Information card for entry 7042778

Structure parameters

• Formula: C24 H54 Co N3 P Si2
• Calculated formula: C24 H54 Co N3 P Si2
• SMILES: [Co]12(N(C3=C(P(=[N]2[Si](C)(C)C)(C(C)C)C(C)C)CCC3)CC[N]1(CC)CC)C[Si](C)(C)C
• Title of publication: Variable Coordination Geometries via an Amine-Tethered-Enamidophosphinimine Ligand on Cobalt
• Authors of publication: Suzuki, Tatsuya; Masuda, Hideki; Fryzuk, Michael D.
• Journal of publication: Dalton Trans.
• Year of publication: 2017
• a: 10.9373 ± 0.0005 Å
• b: 11.4001 ± 0.0005 Å
• c: 12.5228 ± 0.0006 Å
• α: 81.58 ± 0.002°
• β: 84.062 ± 0.002°
• γ: 80.956 ± 0.002°
• Cell volume: 1520.21 ± 0.12 ų
• Cell temperature: 90 K
• Ambient diffraction temperature: 90 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0537
• Residual factor for significantly intense reflections: 0.0367
• Weighted residual factors for significantly intense reflections: 0.08
• Weighted residual factors for all reflections included in the refinement: 0.0881
• Goodness-of-fit parameter for all reflections included in the refinement: 1.0251
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No