Thermal dehydrochlorination in the 4-fluoroaniline-trichloroborane system: identification of reactive intermediates involved in the formation of B,B',B''-trichloro-N,N',N''-tri((4-fluoro)phenyl)borazine.
Authors of publication
Hahn, Jennifer; Krieg, Matthias; Keck, Constanze; Maichle-Mössmer, Cäcilia; Fink, Reinhold F.; Bettinger, Holger F.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2018
Journal volume
47
Journal issue
48
Pages of publication
17304 - 17316
a
8.377 ± 0.007 Å
b
10.109 ± 0.009 Å
c
10.309 ± 0.009 Å
α
99.27 ± 0.02°
β
112.227 ± 0.016°
γ
90.341 ± 0.017°
Cell volume
795.4 ± 1.2 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
100 ± 2 K
Number of distinct elements
5
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0505
Residual factor for significantly intense reflections
0.0402
Weighted residual factors for significantly intense reflections
0.0977
Weighted residual factors for all reflections included in the refinement
0.1037
Goodness-of-fit parameter for all reflections included in the refinement
