Information card for entry 7036601

Structure parameters

• Formula: C27 H49 Al N P
• Calculated formula: C27 H49 Al N P
• Title of publication: Hydroalumination of alkynyl-aminophosphines as a promising tool for the synthesis of unusual phosphines: P-N bond activation, a transient phosphaallene, a zwitterionic AlP2C2 heterocycle and a masked Al/P-based frustrated Lewis pair.
• Authors of publication: Klöcker, Hans; Layh, Marcus; Hepp, Alexander; Uhl, Werner
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 5
• Pages of publication: 2031 - 2043
• a: 10.8218 ± 0.0005 Å
• b: 11.4057 ± 0.0005 Å
• c: 12.6079 ± 0.0006 Å
• α: 74.341 ± 0.001°
• β: 70.402 ± 0.001°
• γ: 84.671 ± 0.001°
• Cell volume: 1411.63 ± 0.11 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0439
• Residual factor for significantly intense reflections: 0.0387
• Weighted residual factors for significantly intense reflections: 0.109
• Weighted residual factors for all reflections included in the refinement: 0.1137
• Goodness-of-fit parameter for all reflections included in the refinement: 1.055
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No