Information card for entry 7063912

Structure parameters

• Chemical name: Dichlorotetrakis{2-[9-borabicyclo[3.3.1]nonan-9-yl]ethyl}(diphenyl)phosphine)}dirhodium
• Formula: C88 H112 B4 Cl2 P4 Rh2
• Calculated formula: C88 H112 B4 Cl2 P4 Rh2
• Title of publication: Primary and secondary coordination sphere Lewis acid interactions in β-phosphinoethylborane-ligated rhodium and iridium complexes
• Authors of publication: Nichols, Brian R.; Petersen, Jeffrey L.; Dolinar, Brian S.; Popp, Brian V.
• Journal of publication: New Journal of Chemistry
• Year of publication: 2025
• Journal volume: 49
• Journal issue: 32
• Pages of publication: 14073 - 14081
• a: 12.2787 ± 0.0005 Å
• b: 14.2439 ± 0.0006 Å
• c: 25.4195 ± 0.001 Å
• α: 96.1831 ± 0.0012°
• β: 100.436 ± 0.0011°
• γ: 114.988 ± 0.0011°
• Cell volume: 3877.4 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0592
• Residual factor for significantly intense reflections: 0.0442
• Weighted residual factors for significantly intense reflections: 0.089
• Weighted residual factors for all reflections included in the refinement: 0.0942
• Goodness-of-fit parameter for all reflections included in the refinement: 1.075
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No