Information card for entry 7035537

Structure parameters

• Chemical name: trans-difluoridotetrakis(pyridine)managnese(III)pentafluorido(pyridine)silicate(IV)
• Formula: C25 H25 F7 Mn N5 Si
• Calculated formula: C25 H25 F7 Mn N5 Si
• SMILES: F[Mn]([n]1ccccc1)(F)([n]1ccccc1)([n]1ccccc1)[n]1ccccc1.F[Si](F)(F)(F)(F)[n]1ccccc1
• Title of publication: Ternary transition-metal fluoride precursors for the fluorolytic sol-gel route: new insights into speciation and decomposition.
• Authors of publication: Kohl, J.; Wiedemann, D.; Troyanov, S. I.; Palamidis, E.; Lerch, M.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2015
• Journal volume: 44
• Journal issue: 29
• Pages of publication: 13272 - 13281
• a: 21.4549 ± 0.0011 Å
• b: 10.3397 ± 0.0005 Å
• c: 11.9769 ± 0.0007 Å
• α: 90°
• β: 98.648 ± 0.005°
• γ: 90°
• Cell volume: 2626.7 ± 0.2 ų
• Cell temperature: 150 ± 0.1 K
• Ambient diffraction temperature: 150 ± 0.1 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0385
• Residual factor for significantly intense reflections: 0.0324
• Weighted residual factors for significantly intense reflections: 0.0743
• Weighted residual factors for all reflections included in the refinement: 0.0768
• Goodness-of-fit parameter for all reflections included in the refinement: 1.078
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No