Information card for entry 7023941

Structure parameters

• Formula: C56 H108 N8 Si8 Sm2
• Calculated formula: C56 H108 N8 Si8 Sm2
• SMILES: CC1=CC(=[N](c2ccc([N]3=C(C=C(C)N(c4c(cccc4C)C)[Sm]3(N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C)cc2)[Sm](N1c1c(cccc1C)C)(N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)C
• Title of publication: Synthesis of β-diketiminate-ligated bimetallic and monometallic lanthanide amide complexes and their reactivity with isoprene and AlMe3.
• Authors of publication: Sun, Song; Ouyang, Hao; Luo, Yunjie; Zhang, Yong; Shen, Qi; Yao, Yingming
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2013
• Journal volume: 42
• Journal issue: 46
• Pages of publication: 16355 - 16364
• a: 11.2006 ± 0.0012 Å
• b: 11.4482 ± 0.0011 Å
• c: 15.2323 ± 0.0013 Å
• α: 92.946 ± 0.002°
• β: 93.603 ± 0.002°
• γ: 108.289 ± 0.003°
• Cell volume: 1845.6 ± 0.3 ų
• Cell temperature: 223 ± 2 K
• Ambient diffraction temperature: 223 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0386
• Residual factor for significantly intense reflections: 0.0316
• Weighted residual factors for significantly intense reflections: 0.0619
• Weighted residual factors for all reflections included in the refinement: 0.0643
• Goodness-of-fit parameter for all reflections included in the refinement: 1.041
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No