#------------------------------------------------------------------------------
#$Date: 2016-03-25 15:20:24 +0100 (Fri 25 de Mar de 2016) $
#$Revision: 179964 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/58/7025814.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7025814
loop_
_publ_author_name
'López-Valbuena, Josep M'
'Escudero-Adan, Eduardo C'
'Benet-Buchholz, Jordi'
'Freixa, Zoraida'
'van Leeuwen, Piet W. N. M.'
_publ_section_title
;
 An approach to bimetallic catalysts by ligand design.
;
_journal_issue                   36
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8560
_journal_page_last               8574
_journal_paper_doi               10.1039/c0dt00011f
_journal_volume                  39
_journal_year                    2010
_chemical_formula_sum            'C90 H76 Cl14 O6 P4 Rh2'
_chemical_formula_weight         2079.51
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 100.5780(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   16.6357(4)
_cell_length_b                   18.7449(5)
_cell_length_c                   14.8117(4)
_cell_measurement_reflns_used    9892
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      39.51
_cell_measurement_theta_min      3.26
_cell_volume                     4540.3(2)
_computing_cell_refinement       'Bruker APEX2 v2009.1-0'
_computing_data_collection       'Bruker APEX2 v2009.1-0'
_computing_data_reduction        'Bruker SAINT V7.60A'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 512
_diffrn_detector_type            '4K CCD area detector APEX II'
_diffrn_measured_fraction_theta_full 0.960
_diffrn_measured_fraction_theta_max 0.960
_diffrn_measurement_device_type  'Kappa 4-axis goniometer bruker-nonius'
_diffrn_measurement_method
;
Fullsphere data collection, phi and omega scans
;
_diffrn_measurement_specimen_support
'magnetic support whith 10 micron nylon fiber cryoloop'
_diffrn_radiation_monochromator  'Multilayer Montel 200 mirrors'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0223
_diffrn_reflns_av_sigmaI/netI    0.0227
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       33
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            90973
_diffrn_reflns_theta_full        39.65
_diffrn_reflns_theta_max         39.65
_diffrn_reflns_theta_min         2.50
_diffrn_source                   'rotating anode X-ray tube'
_diffrn_source_current           70
_diffrn_source_power             50
_diffrn_source_size              '3 mm x 0.3 mm fine focus'
_diffrn_source_type              'Bruker-Nonius FR 591'
_exptl_absorpt_coefficient_mu    0.898
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.9601
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details
;
SADABS Version 2008/1 Bruker-Nonius
Blessing, Acta Cryst. (1995) A51 33-38
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.521
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             2104
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_refine_diff_density_max         2.153
_refine_diff_density_min         -1.885
_refine_diff_density_rms         0.096
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     527
_refine_ls_number_reflns         26435
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.029
_refine_ls_R_factor_all          0.0435
_refine_ls_R_factor_gt           0.0349
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0519P)²+3.4554P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0955
_refine_ls_wR_factor_ref         0.1021
_reflns_number_gt                22591
_reflns_number_total             26435
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c0dt00011f.txt
_cod_data_source_block           jm045p21c_17
_cod_depositor_comments
;
The following automatic conversions were performed:
'_diffrn_measurement_specimen_suppport' tag replaced with
'_diffrn_measurement_specimen_support'.

Automatic conversion script
Id: cif_correct_tags 1440 2010-10-19 06:21:57Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7025814
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Rh1 Rh 1.196000(4) 0.550045(4) 0.105490(5) 0.01116(2) Uani 1 1 d .
P1 P 1.314337(16) 0.512664(15) 0.058169(18) 0.01143(4) Uani 1 1 d .
Cl1 Cl 1.265657(17) 0.535082(18) 0.259601(18) 0.01888(5) Uani 1 1 d .
C1 C 1.14411(6) 0.55566(6) -0.01302(7) 0.01390(15) Uani 1 1 d .
O1 O 1.11075(6) 0.55729(5) -0.08836(6) 0.01865(15) Uani 1 1 d .
P2 P 1.088002(16) 0.611833(15) 0.150435(19) 0.01194(4) Uani 1 1 d .
C2 C 1.39514(6) 0.57424(6) 0.10731(7) 0.01427(15) Uani 1 1 d .
O2 O 1.21469(5) 0.42198(4) -0.09465(5) 0.01363(12) Uani 1 1 d .
C3 C 1.37802(7) 0.64743(6) 0.09641(9) 0.01926(18) Uani 1 1 d .
H3 H 1.3264 0.6627 0.0634 0.023 Uiso 1 1 calc R
O3 O 1.10113(5) 0.36210(4) -0.17403(6) 0.01412(12) Uani 1 1 d .
C4 C 1.43620(9) 0.69773(7) 0.13371(11) 0.0249(2) Uani 1 1 d .
H4 H 1.4246 0.7472 0.1258 0.030 Uiso 1 1 calc R
C5 C 1.51177(9) 0.67522(9) 0.18278(10) 0.0274(3) Uani 1 1 d .
H5 H 1.5516 0.7095 0.2083 0.033 Uiso 1 1 calc R
C6 C 1.52885(8) 0.60267(9) 0.19448(10) 0.0259(2) Uani 1 1 d .
H6 H 1.5802 0.5875 0.2282 0.031 Uiso 1 1 calc R
C7 C 1.47061(7) 0.55222(7) 0.15661(9) 0.01925(19) Uani 1 1 d .
H7 H 1.4824 0.5028 0.1644 0.023 Uiso 1 1 calc R
C8 C 1.35143(6) 0.42191(6) 0.08357(7) 0.01356(15) Uani 1 1 d .
C9 C 1.32069(8) 0.38124(6) 0.14835(9) 0.01879(18) Uani 1 1 d .
H9 H 1.2850 0.4023 0.1840 0.023 Uiso 1 1 calc R
C10 C 1.34237(9) 0.30952(7) 0.16074(11) 0.0246(2) Uani 1 1 d .
H10 H 1.3214 0.2820 0.2050 0.030 Uiso 1 1 calc R
C11 C 1.39436(9) 0.27806(7) 0.10898(10) 0.0241(2) Uani 1 1 d .
H11 H 1.4079 0.2289 0.1168 0.029 Uiso 1 1 calc R
C12 C 1.42650(9) 0.31875(7) 0.04554(9) 0.0233(2) Uani 1 1 d .
H12 H 1.4629 0.2976 0.0108 0.028 Uiso 1 1 calc R
C13 C 1.40540(8) 0.39054(7) 0.03286(8) 0.01888(18) Uani 1 1 d .
H13 H 1.4277 0.4183 -0.0103 0.023 Uiso 1 1 calc R
C14 C 1.31426(6) 0.51830(5) -0.06470(7) 0.01262(14) Uani 1 1 d .
C15 C 1.36162(6) 0.56614(6) -0.10645(7) 0.01429(15) Uani 1 1 d .
H15 H 1.3983 0.5973 -0.0686 0.017 Uiso 1 1 calc R
C16 C 1.35646(7) 0.56933(6) -0.20180(8) 0.01549(16) Uani 1 1 d .
C17 C 1.30096(7) 0.52472(6) -0.25846(7) 0.01606(16) Uani 1 1 d .
H17 H 1.2955 0.5272 -0.3234 0.019 Uiso 1 1 calc R
C18 C 1.25425(6) 0.47705(6) -0.21862(7) 0.01362(15) Uani 1 1 d .
C19 C 1.18988(6) 0.42367(6) -0.25947(7) 0.01443(15) Uani 1 1 d .
C20 C 1.10426(6) 0.45543(6) -0.27430(7) 0.01469(16) Uani 1 1 d .
C21 C 1.05774(6) 0.41757(6) -0.22159(7) 0.01327(15) Uani 1 1 d .
C22 C 1.18478(6) 0.37585(6) -0.17364(7) 0.01388(15) Uani 1 1 d .
C23 C 1.26238(6) 0.47350(6) -0.12374(7) 0.01251(14) Uani 1 1 d .
C24 C 1.41151(8) 0.61872(7) -0.24329(9) 0.0221(2) Uani 1 1 d .
H24A H 1.4600 0.5925 -0.2535 0.033 Uiso 1 1 calc R
H24B H 1.4283 0.6586 -0.2013 0.033 Uiso 1 1 calc R
H24C H 1.3819 0.6371 -0.3020 0.033 Uiso 1 1 calc R
C25 C 1.20812(8) 0.38418(7) -0.34358(8) 0.0209(2) Uani 1 1 d .
H25A H 1.2062 0.4178 -0.3945 0.031 Uiso 1 1 calc R
H25B H 1.1672 0.3467 -0.3613 0.031 Uiso 1 1 calc R
H25C H 1.2626 0.3626 -0.3289 0.031 Uiso 1 1 calc R
C26 C 1.23154(7) 0.30680(6) -0.15943(9) 0.01942(19) Uani 1 1 d .
H26A H 1.2254 0.2858 -0.1005 0.029 Uiso 1 1 calc R
H26B H 1.2896 0.3159 -0.1593 0.029 Uiso 1 1 calc R
H26C H 1.2102 0.2736 -0.2092 0.029 Uiso 1 1 calc R
C27 C 1.07091(7) 0.51292(7) -0.32675(8) 0.01896(19) Uani 1 1 d .
H27 H 1.1027 0.5388 -0.3627 0.023 Uiso 1 1 calc R
C28 C 1.01613(6) 0.64885(6) 0.05363(7) 0.01379(15) Uani 1 1 d .
C29 C 0.96133(7) 0.60262(6) -0.00009(8) 0.01671(17) Uani 1 1 d .
H29 H 0.9607 0.5536 0.0160 0.020 Uiso 1 1 calc R
C30 C 0.90777(8) 0.62745(7) -0.07676(9) 0.0217(2) Uani 1 1 d .
H30 H 0.8704 0.5957 -0.1126 0.026 Uiso 1 1 calc R
C31 C 0.90916(9) 0.69915(8) -0.10086(11) 0.0278(3) Uani 1 1 d .
H31 H 0.8726 0.7164 -0.1532 0.033 Uiso 1 1 calc R
C32 C 0.96421(10) 0.74553(8) -0.04830(11) 0.0280(3) Uani 1 1 d .
H32 H 0.9653 0.7944 -0.0651 0.034 Uiso 1 1 calc R
C33 C 1.01759(8) 0.72057(6) 0.02874(9) 0.02015(19) Uani 1 1 d .
H33 H 1.0550 0.7524 0.0644 0.024 Uiso 1 1 calc R
C34 C 1.12468(7) 0.69043(6) 0.21746(8) 0.01584(16) Uani 1 1 d .
C35 C 1.07203(8) 0.73321(8) 0.25771(11) 0.0256(3) Uani 1 1 d .
H35 H 1.0169 0.7189 0.2553 0.031 Uiso 1 1 calc R
C36 C 1.10003(10) 0.79665(9) 0.30125(14) 0.0347(4) Uani 1 1 d .
H36 H 1.0636 0.8262 0.3270 0.042 Uiso 1 1 calc R
C37 C 1.18114(11) 0.81684(10) 0.30711(16) 0.0406(5) Uani 1 1 d .
H37 H 1.2001 0.8605 0.3361 0.049 Uiso 1 1 calc R
C38 C 1.23465(10) 0.77314(10) 0.27058(16) 0.0413(5) Uani 1 1 d .
H38 H 1.2906 0.7860 0.2770 0.050 Uiso 1 1 calc R
C39 C 1.20644(8) 0.71053(8) 0.22463(11) 0.0262(3) Uani 1 1 d .
H39 H 1.2428 0.6815 0.1982 0.031 Uiso 1 1 calc R
C40 C 1.02321(6) 0.56495(6) 0.21816(7) 0.01347(15) Uani 1 1 d .
C41 C 1.05554(7) 0.50599(7) 0.27196(8) 0.01767(17) Uani 1 1 d .
H41 H 1.1103 0.4919 0.2713 0.021 Uiso 1 1 calc R
C42 C 1.01039(7) 0.46751(7) 0.32619(9) 0.0213(2) Uani 1 1 d .
C43 C 1.04830(9) 0.40515(10) 0.38293(14) 0.0351(4) Uani 1 1 d .
H43A H 1.1038 0.3971 0.3715 0.053 Uiso 1 1 calc R
H43B H 1.0152 0.3623 0.3659 0.053 Uiso 1 1 calc R
H43C H 1.0506 0.4155 0.4482 0.053 Uiso 1 1 calc R
C1S C 1.37004(9) 0.42271(9) 0.44146(11) 0.0282(3) Uani 1 1 d .
H1S H 1.3527 0.4698 0.4127 0.034 Uiso 1 1 calc R
Cl1S Cl 1.41239(4) 0.43677(3) 0.55825(3) 0.04081(10) Uani 1 1 d .
Cl2S Cl 1.28388(3) 0.36727(3) 0.43088(4) 0.04464(11) Uani 1 1 d .
Cl3S Cl 1.44332(4) 0.38608(6) 0.38538(4) 0.0769(3) Uani 1 1 d .
C2S C 1.24856(11) 0.63200(10) 0.45529(12) 0.0333(3) Uani 1 1 d .
H2S H 1.2291 0.6432 0.3889 0.040 Uiso 1 1 calc R
Cl4S Cl 1.21985(5) 0.70146(5) 0.52163(8) 0.0829(3) Uani 1 1 d .
Cl5S Cl 1.20477(4) 0.55040(3) 0.48125(3) 0.04476(11) Uani 1 1 d .
Cl6S Cl 1.35561(3) 0.62529(3) 0.47641(4) 0.04503(11) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Rh1 P1 90.27(3) . .
C1 Rh1 P2 89.58(3) . .
P1 Rh1 P2 167.857(10) . .
C1 Rh1 Cl1 176.46(3) . .
P1 Rh1 Cl1 87.899(10) . .
P2 Rh1 Cl1 92.847(10) . .
C2 P1 C14 103.16(5) . .
C2 P1 C8 108.17(5) . .
C14 P1 C8 101.43(5) . .
C2 P1 Rh1 107.07(3) . .
C14 P1 Rh1 116.09(3) . .
C8 P1 Rh1 119.58(3) . .
O1 C1 Rh1 178.16(10) . .
C34 P2 C28 103.09(5) . .
C34 P2 C40 105.23(5) . .
C28 P2 C40 104.27(5) . .
C34 P2 Rh1 111.03(4) . .
C28 P2 Rh1 113.06(3) . .
C40 P2 Rh1 118.71(4) . .
C7 C2 C3 119.58(10) . .
C7 C2 P1 123.37(9) . .
C3 C2 P1 117.03(8) . .
C23 O2 C22 107.23(8) . .
C4 C3 C2 120.32(12) . .
C21 O3 C22 106.64(8) . .
C3 C4 C5 119.74(13) . .
C6 C5 C4 120.20(12) . .
C5 C6 C7 120.03(13) . .
C2 C7 C6 120.13(12) . .
C9 C8 C13 119.44(10) . .
C9 C8 P1 119.91(8) . .
C13 C8 P1 120.42(8) . .
C8 C9 C10 119.91(11) . .
C11 C10 C9 120.60(12) . .
C10 C11 C12 119.72(12) . .
C11 C12 C13 120.11(12) . .
C12 C13 C8 120.19(11) . .
C23 C14 C15 116.12(9) . .
C23 C14 P1 118.61(7) . .
C15 C14 P1 125.24(8) . .
C16 C15 C14 122.27(10) . .
C15 C16 C17 119.29(10) . .
C15 C16 C24 120.47(11) . .
C17 C16 C24 120.21(10) . .
C18 C17 C16 119.23(10) . .
C17 C18 C23 120.26(10) . .
C17 C18 C19 132.02(10) . .
C23 C18 C19 107.72(9) . .
C18 C19 C20 112.02(9) . .
C18 C19 C25 114.58(9) . .
C20 C19 C25 113.13(9) . .
C18 C19 C22 101.17(8) . .
C20 C19 C22 98.74(8) . .
C25 C19 C22 115.61(10) . .
C27 C20 C21 120.37(10) . .
C27 C20 C19 130.84(10) . .
C21 C20 C19 108.77(9) . .
O3 C21 C20 112.18(9) . .
O3 C21 C40 125.10(9) . 3_765
C20 C21 C40 122.72(10) . 3_765
O3 C22 O2 107.47(8) . .
O3 C22 C26 109.08(9) . .
O2 C22 C26 107.73(9) . .
O3 C22 C19 107.46(8) . .
O2 C22 C19 104.39(8) . .
C26 C22 C19 120.04(9) . .
O2 C23 C18 113.45(9) . .
O2 C23 C14 123.80(9) . .
C18 C23 C14 122.75(9) . .
C20 C27 C42 119.21(10) . 3_765
C33 C28 C29 119.26(10) . .
C33 C28 P2 122.19(9) . .
C29 C28 P2 118.44(8) . .
C30 C29 C28 120.78(11) . .
C29 C30 C31 119.67(12) . .
C30 C31 C32 119.98(12) . .
C33 C32 C31 120.24(13) . .
C32 C33 C28 120.07(12) . .
C39 C34 C35 119.34(11) . .
C39 C34 P2 118.99(9) . .
C35 C34 P2 121.57(9) . .
C36 C35 C34 120.32(12) . .
C37 C36 C35 120.03(13) . .
C36 C37 C38 119.95(14) . .
C37 C38 C39 120.26(14) . .
C38 C39 C34 120.01(12) . .
C21 C40 C41 115.71(9) 3_765 .
C21 C40 P2 125.27(8) 3_765 .
C41 C40 P2 119.02(8) . .
C42 C41 C40 122.70(10) . .
C41 C42 C27 119.28(11) . 3_765
C41 C42 C43 120.44(12) . .
C27 C42 C43 120.28(11) 3_765 .
Cl3S C1S Cl2S 110.90(10) . .
Cl3S C1S Cl1S 109.82(9) . .
Cl2S C1S Cl1S 110.42(9) . .
Cl4S C2S Cl6S 109.02(10) . .
Cl4S C2S Cl5S 110.86(11) . .
Cl6S C2S Cl5S 110.16(11) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Rh1 C1 1.8114(11) .
Rh1 P1 2.3161(3) .
Rh1 P2 2.3349(3) .
Rh1 Cl1 2.3792(3) .
P1 C2 1.8192(11) .
P1 C14 1.8227(10) .
P1 C8 1.8251(11) .
C1 O1 1.1519(14) .
P2 C34 1.8183(11) .
P2 C28 1.8269(11) .
P2 C40 1.8268(11) .
C2 C7 1.3939(16) .
C2 C3 1.4046(16) .
O2 C23 1.3687(13) .
O2 C22 1.4665(13) .
C3 C4 1.3909(18) .
O3 C21 1.3825(13) .
O3 C22 1.4142(13) .
C4 C5 1.397(2) .
C5 C6 1.394(2) .
C6 C7 1.3958(18) .
C8 C9 1.3942(16) .
C8 C13 1.4013(15) .
C9 C10 1.3953(18) .
C10 C11 1.388(2) .
C11 C12 1.391(2) .
C12 C13 1.3947(18) .
C14 C23 1.3920(15) .
C14 C15 1.4093(14) .
C15 C16 1.4003(15) .
C16 C17 1.4041(17) .
C16 C24 1.5099(16) .
C17 C18 1.3853(15) .
C18 C23 1.3886(14) .
C18 C19 1.5086(15) .
C19 C20 1.5221(15) .
C19 C25 1.5267(15) .
C19 C22 1.5704(15) .
C20 C27 1.3835(16) .
C20 C21 1.3908(15) .
C21 C40 1.3958(14) 3_765
C22 C26 1.5051(16) .
C27 C42 1.4030(17) 3_765
C28 C33 1.3954(16) .
C28 C29 1.3960(16) .
C29 C30 1.3888(17) .
C30 C31 1.392(2) .
C31 C32 1.392(2) .
C32 C33 1.3920(19) .
C34 C39 1.3966(17) .
C34 C35 1.3991(17) .
C35 C36 1.3916(19) .
C36 C37 1.389(2) .
C37 C38 1.390(2) .
C38 C39 1.394(2) .
C40 C21 1.3958(14) 3_765
C40 C41 1.4101(16) .
C41 C42 1.3968(17) .
C42 C27 1.4030(17) 3_765
C42 C43 1.5086(19) .
C1S Cl3S 1.7375(16) .
C1S Cl2S 1.7540(17) .
C1S Cl1S 1.7637(16) .
C2S Cl4S 1.750(2) .
C2S Cl6S 1.7551(19) .
C2S Cl5S 1.767(2) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C1 Rh1 P1 C2 124.04(5) . .
P2 Rh1 P1 C2 34.79(6) . .
Cl1 Rh1 P1 C2 -58.98(4) . .
C1 Rh1 P1 C14 9.48(5) . .
P2 Rh1 P1 C14 -79.77(6) . .
Cl1 Rh1 P1 C14 -173.54(4) . .
C1 Rh1 P1 C8 -112.63(5) . .
P2 Rh1 P1 C8 158.12(6) . .
Cl1 Rh1 P1 C8 64.35(4) . .
P1 Rh1 C1 O1 82(3) . .
P2 Rh1 C1 O1 -111(3) . .
Cl1 Rh1 C1 O1 23(3) . .
C1 Rh1 P2 C34 -125.13(5) . .
P1 Rh1 P2 C34 -35.81(7) . .
Cl1 Rh1 P2 C34 57.44(4) . .
C1 Rh1 P2 C28 -9.83(5) . .
P1 Rh1 P2 C28 79.50(6) . .
Cl1 Rh1 P2 C28 172.74(4) . .
C1 Rh1 P2 C40 112.77(5) . .
P1 Rh1 P2 C40 -157.91(5) . .
Cl1 Rh1 P2 C40 -64.66(4) . .
C14 P1 C2 C7 -107.93(10) . .
C8 P1 C2 C7 -1.02(11) . .
Rh1 P1 C2 C7 129.09(9) . .
C14 P1 C2 C3 74.08(10) . .
C8 P1 C2 C3 -179.01(9) . .
Rh1 P1 C2 C3 -48.89(9) . .
C7 C2 C3 C4 0.65(18) . .
P1 C2 C3 C4 178.71(10) . .
C2 C3 C4 C5 -0.5(2) . .
C3 C4 C5 C6 -0.1(2) . .
C4 C5 C6 C7 0.4(2) . .
C3 C2 C7 C6 -0.30(18) . .
P1 C2 C7 C6 -178.23(10) . .
C5 C6 C7 C2 -0.2(2) . .
C2 P1 C8 C9 107.93(10) . .
C14 P1 C8 C9 -143.96(10) . .
Rh1 P1 C8 C9 -14.86(11) . .
C2 P1 C8 C13 -77.58(10) . .
C14 P1 C8 C13 30.53(10) . .
Rh1 P1 C8 C13 159.62(8) . .
C13 C8 C9 C10 -1.39(19) . .
P1 C8 C9 C10 173.15(11) . .
C8 C9 C10 C11 -0.1(2) . .
C9 C10 C11 C12 1.4(2) . .
C10 C11 C12 C13 -1.1(2) . .
C11 C12 C13 C8 -0.3(2) . .
C9 C8 C13 C12 1.60(18) . .
P1 C8 C13 C12 -172.92(10) . .
C2 P1 C14 C23 175.72(8) . .
C8 P1 C14 C23 63.76(9) . .
Rh1 P1 C14 C23 -67.52(9) . .
C2 P1 C14 C15 -5.90(10) . .
C8 P1 C14 C15 -117.86(9) . .
Rh1 P1 C14 C15 110.86(9) . .
C23 C14 C15 C16 0.71(15) . .
P1 C14 C15 C16 -177.71(8) . .
C14 C15 C16 C17 1.55(16) . .
C14 C15 C16 C24 -176.81(11) . .
C15 C16 C17 C18 -1.88(16) . .
C24 C16 C17 C18 176.49(11) . .
C16 C17 C18 C23 -0.04(16) . .
C16 C17 C18 C19 179.18(11) . .
C17 C18 C19 C20 -91.54(14) . .
C23 C18 C19 C20 87.76(11) . .
C17 C18 C19 C25 39.08(17) . .
C23 C18 C19 C25 -141.63(10) . .
C17 C18 C19 C22 164.17(11) . .
C23 C18 C19 C22 -16.53(11) . .
C18 C19 C20 C27 59.63(15) . .
C25 C19 C20 C27 -71.72(16) . .
C22 C19 C20 C27 165.51(12) . .
C18 C19 C20 C21 -118.58(10) . .
C25 C19 C20 C21 110.07(11) . .
C22 C19 C20 C21 -12.70(11) . .
C22 O3 C21 C20 17.23(12) . .
C22 O3 C21 C40 -162.48(10) . 3_765
C27 C20 C21 O3 179.97(10) . .
C19 C20 C21 O3 -1.60(12) . .
C27 C20 C21 C40 -0.31(17) . 3_765
C19 C20 C21 C40 178.12(10) . 3_765
C21 O3 C22 O2 86.62(10) . .
C21 O3 C22 C26 -156.84(9) . .
C21 O3 C22 C19 -25.23(10) . .
C23 O2 C22 O3 -136.90(9) . .
C23 O2 C22 C26 105.69(10) . .
C23 O2 C22 C19 -22.97(10) . .
C18 C19 C22 O3 137.48(8) . .
C20 C19 C22 O3 22.84(10) . .
C25 C19 C22 O3 -98.12(10) . .
C18 C19 C22 O2 23.55(10) . .
C20 C19 C22 O2 -91.09(9) . .
C25 C19 C22 O2 147.95(9) . .
C18 C19 C22 C26 -97.22(11) . .
C20 C19 C22 C26 148.14(10) . .
C25 C19 C22 C26 27.18(14) . .
C22 O2 C23 C18 13.22(12) . .
C22 O2 C23 C14 -166.75(9) . .
C17 C18 C23 O2 -177.51(10) . .
C19 C18 C23 O2 3.09(12) . .
C17 C18 C23 C14 2.46(16) . .
C19 C18 C23 C14 -176.93(9) . .
C15 C14 C23 O2 177.24(9) . .
P1 C14 C23 O2 -4.23(14) . .
C15 C14 C23 C18 -2.73(15) . .
P1 C14 C23 C18 175.80(8) . .
C21 C20 C27 C42 -0.06(18) . 3_765
C19 C20 C27 C42 -178.10(12) . 3_765
C34 P2 C28 C33 19.44(11) . .
C40 P2 C28 C33 129.15(10) . .
Rh1 P2 C28 C33 -100.53(10) . .
C34 P2 C28 C29 -164.42(9) . .
C40 P2 C28 C29 -54.70(10) . .
Rh1 P2 C28 C29 75.62(9) . .
C33 C28 C29 C30 -0.99(17) . .
P2 C28 C29 C30 -177.25(10) . .
C28 C29 C30 C31 0.6(2) . .
C29 C30 C31 C32 0.2(2) . .
C30 C31 C32 C33 -0.4(3) . .
C31 C32 C33 C28 0.0(2) . .
C29 C28 C33 C32 0.70(19) . .
P2 C28 C33 C32 176.82(11) . .
C28 P2 C34 C39 -113.18(12) . .
C40 P2 C34 C39 137.81(11) . .
Rh1 P2 C34 C39 8.16(12) . .
C28 P2 C34 C35 63.32(12) . .
C40 P2 C34 C35 -45.68(13) . .
Rh1 P2 C34 C35 -175.33(11) . .
C39 C34 C35 C36 2.6(2) . .
P2 C34 C35 C36 -173.92(14) . .
C34 C35 C36 C37 -1.8(3) . .
C35 C36 C37 C38 -0.9(4) . .
C36 C37 C38 C39 2.7(4) . .
C37 C38 C39 C34 -1.9(3) . .
C35 C34 C39 C38 -0.8(3) . .
P2 C34 C39 C38 175.81(16) . .
C34 P2 C40 C21 80.33(10) . 3_765
C28 P2 C40 C21 -27.82(11) . 3_765
Rh1 P2 C40 C21 -154.70(8) . 3_765
C34 P2 C40 C41 -99.84(10) . .
C28 P2 C40 C41 152.01(9) . .
Rh1 P2 C40 C41 25.13(10) . .
C21 C40 C41 C42 -0.60(18) 3_765 .
P2 C40 C41 C42 179.56(10) . .
C40 C41 C42 C27 1.0(2) . 3_765
C40 C41 C42 C43 -179.56(14) . .
