Information card for entry 7053503

Structure parameters

• Formula: C35 H59 N4 Si2 V
• Calculated formula: C35 H59 N4 Si2 V
• SMILES: [V]1(N([Si](C)(C)C)C(=CC(=[N]1c1c(C(C)C)cccc1C(C)C)C)C)(=Nc1c(C(C)C)cccc1C(C)C)=N[Si](C)(C)C
• Title of publication: Reductive N‒N bond cleavage and coupling of organic azides mediated by chromium(i) and vanadium(i) β-diketiminate
• Authors of publication: Lin, Kuan-Ming; Wang, Po-Yang; Shieh, Yun-Jen; Chen, Hong-Zhang; Kuo, Ting-Shen; Tsai, Yi-Chou
• Journal of publication: New Journal of Chemistry
• Year of publication: 2010
• Journal volume: 34
• Journal issue: 8
• Pages of publication: 1737
• a: 12.2715 ± 0.0003 Å
• b: 19.3946 ± 0.0005 Å
• c: 16.4428 ± 0.0005 Å
• α: 90°
• β: 100.074 ± 0.001°
• γ: 90°
• Cell volume: 3853.07 ± 0.18 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1358
• Residual factor for significantly intense reflections: 0.0819
• Weighted residual factors for significantly intense reflections: 0.1764
• Weighted residual factors for all reflections included in the refinement: 0.2081
• Goodness-of-fit parameter for all reflections included in the refinement: 1.098
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No