Information card for entry 7029584

Structure parameters

• Formula: C90 H48 B2 Cl4 F48 N10 O4 Rh2
• Calculated formula: C90 H48 B2 Cl4 F48 N10 O4 Rh2
• Title of publication: Bi- and tri-metallic Rh and Ir complexes containing click derived bis- and tris-(pyrazolyl-1,2,3-triazolyl) N-N' donor ligands and their application as catalysts for the dihydroalkoxylation of alkynes.
• Authors of publication: Vuong, Khuong Q.; Wong, Chin M.; Bhadbhade, Mohan; Messerle, Barbara A.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2014
• Journal volume: 43
• Journal issue: 20
• Pages of publication: 7540 - 7553
• a: 12.5978 ± 0.0009 Å
• b: 13.8067 ± 0.001 Å
• c: 15.8805 ± 0.0011 Å
• α: 91.334 ± 0.003°
• β: 106.014 ± 0.003°
• γ: 108.407 ± 0.003°
• Cell volume: 2500.6 ± 0.3 ų
• Cell temperature: 170 ± 2 K
• Ambient diffraction temperature: 170 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0516
• Residual factor for significantly intense reflections: 0.0455
• Weighted residual factors for significantly intense reflections: 0.122
• Weighted residual factors for all reflections included in the refinement: 0.1292
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No