Information card for entry 7035372

Structure parameters

• Formula: C67 H56 B Co3 F24 Mo N O7 P S
• Calculated formula: C67 H56 B Co3 F24 Mo N O7 P S
• Title of publication: P-S bond cleavage in reactions of thiophosphinidene-bridged dimolybdenum complexes with [Co2(CO)8] to give phosphinidene-bridged heterometallic derivatives.
• Authors of publication: Alvarez, Belén; Alvarez, M. Angeles; García, M Esther; Ruiz, Miguel A.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 5
• Pages of publication: 1937 - 1952
• a: 26.9844 ± 0.0004 Å
• b: 17.4241 ± 0.0002 Å
• c: 15.8536 ± 0.0002 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 7454.03 ± 0.17 ų
• Cell temperature: 123 ± 0.1 K
• Ambient diffraction temperature: 123 ± 0.1 K
• Number of distinct elements: 10
• Space group number: 33
• Hermann-Mauguin space group symbol: P n a 21
• Hall space group symbol: P 2c -2n
• Residual factor for all reflections: 0.0962
• Residual factor for significantly intense reflections: 0.0799
• Weighted residual factors for significantly intense reflections: 0.214
• Weighted residual factors for all reflections included in the refinement: 0.2309
• Goodness-of-fit parameter for all reflections included in the refinement: 1.05
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No