Information card for entry 7024699

Structure parameters

• Formula: C150 H118 La2 N2 O9 Si4
• Calculated formula: C150 H118 La2 N2 O9 Si4
• SMILES: [La]1234([n]5c(c6c(O1)c([Si](c1ccccc1)(c1ccccc1)c1ccccc1)cc1ccccc61)cccc5c1c(O2)c([Si](c2ccccc2)(c2ccccc2)c2ccccc2)cc2ccccc12)([O]1CCCC1)([OH2])[La]12([n]5c(c6c(O1)c([Si](c1ccccc1)(c1ccccc1)c1ccccc1)cc1ccccc61)cccc5c1c(O2)c([Si](c2ccccc2)(c2ccccc2)c2ccccc2)cc2ccccc12)([OH2])([OH]3)[OH]4.c1ccccc1.c1ccccc1.c1ccccc1.c1ccccc1
• Title of publication: Group 3 metal complexes supported by tridentate pyridine- and thiophene-linked bis(naphtholate) ligands: synthesis, structure, and use in stereoselective ring-opening polymerization of racemic lactide and beta-butyrolactone.
• Authors of publication: Grunova, Ekaterina; Kirillov, Evgueni; Roisnel, Thierry; Carpentier, Jean-François
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2010
• Journal volume: 39
• Journal issue: 29
• Pages of publication: 6739 - 6752
• a: 22.4713 ± 0.0009 Å
• b: 29.6425 ± 0.0013 Å
• c: 39.18 ± 0.0014 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 26098 ± 1.8 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 61
• Hermann-Mauguin space group symbol: P c a b
• Hall space group symbol: -P 2bc 2ac
• Residual factor for all reflections: 0.1255
• Residual factor for significantly intense reflections: 0.0828
• Weighted residual factors for significantly intense reflections: 0.1829
• Weighted residual factors for all reflections included in the refinement: 0.2032
• Goodness-of-fit parameter for all reflections included in the refinement: 1.032
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No