Synthetic ability of dinuclear mesocates containing 1,3-bis(diazinecarboxamide)benzene bridging ligands to form complexes of increased nuclearity. Crystal structures, magnetic properties and theoretical studies.
Authors of publication
Palacios, Maria A.; Morlieras, Jessica; Herrera, Juan Manuel; Mota, Antonio J.; Brechin, Euan K.; Triki, Smail; Colacio, Enrique
Journal of publication
Dalton Trans.
Year of publication
2017
a
13.076 ± 0.003 Å
b
20.453 ± 0.004 Å
c
24.811 ± 0.005 Å
α
90°
β
96.72 ± 0.03°
γ
90°
Cell volume
6590 ± 2 Å3
Cell temperature
100 K
Ambient diffraction temperature
100 K
Number of distinct elements
5
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/c 1
Hall space group symbol
-P 2ybc
Residual factor for all reflections
0.1582
Residual factor for significantly intense reflections
0.0935
Weighted residual factors for significantly intense reflections
0.1697
Weighted residual factors for all reflections included in the refinement
0.1894
Goodness-of-fit parameter for all reflections included in the refinement
