Information card for entry 7028928

Structure parameters

• Formula: C38 H35 F5 N O0.5 P2 Si
• Calculated formula: C38 H35 F5 N O0.5 P2 Si
• Title of publication: Bis(triphenyl-λ(5)-phosphanylidene)ammonium fluoride: a reactive fluoride source to access the hypervalent silicates [MenSiF5-n](-) (n = 0-3).
• Authors of publication: Bolli, Christoph; Gellhaar, Jorit; Jenne, Carsten; Keßler, Mathias; Scherer, Harald; Seeger, Helene; Uzun, Rabiya
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2014
• Journal volume: 43
• Journal issue: 11
• Pages of publication: 4326 - 4334
• a: 11.7234 ± 0.0002 Å
• b: 11.7602 ± 0.0002 Å
• c: 14.133 ± 0.0002 Å
• α: 68.9697 ± 0.0008°
• β: 69.5406 ± 0.0008°
• γ: 70.8268 ± 0.0008°
• Cell volume: 1657.46 ± 0.05 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0576
• Residual factor for significantly intense reflections: 0.0428
• Weighted residual factors for significantly intense reflections: 0.1089
• Weighted residual factors for all reflections included in the refinement: 0.1179
• Goodness-of-fit parameter for all reflections included in the refinement: 1.032
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No