Information card for entry 7030939

Structure parameters

• Formula: C92 H87 N6 P4 Sm
• Calculated formula: C92 H87 N6 P4 Sm
• Title of publication: Differences in the cyclometalation reactivity of bisphosphinimine-supported organo-rare earth complexes.
• Authors of publication: Zamora, Matthew T.; Johnson, Kevin R. D.; Hänninen, Mikko M; Hayes, Paul G.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2014
• Journal volume: 43
• Journal issue: 28
• Pages of publication: 10739 - 10750
• a: 12.3595 ± 0.0011 Å
• b: 13.8452 ± 0.0012 Å
• c: 24.642 ± 0.002 Å
• α: 104.304 ± 0.0009°
• β: 101.221 ± 0.0009°
• γ: 95.5028 ± 0.0009°
• Cell volume: 3961.7 ± 0.6 ų
• Cell temperature: 173 K
• Ambient diffraction temperature: 173 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0487
• Residual factor for significantly intense reflections: 0.0384
• Weighted residual factors for significantly intense reflections: 0.0931
• Weighted residual factors for all reflections included in the refinement: 0.0965
• Goodness-of-fit parameter for all reflections included in the refinement: 0.993
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No