Stoichiometric control: 8- and 10-coordinate Ln(hfac)<sub>3</sub>(bpy) and Ln(hfac)<sub>3</sub>(bpy)<sub>2</sub> complexes of the early lanthanides La-Sm.
Authors of publication
Fatila, Elisabeth M.; Maahs, Adam C.; Hetherington, Erin E.; Cooper, Brandon J.; Cooper, Riley E.; Daanen, Nick N.; Jennings, Michael; Skrabalak, Sara E.; Preuss, Kathryn E.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2018
Journal volume
47
Journal issue
45
Pages of publication
16232 - 16241
a
12.04 ± 0.002 Å
b
15.83 ± 0.003 Å
c
17.855 ± 0.004 Å
α
78.4 ± 0.03°
β
76.3 ± 0.03°
γ
72.7 ± 0.03°
Cell volume
3125.2 ± 1.2 Å3
Cell temperature
150 ± 2 K
Ambient diffraction temperature
150 ± 2 K
Number of distinct elements
6
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0839
Residual factor for significantly intense reflections
0.0554
Weighted residual factors for significantly intense reflections
0.1262
Weighted residual factors for all reflections included in the refinement
0.1428
Goodness-of-fit parameter for all reflections included in the refinement
