Information card for entry 7043132

Structure parameters

• Common name: Trispyridylphosphine antimony fluoride bis triflate
• Chemical name: Trispyridylphosphine antimony fluoride bis triflate
• Formula: C21 H18 F7 N5 O6 P S2 Sb
• Calculated formula: C21 H18 F7 N5 O6 P S2 Sb
• SMILES: [Sb]12(F)([n]3c(P(c4[n]1cccc4)c1[n]2cccc1)cccc3)(OS(=O)(=O)C(F)(F)F)OS(=O)(=O)C(F)(F)F.C(#N)C.N#CC
• Title of publication: Tris(2-pyridyl)phosphine as a versatile ligand for pnictogen acceptors
• Authors of publication: Suter, Riccardo; Sinclair, Hannah; Burford, Neil; McDonald, Robert; Ferguson, Michael J.; Schrader, Erik
• Journal of publication: Dalton Trans.
• Year of publication: 2017
• a: 14.1583 ± 0.0003 Å
• b: 15.6137 ± 0.0003 Å
• c: 13.3459 ± 0.0003 Å
• α: 90°
• β: 95.51 ± 0.001°
• γ: 90°
• Cell volume: 2936.66 ± 0.11 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173.05 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0511
• Residual factor for significantly intense reflections: 0.0455
• Weighted residual factors for significantly intense reflections: 0.126
• Weighted residual factors for all reflections included in the refinement: 0.1307
• Goodness-of-fit parameter for all reflections included in the refinement: 1.053
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Diffraction radiation X-ray symbol: K-L~3~
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No