Information card for entry 7045013

Structure parameters

• Formula: C54 H75 Cl P Rh Sn
• Calculated formula: C54 H75 Cl P Rh Sn
• SMILES: [Sn]12([Rh]34567([P](c8c2cccc8)(C2CCCCC2)C2CCCCC2)[c]2(c8c1c(ccc8)c1c(cc(C(C)C)cc1C(C)C)C(C)C)[c]3([cH]4[c]5(C(C)C)[cH]6[c]72C(C)C)C(C)C)Cl
• Title of publication: Coordination chemistry of stannylene-based Lewis pairs - insertion into M-Cl and M-C bonds. From base stabilized stannylenes to bidentate ligands.
• Authors of publication: Krebs, K. M.; Freitag, S.; Maudrich, J.-J.; Schubert, H.; Sirsch, P.; Wesemann, L.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2017
• Journal volume: 47
• Journal issue: 1
• Pages of publication: 83 - 95
• a: 10.7739 ± 0.0003 Å
• b: 21.1752 ± 0.0007 Å
• c: 21.97 ± 0.0007 Å
• α: 102.27 ± 0.002°
• β: 95.204 ± 0.002°
• γ: 95.573 ± 0.002°
• Cell volume: 4842.5 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.059
• Residual factor for significantly intense reflections: 0.0323
• Weighted residual factors for significantly intense reflections: 0.0665
• Weighted residual factors for all reflections included in the refinement: 0.074
• Goodness-of-fit parameter for all reflections included in the refinement: 0.989
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No