Information card for entry 7049808

Structure parameters

• Formula: C47.98 H69 Li2 N2 O4 S4 U
• Calculated formula: C47.986 H69 Li2 N2 O4 S4 U
• Title of publication: Oxidation of uranium(iv) mixed imido-amido complexes with PhEEPh and to generate uranium(vi) bis(imido) dichalcogenolates, U(NR)₂(EPh)₂(L)₂.
• Authors of publication: Tomson, Neil C.; Anderson, Nickolas H.; Tondreau, Aaron M.; Scott, Brian L.; Boncella, James M.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2019
• Journal volume: 48
• Journal issue: 29
• Pages of publication: 10865 - 10873
• a: 10.79 ± 0.002 Å
• b: 22.803 ± 0.005 Å
• c: 21.399 ± 0.005 Å
• α: 90°
• β: 99.345 ± 0.002°
• γ: 90°
• Cell volume: 5195.2 ± 1.9 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0918
• Residual factor for significantly intense reflections: 0.0486
• Weighted residual factors for significantly intense reflections: 0.0971
• Weighted residual factors for all reflections included in the refinement: 0.1124
• Goodness-of-fit parameter for all reflections included in the refinement: 0.999
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No