Information card for entry 7046821

Structure parameters

• Formula: C25 H47 Li O3 P2 Si
• Calculated formula: C25 H47 Li O3 P2 Si
• Title of publication: Reactions of (Ph)tBuP-P(SiMe₃)Li·3THF with [(PNP)TiCl₂] and [^MeNacNacTiCl₂·THF]: synthesis of first PNP titanium(iv) complex with the phosphanylphosphinidene ligand [(PNP)Ti(Cl){η²-P-P(Ph)tBu}].
• Authors of publication: Ziółkowska, Aleksandra; Szynkiewicz, Natalia; Wiśniewska, Aleksandra; Pikies, Jerzy; Ponikiewski, Łukasz
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2018
• Journal volume: 47
• Journal issue: 29
• Pages of publication: 9733 - 9741
• a: 10.0158 ± 0.0006 Å
• b: 15.7842 ± 0.0012 Å
• c: 18.828 ± 0.0012 Å
• α: 90°
• β: 96.404 ± 0.005°
• γ: 90°
• Cell volume: 2958 ± 0.3 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 6
• Space group number: 9
• Hermann-Mauguin space group symbol: C 1 c 1
• Hall space group symbol: C -2yc
• Residual factor for all reflections: 0.2226
• Residual factor for significantly intense reflections: 0.0898
• Weighted residual factors for significantly intense reflections: 0.1735
• Weighted residual factors for all reflections included in the refinement: 0.2268
• Goodness-of-fit parameter for all reflections included in the refinement: 1.027
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No