Information card for entry 7027496

Structure parameters

• Common name: [{C6H4CH2NMe2}Pd{OC(Ph)NH}2Pd{C6H4CH2NMe2}]
• Formula: C32 H36 N4 O2 Pd2
• Calculated formula: C32 H36 N4 O2 Pd2
• SMILES: [Pd]12(NC(c3ccccc3)=[O][Pd]3(NC(=[O]1)c1ccccc1)[N](Cc1c3cccc1)(C)C)[N](Cc1c2cccc1)(C)C
• Title of publication: Reactivity of hydroxo complexes of palladium(II) towards nitriles: formation of carboxamide and imino ether derivatives of palladium(II)
• Authors of publication: Ruiz, José; Cutillas, Natalia; Rodríguez, Venancio; Sampedro, José; López, Gregorio; Chaloner, Penny A.; Hitchcock, Peter B.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1999
• Journal issue: 17
• Pages of publication: 2939
• a: 15.487 ± 0.002 Å
• b: 10.811 ± 0.004 Å
• c: 18.249 ± 0.003 Å
• α: 90°
• β: 91.54 ± 0.01°
• γ: 90°
• Cell volume: 3054.3 ± 1.3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0699
• Residual factor for significantly intense reflections: 0.0404
• Weighted residual factors for all reflections: 0.1034
• Weighted residual factors for significantly intense reflections: 0.0882
• Goodness-of-fit parameter for all reflections: 0.999
• Goodness-of-fit parameter for significantly intense reflections: 1.028
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No