Information card for entry 7038972

Structure parameters

• Formula: C98 H94 Cl4 F12 N2 P10 Pt3
• Calculated formula: C98 H94 Cl4 F12 N2 P10 Pt3
• SMILES: C(#[N]c1c(cccc1C)C)[Pt]123[P](C[P]4([Pt]51[P]1(C[P](c6ccccc6)(c6ccccc6)[Pt]5(C#[N]c5c(cccc5C)C)([P](C1)(c1ccccc1)c1ccccc1)[P](C4)(c1ccccc1)c1ccccc1)C[P]3(c1ccccc1)c1ccccc1)C[P]2(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1.[P](F)(F)(F)(F)(F)[F-].C(Cl)Cl.[P](F)(F)(F)(F)(F)[F-].C(Cl)Cl
• Title of publication: Electron-rich linear triplatinum complexes stabilized by a spinning tetraphosphine, tris(diphenylphosphinomethyl)phosphine.
• Authors of publication: Tanase, Tomoaki; Koike, Kanako; Uegaki, Miho; Hatada, Satoko; Nakamae, Kanako; Kure, Bunsho; Ura, Yasuyuki; Nakajima, Takayuki
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 17
• Pages of publication: 7209 - 7214
• a: 13.328 ± 0.004 Å
• b: 14.042 ± 0.005 Å
• c: 15.35 ± 0.005 Å
• α: 107.847 ± 0.002°
• β: 114.56 ± 0.005°
• γ: 94.641 ± 0.003°
• Cell volume: 2414.1 ± 1.4 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.0597
• Weighted residual factors for all reflections included in the refinement: 0.1447
• Goodness-of-fit parameter for all reflections included in the refinement: 1.095
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No