Alternative (κ<sup>1</sup>-N:η<sup>6</sup>-arene vs.κ<sup>2</sup>-N,N) coordination of a sterically demanding amidinate ligand: are size and electronic structure of the Ln ion decisive factors?
Authors of publication
Tolpygin, Aleksei O.; Shavyrin, Andrei S.; Cherkasov, Anton V.; Fukin, Georgy K.; Del Rosal, Iker; Maron, Laurent; Trifonov, Alexander A.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2019
Journal volume
48
Journal issue
23
Pages of publication
8317 - 8326
a
10.5855 ± 0.0001 Å
b
11.9856 ± 0.0001 Å
c
16.2221 ± 0.0002 Å
α
81.575 ± 0.001°
β
87.14 ± 0.001°
γ
77.417 ± 0.001°
Cell volume
1986.7 ± 0.04 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
100 ± 2 K
Number of distinct elements
5
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0272
Residual factor for significantly intense reflections
0.0232
Weighted residual factors for significantly intense reflections
0.0503
Weighted residual factors for all reflections included in the refinement
0.0521
Goodness-of-fit parameter for all reflections included in the refinement
