Sterically demanding methoxy and methyl groups in ruthenium complexes lead to enhanced quantum yields for blue light triggered photodissociation.
Authors of publication
Qu, Fengrui; Martinez, Kristina; Arcidiacono, Ashley M.; Park, Seungjo; Zeller, Matthias; Schmehl, Russell H.; Paul, Jared J.; Kim, Yonghyun; Papish, Elizabeth T.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2018
Journal volume
47
Journal issue
44
Pages of publication
15685 - 15693
a
10.1716 ± 0.0004 Å
b
20.3819 ± 0.0009 Å
c
16.9731 ± 0.0007 Å
α
90°
β
91.121 ± 0.002°
γ
90°
Cell volume
3518.1 ± 0.3 Å3
Cell temperature
223 ± 2 K
Ambient diffraction temperature
223 ± 2 K
Number of distinct elements
6
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for all reflections
0.0308
Residual factor for significantly intense reflections
0.0249
Weighted residual factors for significantly intense reflections
0.0638
Weighted residual factors for all reflections included in the refinement
0.0681
Goodness-of-fit parameter for all reflections included in the refinement
