Mono- and dinuclear Ni(i) products formed upon bromide abstraction from the Ni(i) ring-expanded NHC complex [Ni(6-Mes)(PPh<sub>3</sub>)Br].
Authors of publication
Blackaby, William J. M.; Sabater, Sara; Poulten, Rebecca C.; Page, Michael J.; Folli, Andrea; Krewald, Vera; Mahon, Mary F.; Murphy, Damien M.; Richards, Emma; Whittlesey, Michael K.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2018
Journal volume
47
Journal issue
3
Pages of publication
769 - 782
a
31.549 ± 0.0003 Å
b
10.328 ± 0.0001 Å
c
28.81 ± 0.0003 Å
α
90°
β
92.977 ± 0.001°
γ
90°
Cell volume
9374.73 ± 0.16 Å3
Cell temperature
150 ± 0.1 K
Ambient diffraction temperature
150 ± 0.1 K
Number of distinct elements
6
Space group number
15
Hermann-Mauguin space group symbol
C 1 2/c 1
Hall space group symbol
-C 2yc
Residual factor for all reflections
0.0852
Residual factor for significantly intense reflections
0.0503
Weighted residual factors for significantly intense reflections
0.1086
Weighted residual factors for all reflections included in the refinement
0.1192
Goodness-of-fit parameter for all reflections included in the refinement
