Information card for entry 7053542

Structure parameters

• Common name: (2-Bis(trimethylsilyl)methyl-3,5,-di(2-thienyl)-2H-1,4,2- diazaphosphole-kappaP)pentacarbonyltungsten(0)
• Chemical name: [2-Bis(trimethylsilyl)methyl-3,5,-di(2-thienyl)-2H-1,4,2-diazaphosphole- kappaP]pentacarbonyltungsten(0)
• Formula: C22 H25 N2 O5 P S2 Si2 W
• Calculated formula: C22 H25 N2 O5 P S2 Si2 W
• Title of publication: Extended π conjugation in 2H-1,4,2-diazaphosphole complexes
• Authors of publication: Helten, Holger; Daniels, Jörg; Nieger, Martin; Streubel, Rainer
• Journal of publication: New Journal of Chemistry
• Year of publication: 2010
• Journal volume: 34
• Journal issue: 8
• Pages of publication: 1593
• a: 9.5035 ± 0.0003 Å
• b: 10.958 ± 0.0004 Å
• c: 15.4221 ± 0.0007 Å
• α: 75.868 ± 0.002°
• β: 84.937 ± 0.002°
• γ: 65.551 ± 0.002°
• Cell volume: 1417.64 ± 0.1 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0337
• Residual factor for significantly intense reflections: 0.0291
• Weighted residual factors for significantly intense reflections: 0.0668
• Weighted residual factors for all reflections included in the refinement: 0.0686
• Goodness-of-fit parameter for all reflections included in the refinement: 1.04
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No