Information card for entry 7028926

Structure parameters

• Formula: C78 H84 F6 N2 O6 P4 Si
• Calculated formula: C78 H84 F6 N2 O6 P4 Si
• SMILES: c1(ccccc1)P(=N[P+](c1ccccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1.F[Si](F)(F)(F)([F-])[F-].OC.OC.OC.c1(ccccc1)P(c1ccccc1)(=N[P+](c1ccccc1)(c1ccccc1)c1ccccc1)c1ccccc1.OC.OC.OC
• Title of publication: Bis(triphenyl-λ(5)-phosphanylidene)ammonium fluoride: a reactive fluoride source to access the hypervalent silicates [MenSiF5-n](-) (n = 0-3).
• Authors of publication: Bolli, Christoph; Gellhaar, Jorit; Jenne, Carsten; Keßler, Mathias; Scherer, Harald; Seeger, Helene; Uzun, Rabiya
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2014
• Journal volume: 43
• Journal issue: 11
• Pages of publication: 4326 - 4334
• a: 11.131 ± 0.002 Å
• b: 12.139 ± 0.002 Å
• c: 26.696 ± 0.005 Å
• α: 90°
• β: 91.74 ± 0.03°
• γ: 90°
• Cell volume: 3605.5 ± 1.1 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0641
• Residual factor for significantly intense reflections: 0.0516
• Weighted residual factors for significantly intense reflections: 0.1117
• Weighted residual factors for all reflections included in the refinement: 0.119
• Goodness-of-fit parameter for all reflections included in the refinement: 1.107
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No