . . ?
C12 C11 H11A 108.2 . . ?
N2 C11 H11B 108.2 . . ?
C12 C11 H11B 108.2 . . ?
H11A C11 H11B 107.4 . . ?
N3 C12 C11 110.2(6) . . ?
N3 C12 H12A 109.6 . . ?
C11 C12 H12A 109.6 . . ?
N3 C12 H12B 109.6 . . ?
C11 C12 H12B 109.6 . . ?
H12A C12 H12B 108.1 . . ?
N3 C13 C14 127.7(7) . . ?
N3 C13 H13 116.2 . . ?
C14 C13 H13 116.2 . . ?
C19 C14 C15 117.8(8) . . ?
C19 C14 C13 123.8(6) . . ?
C15 C14 C13 118.1(8) . . ?
C16 C15 C14 123.1(10) . . ?
C16 C15 H15 118.4 . . ?
C14 C15 H15 118.4 . . ?
C15 C16 C17 119.6(9) . . ?
C15 C16 H16 120.2 . . ?
C17 C16 H16 120.2 . . ?
C16 C17 C18 121.1(9) . . ?
C16 C17 H17 119.4 . . ?
C18 C17 H17 119.4 . . ?
C17 C18 C19 120.3(8) . . ?
C17 C18 C20 116.6(7) . . ?
C19 C18 C20 123.1(6) . . ?
O4 C19 C14 121.5(6) . . ?
O4 C19 C18 120.6(6) . . ?
C14 C19 C18 117.9(6) . . ?
O5 C20 O6 121.3(8) . . ?
O5 C20 C18 118.2(7) . . ?
O6 C20 C18 120.5(6) . . ?
N2 C21 C22 111.8(5) . . ?
N2 C21 H21A 109.3 . . ?
C22 C21 H21A 109.3 . . ?
N2 C21 H21B 109.3 . . ?
C22 C21 H21B 109.3 . . ?
H21A C21 H21B 107.9 . . ?
C21 C22 N4 109.3(6) . . ?
C21 C22 H22A 109.8 . . ?
N4 C22 H22A 109.8 . . ?
C21 C22 H22B 109.8 . . ?
N4 C22 H22B 109.8 . . ?
H22A C22 H22B 108.3 . . ?
C25 C24 C31 117.1(6) . . ?
C25 C24 C29 118.6(6) . . ?
C31 C24 C29 124.1(5) . . ?
C26 C25 C24 123.0(6) . . ?
C26 C25 H25 118.5 . . ?
C24 C25 H25 118.5 . . ?
C25 C26 C27 118.4(6) . . ?
C25 C26 H26 120.8 . . ?
C27 C26 H26 120.8 . . ?
C28 C27 C26 122.5(6) . . ?
C28 C27 H27 118.8 . . ?
C26 C27 H27 118.8 . . ?
C27 C28 C29 118.7(5) . . ?
C27 C28 C30 118.3(5) . . ?
C29 C28 C30 122.9(5) . . ?
O8 C29 C28 121.8(5) . . ?
O8 C29 C24 119.6(5) . . ?
C28 C29 C24 118.7(5) . . ?
O10 C30 O9 120.9(5) . . ?
O10 C30 C28 118.8(5) . . ?
O9 C30 C28 120.3(5) . . ?
C8 N1 C9 118.0(5) . . ?
C8 N1 Ni1 126.2(4) . . ?
C9 N1 Ni1 115.3(4) . . ?
C11 N2 C21 109.3(5) . . ?
C11 N2 C10 111.5(5) . . ?
C21 N2 C10 109.1(5) . . ?
C11 N2 Ni1 116.4(4) . . ?
C21 N2 Ni1 104.0(4) . . ?
C10 N2 Ni1 106.2(4) . . ?
C13 N3 C12 117.5(6) . . ?
C13 N3 Ni2 123.1(4) . . ?
C12 N3 Ni2 118.5(4) . . ?
C22 N4 Ni1 105.4(4) . . ?
C22 N4 H4A 110.7 . . ?
Ni1 N4 H4A 110.7 . . ?
C22 N4 H4B 110.7 . . ?
Ni1 N4 H4B 110.7 . . ?
H4A N4 H4B 108.8 . . ?
O7 C31 C24 130.3(6) . . ?
O7 C31 H31 114.9 . . ?
C24 C31 H31 114.9 . . ?
C6 O1 Ni1 128.1(3) . . ?
C6 O1 Eu1 128.9(3) . . ?
Ni1 O1 Eu1 102.75(15) . . ?
C7 O2 Eu1 121.1(3) . . ?
C7 O2 Eu1 125.9(3) . 3_576 ?
Eu1 O2 Eu1 111.02(13) . 3_576 ?
C19 O4 Ni2 130.3(4) . . ?
C20 O6 Eu1 138.1(5) . . ?
C31 O7 Ni2 124.4(4) . . ?
C29 O8 Ni2 131.7(3) . . ?
C29 O8 Eu1 128.6(3) . . ?
Ni2 O8 Eu1 90.31(13) . . ?
C30 O9 Eu1 139.2(4) . . ?
Ni2 O1W H1WA 105.4 . . ?
Ni2 O1W H1WB 107.1 . . ?
H1WA O1W H1WB 104.5 . . ?
Ni1 O12 Ni2 116.62(18) . . ?
Ni1 O12 Eu1 104.12(15) . . ?
Ni2 O12 Eu1 89.25(13) . . ?
Ni1 O12 H12 114.6 . . ?
Ni2 O12 H12 114.6 . . ?
Eu1 O12 H12 114.6 . . ?
H2WA O2W H2WB 104.5 . . ?
H3WA O3W H3WB 104.5 . . ?
H4WA O4W H4WB 104.5 . . ?
H5WA O5W H5WB 104.5 . . ?
H6WA O6W H6WB 104.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ni1 N1 1.970(5) . y
Ni1 O12 1.994(4) . y
Ni1 N4 2.039(6) . y
Ni1 O1 2.057(4) . y
Ni1 N2 2.165(5) . y
Ni2 O4 2.022(4) . y
Ni2 N3 2.026(5) . y
Ni2 O8 2.030(4) . y
Ni2 O12 2.053(4) . y
Ni2 O7 2.054(4) . y
Ni2 O1W 2.090(4) . y
Ni2 Eu1 3.1672(10) . y
Eu1 O6 2.325(4) . y
Eu1 O9 2.363(4) . y
Eu1 O2 2.389(4) . y
Eu1 O8 2.420(4) . y
Eu1 O1 2.422(4) . y
Eu1 O2 2.437(4) 3_576 y
Eu1 O12 2.438(4) . y
C1 C2 1.405(8) . ?
C1 C6 1.422(8) . ?
C1 C7 1.497(8) . ?
C2 C3 1.371(10) . ?
C2 H2 0.9300 . ?
C3 C4 1.365(11) . ?
C3 H3 0.9300 . ?
C4 C5 1.410(9) . ?
C4 H4 0.9300 . ?
C5 C6 1.438(8) . ?
C5 C8 1.454(9) . ?
C6 O1 1.319(7) . ?
C7 O3 1.248(7) . ?
C7 O2 1.303(6) . ?
C8 N1 1.281(8) . ?
C8 H8 0.9300 . ?
C9 N1 1.490(8) . ?
C9 C10 1.499(10) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 N2 1.504(8) . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C11 N2 1.475(8) . ?
C11 C12 1.542(10) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C12 N3 1.477(9) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C13 N3 1.284(9) . ?
C13 C14 1.477(11) . ?
C13 H13 0.9300 . ?
C14 C19 1.398(11) . ?
C14 C15 1.425(11) . ?
C15 C16 1.325(16) . ?
C15 H15 0.9300 . ?
C16 C17 1.359(16) . ?
C16 H16 0.9300 . ?
C17 C18 1.385(10) . ?
C17 H17 0.9300 . ?
C18 C19 1.423(9) . ?
C18 C20 1.494(11) . ?
C19 O4 1.294(7) . ?
C20 O5 1.244(8) . ?
C20 O6 1.266(8) . ?
C21 N2 1.480(9) . ?
C21 C22 1.488(10) . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C22 N4 1.496(8) . ?
C22 H22A 0.9700 . ?
C22 H22B 0.9700 . ?
C24 C25 1.407(8) . ?
C24 C31 1.425(9) . ?
C24 C29 1.436(7) . ?
C25 C26 1.352(10) . ?
C25 H25 0.9300 . ?
C26 C27 1.401(9) . ?
C26 H26 0.9300 . ?
C27 C28 1.396(8) . ?
C27 H27 0.9300 . ?
C28 C29 1.424(8) . ?
C28 C30 1.494(8) . ?
C29 O8 1.318(6) . ?
C30 O10 1.248(7) . ?
C30 O9 1.275(6) . ?
N4 H4A 0.9000 . ?
N4 H4B 0.9000 . ?
C31 O7 1.246(7) . ?
C31 H31 0.9300 . ?
O2 Eu1 2.438(4) 3_576 y
O1W H1WA 0.8500 . ?
O1W H1WB 0.8500 . ?
O12 H12 0.9800 . ?
O2W H2WA 0.8500 . ?
O2W H2WB 0.8500 . ?
O3W H3WA 0.8500 . ?
O3W H3WB 0.8500 . ?
O4W H4WA 0.8500 . ?
O4W H4WB 0.8500 . ?
O5W H5WA 0.8500 . ?
O5W H5WB 0.8500 . ?
O6W H6WA 0.8500 . ?
O6W H6WB 0.8500 . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N4 H4A O10 0.90 2.58 3.319(7) 139.3 3_576
N4 H4B O9 0.90 2.54 3.099(7) 121.2 3_576
O1W H1WA O5W 0.85 2.05 2.811(9) 148.4 1_565
O1W H1WB O3W 0.85 1.92 2.656(7) 143.4 1_565
O12 H12 O3 0.98 2.12 2.983(6) 146.1 3_576
O2W H2WA O3W 0.85 1.94 2.723(9) 151.8 .
O2W H2WB O5 0.85 1.83 2.676(8) 170.6 1_645
O3W H3WA O2W 0.85 1.96 2.723(9) 149.1 .
O4W H4WA O2W 0.85 2.60 3.199(11) 128.8 2_656
O4W H4WB O5 0.85 2.62 3.337(12) 142.2 2_546
O5W H5WA O1W 0.85 2.28 2.811(9) 120.7 1_545
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O4 Ni2 Eu1 O6 17.21(19) . .
N3 Ni2 Eu1 O6 74.8(2) . .
O8 Ni2 Eu1 O6 -101.09(19) . .
O12 Ni2 Eu1 O6 141.23(18) . .
O7 Ni2 Eu1 O6 -153.81(19) . .
O1W Ni2 Eu1 O6 -38.1(2) . .
O4 Ni2 Eu1 O9 106.31(19) . .
N3 Ni2 Eu1 O9 163.9(2) . .
O8 Ni2 Eu1 O9 -11.99(18) . .
O12 Ni2 Eu1 O9 -129.67(17) . .
O7 Ni2 Eu1 O9 -64.71(18) . .
O1W Ni2 Eu1 O9 51.0(2) . .
O4 Ni2 Eu1 O2 -90.5(3) . .
N3 Ni2 Eu1 O2 -32.9(3) . .
O8 Ni2 Eu1 O2 151.2(3) . .
O12 Ni2 Eu1 O2 33.5(3) . .
O7 Ni2 Eu1 O2 98.5(3) . .
O1W Ni2 Eu1 O2 -145.8(3) . .
O4 Ni2 Eu1 O8 118.3(2) . .
N3 Ni2 Eu1 O8 175.9(2) . .
O12 Ni2 Eu1 O8 -117.67(19) . .
O7 Ni2 Eu1 O8 -52.7(2) . .
O1W Ni2 Eu1 O8 63.0(2) . .
O4 Ni2 Eu1 O1 -70.50(18) . .
N3 Ni2 Eu1 O1 -12.91(19) . .
O8 Ni2 Eu1 O1 171.20(17) . .
O12 Ni2 Eu1 O1 53.53(16) . .
O7 Ni2 Eu1 O1 118.48(17) . .
O1W Ni2 Eu1 O1 -125.82(19) . .
O4 Ni2 Eu1 O2 -164.42(18) . 3_576
N3 Ni2 Eu1 O2 -106.8(2) . 3_576
O8 Ni2 Eu1 O2 77.27(17) . 3_576
O12 Ni2 Eu1 O2 -40.40(16) . 3_576
O7 Ni2 Eu1 O2 24.56(17) . 3_576
O1W Ni2 Eu1 O2 140.26(19) . 3_576
O4 Ni2 Eu1 O12 -124.0(2) . .
N3 Ni2 Eu1 O12 -66.4(2) . .
O8 Ni2 Eu1 O12 117.67(19) . .
O7 Ni2 Eu1 O12 64.95(19) . .
O1W Ni2 Eu1 O12 -179.3(2) . .
O4 Ni2 Eu1 Eu1 -146.64(16) . 3_576
N3 Ni2 Eu1 Eu1 -89.05(17) . 3_576
O8 Ni2 Eu1 Eu1 95.06(14) . 3_576
O12 Ni2 Eu1 Eu1 -22.61(13) . 3_576
O7 Ni2 Eu1 Eu1 42.34(15) . 3_576
O1W Ni2 Eu1 Eu1 158.05(16) . 3_576
C6 C1 C2 C3 -3.2(11) . .
C7 C1 C2 C3 173.4(7) . .
C1 C2 C3 C4 -2.0(14) . .
C2 C3 C4 C5 3.7(15) . .
C3 C4 C5 C6 -0.3(13) . .
C3 C4 C5 C8 -178.9(9) . .
C2 C1 C6 O1 -172.9(6) . .
C7 C1 C6 O1 10.7(9) . .
C2 C1 C6 C5 6.4(9) . .
C7 C1 C6 C5 -170.0(6) . .
C4 C5 C6 O1 174.6(7) . .
C8 C5 C6 O1 -7.0(10) . .
C4 C5 C6 C1 -4.7(10) . .
C8 C5 C6 C1 173.7(7) . .
C2 C1 C7 O3 7.8(8) . .
C6 C1 C7 O3 -175.7(5) . .
C2 C1 C7 O2 -167.9(6) . .
C6 C1 C7 O2 8.5(8) . .
C4 C5 C8 N1 179.1(8) . .
C6 C5 C8 N1 0.7(13) . .
N1 C9 C10 N2 -43.5(9) . .
N2 C11 C12 N3 -53.2(8) . .
N3 C13 C14 C19 2.6(16) . .
N3 C13 C14 C15 176.8(10) . .
C19 C14 C15 C16 -3(2) . .
C13 C14 C15 C16 -177.4(13) . .
C14 C15 C16 C17 4(2) . .
C15 C16 C17 C18 -2(2) . .
C16 C17 C18 C19 -2.1(15) . .
C16 C17 C18 C20 175.6(11) . .
C15 C14 C19 O4 178.9(9) . .
C13 C14 C19 O4 -6.9(14) . .
C15 C14 C19 C18 -1.2(13) . .
C13 C14 C19 C18 173.0(8) . .
C17 C18 C19 O4 -176.6(7) . .
C20 C18 C19 O4 5.9(10) . .
C17 C18 C19 C14 3.6(11) . .
C20 C18 C19 C14 -174.0(7) . .
C17 C18 C20 O5 16.6(11) . .
C19 C18 C20 O5 -165.8(8) . .
C17 C18 C20 O6 -161.7(7) . .
C19 C18 C20 O6 15.9(10) . .
N2 C21 C22 N4 -55.7(8) . .
C31 C24 C25 C26 176.3(7) . .
C29 C24 C25 C26 0.0(11) . .
C24 C25 C26 C27 -2.5(12) . .
C25 C26 C27 C28 1.0(11) . .
C26 C27 C28 C29 2.8(10) . .
C26 C27 C28 C30 -179.5(6) . .
C27 C28 C29 O8 173.0(5) . .
C30 C28 C29 O8 -4.6(8) . .
C27 C28 C29 C24 -5.2(8) . .
C30 C28 C29 C24 177.2(5) . .
C25 C24 C29 O8 -174.4(5) . .
C31 C24 C29 O8 9.6(9) . .
C25 C24 C29 C28 3.8(8) . .
C31 C24 C29 C28 -172.2(6) . .
C27 C28 C30 O10 -17.4(9) . .
C29 C28 C30 O10 160.2(6) . .
C27 C28 C30 O9 161.8(6) . .
C29 C28 C30 O9 -20.6(9) . .
C5 C8 N1 C9 -174.8(8) . .
C5 C8 N1 Ni1 -3.7(12) . .
C10 C9 N1 C8 -158.7(7) . .
C10 C9 N1 Ni1 29.2(8) . .
O12 Ni1 N1 C8 83.0(9) . .
N4 Ni1 N1 C8 -95.0(7) . .
O1 Ni1 N1 C8 8.2(7) . .
N2 Ni1 N1 C8 -178.3(7) . .
O12 Ni1 N1 C9 -105.8(7) . .
N4 Ni1 N1 C9 76.2(6) . .
O1 Ni1 N1 C9 179.5(5) . .
N2 Ni1 N1 C9 -7.0(5) . .
C12 C11 N2 C21 -171.9(5) . .
C12 C11 N2 C10 -51.3(7) . .
C12 C11 N2 Ni1 70.7(6) . .
C22 C21 N2 C11 -91.5(6) . .
C22 C21 N2 C10 146.4(6) . .
C22 C21 N2 Ni1 33.4(6) . .
C9 C10 N2 C11 164.2(6) . .
C9 C10 N2 C21 -75.0(7) . .
C9 C10 N2 Ni1 36.6(7) . .
N1 Ni1 N2 C11 -140.9(5) . .
O12 Ni1 N2 C11 20.8(5) . .
N4 Ni1 N2 C11 114.5(5) . .
N1 Ni1 N2 C21 98.8(4) . .
O12 Ni1 N2 C21 -99.5(4) . .
N4 Ni1 N2 C21 -5.7(4) . .
N1 Ni1 N2 C10 -16.3(5) . .
O12 Ni1 N2 C10 145.5(4) . .
N4 Ni1 N2 C10 -120.8(5) . .
C14 C13 N3 C12 -174.6(9) . .
C14 C13 N3 Ni2 16.2(13) . .
C11 C12 N3 C13 121.5(8) . .
C11 C12 N3 Ni2 -68.8(7) . .
O4 Ni2 N3 C13 -22.0(7) . .
O8 Ni2 N3 C13 -44.9(13) . .
O12 Ni2 N3 C13 -105.6(7) . .
O7 Ni2 N3 C13 159.2(7) . .
O1W Ni2 N3 C13 71.3(7) . .
Eu1 Ni2 N3 C13 -60.6(7) . .
O4 Ni2 N3 C12 168.9(5) . .
O8 Ni2 N3 C12 146.0(8) . .
O12 Ni2 N3 C12 85.4(5) . .
O7 Ni2 N3 C12 -9.8(5) . .
O1W Ni2 N3 C12 -97.7(5) . .
Eu1 Ni2 N3 C12 130.3(5) . .
C21 C22 N4 Ni1 46.5(6) . .
N1 Ni1 N4 C22 -103.0(4) . .
O12 Ni1 N4 C22 77.6(4) . .
O1 Ni1 N4 C22 163.2(4) . .
N2 Ni1 N4 C22 -21.7(4) . .
C25 C24 C31 O7 178.8(7) . .
C29 C24 C31 O7 -5.1(11) . .
C1 C6 O1 Ni1 -165.0(4) . .
C5 C6 O1 Ni1 15.8(8) . .
C1 C6 O1 Eu1 22.6(8) . .
C5 C6 O1 Eu1 -156.7(4) . .
N1 Ni1 O1 C6 -14.7(5) . .
O12 Ni1 O1 C6 -177.0(5) . .
N4 Ni1 O1 C6 89.5(5) . .
N1 Ni1 O1 Eu1 159.3(2) . .
O12 Ni1 O1 Eu1 -3.06(15) . .
N4 Ni1 O1 Eu1 -96.5(2) . .
O6 Eu1 O1 C6 33.5(5) . .
O9 Eu1 O1 C6 -29.1(7) . .
O2 Eu1 O1 C6 -45.1(5) . .
O8 Eu1 O1 C6 149.8(4) . .
O2 Eu1 O1 C6 -111.1(5) 3_576 .
O12 Eu1 O1 C6 176.6(5) . .
Ni2 Eu1 O1 C6 142.4(5) . .
Eu1 Eu1 O1 C6 -79.7(5) 3_576 .
O6 Eu1 O1 Ni1 -140.42(18) . .
O9 Eu1 O1 Ni1 157.1(3) . .
O2 Eu1 O1 Ni1 140.97(19) . .
O8 Eu1 O1 Ni1 -24.0(2) . .
O2 Eu1 O1 Ni1 75.03(17) 3_576 .
O12 Eu1 O1 Ni1 2.68(14) . .
Ni2 Eu1 O1 Ni1 -31.45(14) . .
Eu1 Eu1 O1 Ni1 106.39(14) 3_576 .
O3 C7 O2 Eu1 125.1(5) . .
C1 C7 O2 Eu1 -59.2(6) . .
O3 C7 O2 Eu1 -72.3(6) . 3_576
C1 C7 O2 Eu1 103.4(5) . 3_576
O6 Eu1 O2 C7 -29.2(4) . .
O9 Eu1 O2 C7 -111.8(4) . .
O8 Eu1 O2 C7 -147.3(4) . .
O1 Eu1 O2 C7 62.5(4) . .
O2 Eu1 O2 C7 165.0(5) 3_576 .
O12 Eu1 O2 C7 108.7(4) . .
Ni2 Eu1 O2 C7 84.0(4) . .
Eu1 Eu1 O2 C7 165.0(5) 3_576 .
O6 Eu1 O2 Eu1 165.85(19) . 3_576
O9 Eu1 O2 Eu1 83.19(16) . 3_576
O8 Eu1 O2 Eu1 47.7(4) . 3_576
O1 Eu1 O2 Eu1 -102.46(17) . 3_576
O2 Eu1 O2 Eu1 0.0 3_576 3_576
O12 Eu1 O2 Eu1 -56.27(19) . 3_576
Ni2 Eu1 O2 Eu1 -81.0(3) . 3_576
C14 C19 O4 Ni2 -9.3(10) . .
C18 C19 O4 Ni2 170.8(4) . .
N3 Ni2 O4 C19 20.1(5) . .
O8 Ni2 O4 C19 -164.4(5) . .
O12 Ni2 O4 C19 112.6(5) . .
O7 Ni2 O4 C19 -165.9(8) . .
O1W Ni2 O4 C19 -69.1(5) . .
Eu1 Ni2 O4 C19 152.5(6) . .
O5 C20 O6 Eu1 -176.3(6) . .
C18 C20 O6 Eu1 2.0(10) . .
O9 Eu1 O6 C20 -142.0(7) . .
O2 Eu1 O6 C20 125.7(7) . .
O8 Eu1 O6 C20 -76.4(7) . .
O1 Eu1 O6 C20 56.5(6) . .
O2 Eu1 O6 C20 148.9(6) 3_576 .
O12 Eu1 O6 C20 2.3(7) . .
Ni2 Eu1 O6 C20 -33.8(7) . .
Eu1 Eu1 O6 C20 134.4(6) 3_576 .
C24 C31 O7 Ni2 -8.6(10) . .
O4 Ni2 O7 C31 14.0(12) . .
N3 Ni2 O7 C31 -172.2(5) . .
O8 Ni2 O7 C31 12.5(5) . .
O12 Ni2 O7 C31 94.4(5) . .
O1W Ni2 O7 C31 -83.4(5) . .
Eu1 Ni2 O7 C31 50.0(5) . .
C28 C29 O8 Ni2 -178.0(4) . .
C24 C29 O8 Ni2 0.1(7) . .
C28 C29 O8 Eu1 45.8(7) . .
C24 C29 O8 Eu1 -136.1(4) . .
O4 Ni2 O8 C29 171.4(5) . .
N3 Ni2 O8 C29 -165.3(9) . .
O12 Ni2 O8 C29 -103.8(5) . .
O7 Ni2 O8 C29 -8.9(5) . .
O1W Ni2 O8 C29 79.0(5) . .
Eu1 Ni2 O8 C29 -147.3(5) . .
O4 Ni2 O8 Eu1 -41.34(14) . .
N3 Ni2 O8 Eu1 -18.1(10) . .
O12 Ni2 O8 Eu1 43.50(13) . .
O7 Ni2 O8 Eu1 138.36(15) . .
O1W Ni2 O8 Eu1 -133.73(15) . .
O6 Eu1 O8 C29 -116.9(4) . .
O9 Eu1 O8 C29 -43.1(4) . .
O2 Eu1 O8 C29 -5.1(6) . .
O1 Eu1 O8 C29 137.3(4) . .
O2 Eu1 O8 C29 38.8(4) 3_576 .
O12 Eu1 O8 C29 110.3(4) . .
Ni2 Eu1 O8 C29 148.9(5) . .
Eu1 Eu1 O8 C29 26.9(4) 3_576 .
O6 Eu1 O8 Ni2 94.26(17) . .
O9 Eu1 O8 Ni2 167.98(18) . .
O2 Eu1 O8 Ni2 -154.0(2) . .
O1 Eu1 O8 Ni2 -11.6(2) . .
O2 Eu1 O8 Ni2 -110.12(14) 3_576 .
O12 Eu1 O8 Ni2 -38.60(12) . .
Eu1 Eu1 O8 Ni2 -122.02(10) 3_576 .
O10 C30 O9 Eu1 -176.8(5) . .
C28 C30 O9 Eu1 4.0(9) . .
O6 Eu1 O9 C30 134.8(6) . .
O2 Eu1 O9 C30 -146.9(6) . .
O8 Eu1 O9 C30 19.0(6) . .
O1 Eu1 O9 C30 -161.9(5) . .
O2 Eu1 O9 C30 -78.2(6) 3_576 .
O12 Eu1 O9 C30 -13.6(7) . .
Ni2 Eu1 O9 C30 27.1(6) . .
Eu1 Eu1 O9 C30 -112.3(6) 3_576 .
N1 Ni1 O12 Ni2 23.7(7) . .
N4 Ni1 O12 Ni2 -158.2(2) . .
O1 Ni1 O12 Ni2 99.4(2) . .
N2 Ni1 O12 Ni2 -72.4(2) . .
N1 Ni1 O12 Eu1 -72.7(6) . .
N4 Ni1 O12 Eu1 105.39(19) . .
O1 Ni1 O12 Eu1 3.06(15) . .
N2 Ni1 O12 Eu1 -168.73(18) . .
O4 Ni2 O12 Ni1 -67.4(2) . .
N3 Ni2 O12 Ni1 21.2(2) . .
O8 Ni2 O12 Ni1 -148.5(2) . .
O7 Ni2 O12 Ni1 123.9(2) . .
Eu1 Ni2 O12 Ni1 -105.4(2) . .
O4 Ni2 O12 Eu1 38.09(14) . .
N3 Ni2 O12 Eu1 126.66(17) . .
O8 Ni2 O12 Eu1 -43.10(12) . .
O7 Ni2 O12 Eu1 -130.66(14) . .
O6 Eu1 O12 Ni1 57.9(2) . .
O9 Eu1 O12 Ni1 -171.21(15) . .
O2 Eu1 O12 Ni1 -49.27(19) . .
O8 Eu1 O12 Ni1 155.41(19) . .
O1 Eu1 O12 Ni1 -2.78(14) . .
O2 Eu1 O12 Ni1 -102.77(16) 3_576 .
Ni2 Eu1 O12 Ni1 117.3(2) . .
Eu1 Eu1 O12 Ni1 -78.03(13) 3_576 .
O6 Eu1 O12 Ni2 -59.4(2) . .
O9 Eu1 O12 Ni2 71.5(2) . .
O2 Eu1 O12 Ni2 -166.58(11) . .
O8 Eu1 O12 Ni2 38.09(12) . .
O1 Eu1 O12 Ni2 -120.09(16) . .
O2 Eu1 O12 Ni2 139.92(15) 3_576 .
Eu1 Eu1 O12 Ni2 164.66(9) 3_576 .
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1 PubChem 139160813
