Information card for entry 7046401

Structure parameters

• Formula: C28 H68 Cs2 N2 O2 Si4
• Calculated formula: C28 H68 Cs2 N2 O2 Si4
• Title of publication: Straightforward synthesis of rubidium bis(trimethylsilyl)amide and complexes of the alkali metal bis(trimethylsilyl)amides with weakly coordinating 2,2,5,5-tetramethyltetrahydrofuran.
• Authors of publication: Krieck, Sven; Schüler, Philipp; Görls, Helmar; Westerhausen, Matthias
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2018
• Journal volume: 47
• Journal issue: 36
• Pages of publication: 12562 - 12569
• a: 12.4061 ± 0.0004 Å
• b: 12.8719 ± 0.0004 Å
• c: 14.4174 ± 0.0004 Å
• α: 90°
• β: 111.177 ± 0.002°
• γ: 90°
• Cell volume: 2146.84 ± 0.12 ų
• Cell temperature: 133 ± 2 K
• Ambient diffraction temperature: 133 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0256
• Residual factor for significantly intense reflections: 0.0225
• Weighted residual factors for significantly intense reflections: 0.047
• Weighted residual factors for all reflections included in the refinement: 0.0484
• Goodness-of-fit parameter for all reflections included in the refinement: 1.113
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No