Structural snapshots in the copper(ii) induced azide-nitrile cycloaddition: effects of peripheral ligand substituents on the formation of unsupported μ1,1-azido vs.μ1,4-tetrazolato bridged complexes.
Authors of publication
Sommer, Michael G.; Rechkemmer, Yvonne; Suntrup, Lisa; Hohloch, Stephan; van der Meer, Margarethe; van Slageren, Joris; Sarkar, Biprajit
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2016
Journal volume
45
Journal issue
44
Pages of publication
17770 - 17781
a
22.312 ± 0.005 Å
b
16.019 ± 0.005 Å
c
13.436 ± 0.005 Å
α
90 ± 0.005°
β
100.679 ± 0.005°
γ
90 ± 0.005°
Cell volume
4719 ± 3 Å3
Cell temperature
140 ± 2 K
Ambient diffraction temperature
140 ± 2 K
Number of distinct elements
6
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/c 1
Hall space group symbol
-P 2ybc
Residual factor for all reflections
0.1151
Residual factor for significantly intense reflections
0.0654
Weighted residual factors for significantly intense reflections
0.1529
Weighted residual factors for all reflections included in the refinement
0.2088
Goodness-of-fit parameter for all reflections included in the refinement
