Information card for entry 7034815

Structure parameters

• Formula: C38.5 H59 B N2 P3 Rh
• Calculated formula: C38.5 H59 B N2 P3 Rh
• Title of publication: Selective B-B bond activation in an unsymmetrical diborane(4) by [(Me3P)4Rh-X] (X = Me, OtBu): a switch of mechanism?
• Authors of publication: Borner, C.; Brandhorst, K.; Kleeberg, C.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2015
• Journal volume: 44
• Journal issue: 18
• Pages of publication: 8600 - 8604
• a: 9.9185 ± 0.0001 Å
• b: 11.7946 ± 0.0002 Å
• c: 18.9805 ± 0.0002 Å
• α: 72.324 ± 0.001°
• β: 80.447 ± 0.001°
• γ: 67.981 ± 0.001°
• Cell volume: 1957.87 ± 0.05 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0524
• Residual factor for significantly intense reflections: 0.0423
• Weighted residual factors for significantly intense reflections: 0.0979
• Weighted residual factors for all reflections included in the refinement: 0.104
• Goodness-of-fit parameter for all reflections included in the refinement: 1.129
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No