Information card for entry 7038987

Structure parameters

• Common name: Ni(dmpe)2(H)(BF4)
• Chemical name: Nickel(II) bis(dimethylphosphinoethane) hydride tetrafluoroborate
• Formula: C20 H32 B F4 Ni P4
• Calculated formula: C20 H32 B F4 Ni P4
• Title of publication: Solvent influence on the thermodynamics for hydride transfer from bis(diphosphine) complexes of nickel.
• Authors of publication: Connelly Robinson, Samantha J.; Zall, Christopher M.; Miller, Deanna L.; Linehan, John C.; Appel, Aaron M.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 24
• Pages of publication: 10017 - 10023
• a: 12.354 ± 0.003 Å
• b: 19.109 ± 0.003 Å
• c: 20.927 ± 0.005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4940.3 ± 1.9 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 70
• Hermann-Mauguin space group symbol: F d d d
• Hall space group symbol: -F 2uv 2vw
• Residual factor for all reflections: 0.0506
• Residual factor for significantly intense reflections: 0.0317
• Weighted residual factors for significantly intense reflections: 0.0687
• Weighted residual factors for all reflections included in the refinement: 0.0743
• Goodness-of-fit parameter for all reflections included in the refinement: 1.039
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No