Information card for entry 7035078

Structure parameters

• Formula: C32 H46 Cl4 N4 Rh2 S2
• Calculated formula: C32 H46 Cl4 N4 Rh2 S2
• SMILES: C1(=[S][Rh]2345([c]6([c]3([c]2(C)[c]5([c]46C)C)C)C)(Cl)Cl)N(C=CN1C/C=C/CN1C(=[S][Rh]2345([c]6([c]2([c]3([c]4([c]56C)C)C)C)C)(Cl)Cl)N(C=C1)C)C
• Title of publication: Synthesis of a new type of alkene metal complex using face-capping thione-alkene ligands.
• Authors of publication: Zhang, Long; Yan, Tao; Han, Ying-Feng; Hahn, F. Ekkehardt; Jin, Guo-Xin
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2015
• Journal volume: 44
• Journal issue: 19
• Pages of publication: 8797 - 8800
• a: 8.7048 ± 0.0016 Å
• b: 8.8755 ± 0.0016 Å
• c: 14.672 ± 0.003 Å
• α: 72.896 ± 0.003°
• β: 82.099 ± 0.003°
• γ: 74.103 ± 0.003°
• Cell volume: 1040 ± 0.3 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0625
• Residual factor for significantly intense reflections: 0.0491
• Weighted residual factors for significantly intense reflections: 0.1551
• Weighted residual factors for all reflections included in the refinement: 0.166
• Goodness-of-fit parameter for all reflections included in the refinement: 1.062
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No