Extraction and coordination studies of a carbonyl-phosphine oxide scorpionate ligand with uranyl and lanthanide(iii) nitrates: structural, spectroscopic and DFT characterization of the complexes.
Authors of publication
Matveeva, Anna G.; Vologzhanina, Anna V.; Goryunov, Evgenii I.; Aysin, Rinat R.; Pasechnik, Margarita P.; Matveev, Sergey V.; Godovikov, Ivan A.; Safiulina, Alfiya M.; Brel, Valery K.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2016
Journal volume
45
Journal issue
12
Pages of publication
5162 - 5179
a
9.8274 ± 0.0012 Å
b
11.8989 ± 0.0015 Å
c
13.0901 ± 0.0016 Å
α
70.615 ± 0.002°
β
68.839 ± 0.002°
γ
87.156 ± 0.002°
Cell volume
1342.3 ± 0.3 Å3
Cell temperature
148 ± 2 K
Ambient diffraction temperature
148 ± 2 K
Number of distinct elements
4
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0678
Residual factor for significantly intense reflections
0.0474
Weighted residual factors for significantly intense reflections
0.1117
Weighted residual factors for all reflections included in the refinement
0.1251
Goodness-of-fit parameter for all reflections included in the refinement
