Information card for entry 7025185

Structure parameters

• Formula: C64 H84 Cl2 N4 O P4 Si4 Zn4
• Calculated formula: C64 H84 Cl2 N4 O P4 Si4 Zn4
• SMILES: C1[Zn]23[N](=P(C[Zn]45[N](=P(C[Zn]6([N](=P(C[Zn]([N](=P1(c1ccccc1)c1ccccc1)[Si](C)(C)C)([O]256)[Cl]4)(c1ccccc1)c1ccccc1)[Si](C)(C)C)[Cl]3)(c1ccccc1)c1ccccc1)[Si](C)(C)C)(c1ccccc1)c1ccccc1)[Si](C)(C)C
• Title of publication: Reactivity of Zn(II), Mg(II) and Al(III) chlorides with a phosphinimine ligand: new tetrameric inverse crown ether structures.
• Authors of publication: Valerio Cárdenas, Cintya; Muñoz Hernández, Miguel Angel; Grévy, Jean-Michel
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2010
• Journal volume: 39
• Journal issue: 28
• Pages of publication: 6441 - 6448
• a: 14.8254 ± 0.0019 Å
• b: 14.8254 ± 0.0019 Å
• c: 16.278 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3577.8 ± 0.9 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 114
• Hermann-Mauguin space group symbol: P -4 21 c
• Hall space group symbol: P -4 2n
• Residual factor for all reflections: 0.0456
• Residual factor for significantly intense reflections: 0.0364
• Weighted residual factors for significantly intense reflections: 0.057
• Weighted residual factors for all reflections included in the refinement: 0.0581
• Goodness-of-fit parameter for all reflections included in the refinement: 0.976
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No