Information card for entry 7052522

Structure parameters

• Common name: trans-[PtCl2{NH=C(Et)ON=C(Me)C(Me)(=O)}2]
• Formula: C14 H24 Cl2 N4 O4 Pt
• Calculated formula: C14 H24 Cl2 N4 O4 Pt
• SMILES: [Pt]([NH]=C(CC)O/N=C(C)/C(=O)C)([NH]=C(CC)O/N=C(C)/C(=O)C)(Cl)Cl
• Title of publication: Platinum(iv)-mediated coupling of dione monoximes and nitriles: a novel reactivity pattern of the classic oxime-based chelating ligands
• Authors of publication: Makarycheva-Mikhailova, Anastassiya V.; Haukka, Matti; Bokach, Nadezhda A.; Garnovskii, Dmitrii A.; Galanski, Markus; Keppler, Bernhard K.; Pombeiro, Armando J. L.; Kukushkin, Vadim Yu.
• Journal of publication: New Journal of Chemistry
• Year of publication: 2002
• Journal volume: 26
• Journal issue: 8
• Pages of publication: 1085
• a: 6.1482 ± 0.0001 Å
• b: 9.4605 ± 0.0002 Å
• c: 17.0184 ± 0.0003 Å
• α: 90°
• β: 96.5058 ± 0.0009°
• γ: 90°
• Cell volume: 983.5 ± 0.03 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0195
• Residual factor for significantly intense reflections: 0.016
• Weighted residual factors for significantly intense reflections: 0.0386
• Weighted residual factors for all reflections included in the refinement: 0.0406
• Goodness-of-fit parameter for all reflections included in the refinement: 1.148
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No