Information card for entry 7036994

Structure parameters

• Formula: C54 H84 N6 Si4 Sm2
• Calculated formula: C54 H84 N6 Si4 Sm2
• SMILES: [C]123=[CH]4[Sm]56782([N]1([Sm]129%10(N(C3)c3c(cccc3C(C)C)C(C)C)([N]36[C]1(=[CH]2[C]19C=CC=C[C]%103=1)CN7c1c(cccc1C(C)C)C(C)C)N([Si](C)(C)C)[Si](C)(C)C)[C]18=[C]45C=CC=C1)N([Si](C)(C)C)[Si](C)(C)C
• Title of publication: Reactivity of functionalized indoles with rare-earth metal amides. Synthesis, characterization and catalytic activity of rare-earth metal complexes incorporating indolyl ligands.
• Authors of publication: Feng, Zhijun; Wei, Yun; Zhou, Shuangliu; Zhang, Guangchao; Zhu, Xiancui; Guo, Liping; Wang, Shaowu; Mu, Xiaolong
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2015
• Journal volume: 44
• Journal issue: 47
• Pages of publication: 20502 - 20513
• a: 9.814 ± 0.003 Å
• b: 15.222 ± 0.004 Å
• c: 21.286 ± 0.006 Å
• α: 73.257 ± 0.003°
• β: 86.632 ± 0.003°
• γ: 77.623 ± 0.003°
• Cell volume: 2974.3 ± 1.5 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0932
• Residual factor for significantly intense reflections: 0.0614
• Weighted residual factors for significantly intense reflections: 0.1575
• Weighted residual factors for all reflections included in the refinement: 0.1793
• Goodness-of-fit parameter for all reflections included in the refinement: 1.066
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No