B-B bond activation and NHC ring-expansion reactions of diboron(4) compounds, and accurate molecular structures of B2(NMe2)4, B2eg2, B2neop2 and B2pin2.
Authors of publication
Eck, Martin; Würtemberger-Pietsch, Sabrina; Eichhorn, Antonius; Berthel, Johannes H. J.; Bertermann, Rüdiger; Paul, Ursula S. D.; Schneider, Heidi; Friedrich, Alexandra; Kleeberg, Christian; Radius, Udo; Marder, Todd B.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2017
Journal volume
46
Journal issue
11
Pages of publication
3661 - 3680
a
7.5233 ± 0.0013 Å
b
12.07 ± 0.002 Å
c
21.443 ± 0.004 Å
α
94.556 ± 0.005°
β
92.752 ± 0.005°
γ
106.214 ± 0.005°
Cell volume
1858.8 ± 0.6 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
100 ± 2 K
Number of distinct elements
5
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0998
Residual factor for significantly intense reflections
0.0696
Weighted residual factors for significantly intense reflections
0.1403
Weighted residual factors for all reflections included in the refinement
0.1513
Goodness-of-fit parameter for all reflections included in the refinement
