#------------------------------------------------------------------------------
#$Date: 2025-12-06 02:46:35 +0100 (Sat 06 de Dec de 2025) $
#$Revision: 304066 $
#$URL: svn://www.crystallography.net/cod/cif/7/06/41/7064149.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7064149
loop_
_publ_author_name
'Shao, Tai-ming'
'Liao, Hai-Xia'
'Li, Qiu-Ming'
'Tan, Mingxiong'
'Liang, Chun-Jie'
'Liang, Hong'
'Qin, Qi-Pin'
_publ_section_title
;
 Designing mitophagy-targeted robustine- and 4-acridinol-rhodium(III)
 coordination compounds to overcome cisplatin resistance in A549/DDP lung
 cancer cells
;
_journal_name_full               'New Journal of Chemistry'
_journal_paper_doi               10.1039/D5NJ02700D
_journal_year                    2026
_chemical_formula_moiety         'C60 H46 N2 O6 P2 Rh, Cl, 3(C H4 O)'
_chemical_formula_sum            'C63 H58 Cl N2 O9 P2 Rh'
_chemical_formula_weight         1187.41
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_audit_creation_date             2023-04-21
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2025-11-24 deposited with the CCDC.	2025-12-05 downloaded from the CCDC.
;
_cell_angle_alpha                96.8680(10)
_cell_angle_beta                 99.566(2)
_cell_angle_gamma                107.8630(10)
_cell_formula_units_Z            2
_cell_length_a                   11.7749(4)
_cell_length_b                   13.8665(4)
_cell_length_c                   18.1394(7)
_cell_measurement_reflns_used    9886
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      26.308
_cell_measurement_theta_min      2.393
_cell_volume                     2733.48(16)
_computing_cell_refinement       'SAINT V8.40A (?, 2016)'
_computing_data_reduction        'SAINT V8.40A (?, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution
;
Superflip (Palatinus & Chapuis, 2007;Palatinus & van der Lee, 2008;
Palatinus et al., 2012)
;
_diffrn_ambient_temperature      150.0
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0706
_diffrn_reflns_av_unetI/netI     0.0356
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            97217
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.440
_diffrn_reflns_theta_min         2.113
_exptl_absorpt_coefficient_mu    0.481
_exptl_absorpt_correction_T_max  0.0276
_exptl_absorpt_correction_T_min  0.0112
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0772 before and 0.0676 after correction.
The Ratio of minimum to maximum transmission is 0.4058.
The λ/2 correction factor is Not present.
;
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.443
_exptl_crystal_description       block
_exptl_crystal_F_000             1228
_exptl_crystal_size_max          0.54
_exptl_crystal_size_mid          0.45
_exptl_crystal_size_min          0.41
_refine_diff_density_max         0.379
_refine_diff_density_min         -1.029
_refine_diff_density_rms         0.118
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     711
_refine_ls_number_reflns         11211
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.018
_refine_ls_R_factor_all          0.0535
_refine_ls_R_factor_gt           0.0405
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0706P)²+1.2813P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1055
_refine_ls_wR_factor_ref         0.1176
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9158
_reflns_number_total             11211
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d5nj02700d2.cif
_cod_data_source_block           wf7
_cod_database_code               7064149
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.827
_shelx_estimated_absorpt_t_min   0.781
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C12(H12), C6(H6), C36(H36), C11(H11), C37(H37), C32(H32), C58(H58), C23(H23),
 C24(H24), C10(H10), C26(H26), C46(H46), C35(H35), C44(H44), C34(H34), C33(H33),
  C38(H38), C21(H21), C8(H8), C50(H50), C49(H49), C5(H5), C18(H18), C30(H30),
 C27(H27), C57(H57), C20(H20), C2(H2), C9(H9), C45(H45), C28(H28), C22(H22),
 C14(H14), C17(H17), C56(H56), C29(H29), C16(H16), C4(H4), C15(H15), C3(H3)
2.b Idealised Me refined as rotating group:
 C48(H48A,H48B,H48C), C63(H63A,H63B,H63C), C62(H62A,H62B,H62C), C60(H60A,H60B,
 H60C), C61(H61A,H61B,H61C)
2.c Idealised tetrahedral OH refined as rotating group:
 O9(H9A), O8(H8A), O7(H7)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.67800(2) 0.26420(2) 0.17648(2) 0.02537(8) Uani 1 1 d . . . . .
P1 P 0.81246(6) 0.35124(5) 0.10142(4) 0.02695(15) Uani 1 1 d . . . . .
Cl1 Cl 1.12223(9) 0.67757(7) 0.42403(6) 0.0551(2) Uani 1 1 d . . . . .
O5 O 0.64246(18) 0.12811(14) 0.10725(11) 0.0314(4) Uani 1 1 d . . . . .
O1 O 0.78337(18) 0.39856(14) 0.36238(11) 0.0301(4) Uani 1 1 d . . . . .
O2 O 0.54135(18) 0.29453(14) 0.11056(11) 0.0304(4) Uani 1 1 d . . . . .
O3 O 0.6500(2) 0.68126(15) 0.32996(12) 0.0369(5) Uani 1 1 d . . . . .
O4 O 0.95916(18) 0.37029(14) 0.30125(11) 0.0317(4) Uani 1 1 d . . . . .
O6 O 1.0485(2) 0.06306(17) 0.31582(13) 0.0436(5) Uani 1 1 d . . . . .
N1 N 0.6834(2) 0.39991(17) 0.24097(13) 0.0267(5) Uani 1 1 d . . . . .
N2 N 0.8187(2) 0.21904(17) 0.22748(13) 0.0278(5) Uani 1 1 d . . . . .
O9 O 1.3349(2) 0.6063(2) 0.38984(14) 0.0501(6) Uani 1 1 d . . . . .
H9A H 1.284905 0.626540 0.409927 0.075 Uiso 1 1 calc GR . . . .
O8 O 1.0420(3) 0.1965(2) 0.53447(18) 0.0617(7) Uani 1 1 d . . . . .
H8A H 1.008058 0.241055 0.541028 0.093 Uiso 1 1 calc GR . . . .
C12 C 0.6360(3) 0.2499(2) -0.03229(17) 0.0336(6) Uani 1 1 d . . . . .
H12 H 0.580211 0.228739 -0.000339 0.040 Uiso 1 1 calc R . . . .
C7 C 0.7549(3) 0.3132(2) -0.00126(15) 0.0287(6) Uani 1 1 d . . . . .
C31 C 0.3951(3) 0.0831(2) 0.19289(16) 0.0306(6) Uani 1 1 d . . . . .
C6 C 0.9112(3) 0.5423(2) 0.19698(17) 0.0324(6) Uani 1 1 d . . . . .
H6 H 0.933545 0.504723 0.234064 0.039 Uiso 1 1 calc R . . . .
O7 O 0.2709(3) -0.1223(3) 0.3669(2) 0.0910(11) Uani 1 1 d . . . . .
H7 H 0.221720 -0.173003 0.378906 0.137 Uiso 1 1 calc GR . . . .
C36 C 0.3628(3) 0.0698(2) 0.11432(17) 0.0396(7) Uani 1 1 d . . . . .
H36 H 0.418822 0.105626 0.086681 0.048 Uiso 1 1 calc R . . . .
C41 C 0.6170(2) 0.4502(2) 0.19952(16) 0.0276(5) Uani 1 1 d . . . . .
C11 C 0.5989(3) 0.2174(2) -0.11061(17) 0.0376(7) Uani 1 1 d . . . . .
H11 H 0.517268 0.173961 -0.132107 0.045 Uiso 1 1 calc R . . . .
C1 C 0.8529(2) 0.4910(2) 0.12295(16) 0.0293(6) Uani 1 1 d . . . . .
C40 C 0.7285(2) 0.4439(2) 0.31254(15) 0.0264(5) Uani 1 1 d . . . . .
C37 C 0.8194(3) 0.4659(2) 0.43204(16) 0.0340(6) Uani 1 1 d . . . . .
H37 H 0.861585 0.453660 0.477429 0.041 Uiso 1 1 calc R . . . .
C32 C 0.3122(3) 0.0296(2) 0.23254(18) 0.0379(7) Uani 1 1 d . . . . .
H32 H 0.333837 0.038817 0.286378 0.045 Uiso 1 1 calc R . . . .
C25 C 0.6092(3) 0.0937(2) 0.30269(16) 0.0295(6) Uani 1 1 d . . . . .
C58 C 0.6814(3) -0.0317(2) 0.10490(18) 0.0357(6) Uani 1 1 d . . . . .
H58 H 0.616824 -0.065166 0.061844 0.043 Uiso 1 1 calc R . . . .
C59 C 0.7036(3) 0.0703(2) 0.13615(16) 0.0308(6) Uani 1 1 d . . . . .
C51 C 1.0075(3) 0.2248(2) 0.31186(17) 0.0320(6) Uani 1 1 d . . . . .
C42 C 0.6110(2) 0.5468(2) 0.22793(16) 0.0283(6) Uani 1 1 d . . . . .
C23 C 0.4970(3) 0.3428(2) 0.43654(18) 0.0385(7) Uani 1 1 d . . . . .
H23 H 0.522058 0.354596 0.490334 0.046 Uiso 1 1 calc R . . . .
C24 C 0.5300(3) 0.2712(2) 0.39220(16) 0.0333(6) Uani 1 1 d . . . . .
H24 H 0.576518 0.233760 0.415699 0.040 Uiso 1 1 calc R . . . .
C52 C 0.9218(3) 0.2675(2) 0.27704(16) 0.0286(6) Uani 1 1 d . . . . .
C43 C 0.6655(3) 0.5917(2) 0.30518(17) 0.0314(6) Uani 1 1 d . . . . .
C10 C 0.6793(3) 0.2477(2) -0.15752(17) 0.0377(7) Uani 1 1 d . . . . .
H10 H 0.653253 0.224486 -0.210927 0.045 Uiso 1 1 calc R . . . .
C26 C 0.7097(3) 0.1401(2) 0.36273(16) 0.0309(6) Uani 1 1 d . . . . .
H26 H 0.739981 0.212938 0.377588 0.037 Uiso 1 1 calc R . . . .
C46 C 0.4778(3) 0.4364(2) 0.08225(17) 0.0329(6) Uani 1 1 d . . . . .
H46 H 0.430936 0.399756 0.033535 0.039 Uiso 1 1 calc R . . . .
C19 C 0.4946(2) 0.2545(2) 0.31320(16) 0.0287(6) Uani 1 1 d . . . . .
C35 C 0.2472(3) 0.0032(3) 0.0763(2) 0.0474(8) Uani 1 1 d . . . . .
H35 H 0.224179 -0.005639 0.022535 0.057 Uiso 1 1 calc R . . . .
C53 C 0.8016(3) 0.1173(2) 0.20043(16) 0.0308(6) Uani 1 1 d . . . . .
C48 C 0.6536(3) 0.7077(2) 0.40977(18) 0.0397(7) Uani 1 1 d . . . . .
H48A H 0.610762 0.757303 0.417258 0.060 Uiso 1 1 calc GR . . . .
H48B H 0.738800 0.738286 0.437623 0.060 Uiso 1 1 calc GR . . . .
H48C H 0.613754 0.645389 0.428725 0.060 Uiso 1 1 calc GR . . . .
C44 C 0.5418(3) 0.5911(2) 0.17868(17) 0.0347(6) Uani 1 1 d . . . . .
H44 H 0.539364 0.658047 0.194920 0.042 Uiso 1 1 calc R . . . .
C34 C 0.1662(3) -0.0498(3) 0.1161(2) 0.0438(7) Uani 1 1 d . . . . .
H34 H 0.087841 -0.095305 0.089750 0.053 Uiso 1 1 calc R . . . .
C33 C 0.1984(3) -0.0370(3) 0.19378(19) 0.0427(7) Uani 1 1 d . . . . .
H33 H 0.142519 -0.074012 0.221030 0.051 Uiso 1 1 calc R . . . .
C38 C 0.7876(3) 0.5496(2) 0.42716(17) 0.0345(6) Uani 1 1 d . . . . .
H38 H 0.803141 0.605731 0.467293 0.041 Uiso 1 1 calc R . . . .
C39 C 0.7247(3) 0.5390(2) 0.34924(16) 0.0303(6) Uani 1 1 d . . . . .
C21 C 0.3903(3) 0.3784(2) 0.32498(18) 0.0371(7) Uani 1 1 d . . . . .
H21 H 0.341149 0.414186 0.301847 0.044 Uiso 1 1 calc R . . . .
C8 C 0.8356(3) 0.3445(2) -0.04904(17) 0.0361(6) Uani 1 1 d . . . . .
H8 H 0.917094 0.388513 -0.027934 0.043 Uiso 1 1 calc R . . . .
C50 C 1.1013(3) 0.3123(2) 0.36250(17) 0.0358(6) Uani 1 1 d . . . . .
H50 H 1.171891 0.310756 0.395711 0.043 Uiso 1 1 calc R . . . .
C49 C 1.0694(3) 0.3952(2) 0.35351(18) 0.0367(7) Uani 1 1 d . . . . .
H49 H 1.116245 0.463064 0.379610 0.044 Uiso 1 1 calc R . . . .
C13 C 0.9568(3) 0.3249(2) 0.10992(16) 0.0298(6) Uani 1 1 d . . . . .
C5 C 0.9371(3) 0.6481(2) 0.21701(19) 0.0389(7) Uani 1 1 d . . . . .
H5 H 0.976960 0.682903 0.267418 0.047 Uiso 1 1 calc R . . . .
C18 C 0.9492(3) 0.2240(2) 0.08346(17) 0.0356(6) Uani 1 1 d . . . . .
H18 H 0.871302 0.172880 0.063815 0.043 Uiso 1 1 calc R . . . .
C30 C 0.5686(3) -0.0130(2) 0.27918(18) 0.0356(6) Uani 1 1 d . . . . .
H30 H 0.501483 -0.045079 0.237322 0.043 Uiso 1 1 calc R . . . .
C27 C 0.7661(3) 0.0802(2) 0.40107(19) 0.0391(7) Uani 1 1 d . . . . .
H27 H 0.833443 0.111763 0.442820 0.047 Uiso 1 1 calc R . . . .
C57 C 0.7547(3) -0.0855(2) 0.1371(2) 0.0439(8) Uani 1 1 d . . . . .
H57 H 0.736927 -0.155930 0.116021 0.053 Uiso 1 1 calc R . . . .
C20 C 0.4234(3) 0.3080(2) 0.28020(17) 0.0326(6) Uani 1 1 d . . . . .
H20 H 0.397283 0.296180 0.226475 0.039 Uiso 1 1 calc R . . . .
C55 C 0.9828(3) 0.1198(2) 0.28946(17) 0.0339(6) Uani 1 1 d . . . . .
C47 C 0.5447(3) 0.3917(2) 0.12784(16) 0.0284(6) Uani 1 1 d . . . . .
C2 C 0.8201(3) 0.5465(2) 0.06861(19) 0.0367(6) Uani 1 1 d . . . . .
H2 H 0.780380 0.512324 0.018041 0.044 Uiso 1 1 calc R . . . .
C9 C 0.7976(3) 0.3117(2) -0.12678(18) 0.0387(7) Uani 1 1 d . . . . .
H9 H 0.852755 0.333244 -0.159030 0.046 Uiso 1 1 calc R . . . .
C45 C 0.4791(3) 0.5369(2) 0.10810(17) 0.0355(6) Uani 1 1 d . . . . .
H45 H 0.435018 0.567846 0.075338 0.043 Uiso 1 1 calc R . . . .
C28 C 0.7228(3) -0.0262(3) 0.3777(2) 0.0454(8) Uani 1 1 d . . . . .
H28 H 0.760490 -0.067501 0.404045 0.054 Uiso 1 1 calc R . . . .
C22 C 0.4282(3) 0.3969(2) 0.40311(19) 0.0386(7) Uani 1 1 d . . . . .
H22 H 0.407137 0.446572 0.433666 0.046 Uiso 1 1 calc R . . . .
C14 C 1.0714(3) 0.3989(2) 0.13836(17) 0.0351(6) Uani 1 1 d . . . . .
H14 H 1.078177 0.467768 0.157382 0.042 Uiso 1 1 calc R . . . .
C17 C 1.0534(3) 0.1975(3) 0.08546(19) 0.0411(7) Uani 1 1 d . . . . .
H17 H 1.046959 0.128173 0.068286 0.049 Uiso 1 1 calc R . . . .
C56 C 0.8504(3) -0.0401(2) 0.1977(2) 0.0417(7) Uani 1 1 d . . . . .
H56 H 0.897973 -0.078871 0.218099 0.050 Uiso 1 1 calc R . . . .
C29 C 0.6261(3) -0.0722(2) 0.3170(2) 0.0442(8) Uani 1 1 d . . . . .
H29 H 0.598604 -0.144825 0.300767 0.053 Uiso 1 1 calc R . . . .
C54 C 0.8789(3) 0.0651(2) 0.23015(17) 0.0333(6) Uani 1 1 d . . . . .
C16 C 1.1672(3) 0.2720(3) 0.11250(19) 0.0452(8) Uani 1 1 d . . . . .
H16 H 1.239045 0.254309 0.112864 0.054 Uiso 1 1 calc R . . . .
C4 C 0.9036(3) 0.7020(2) 0.1621(2) 0.0466(8) Uani 1 1 d . . . . .
H4 H 0.920726 0.774231 0.175240 0.056 Uiso 1 1 calc R . . . .
C15 C 1.1759(3) 0.3721(3) 0.13895(18) 0.0426(7) Uani 1 1 d . . . . .
H15 H 1.254041 0.423196 0.157710 0.051 Uiso 1 1 calc R . . . .
C3 C 0.8458(3) 0.6520(2) 0.0889(2) 0.0459(8) Uani 1 1 d . . . . .
H3 H 0.823417 0.689846 0.052067 0.055 Uiso 1 1 calc R . . . .
C63 C 1.3272(4) 0.6268(3) 0.3154(2) 0.0570(10) Uani 1 1 d . . . . .
H63A H 1.244729 0.589257 0.285119 0.086 Uiso 1 1 calc GR . . . .
H63B H 1.386729 0.604524 0.292344 0.086 Uiso 1 1 calc GR . . . .
H63C H 1.344921 0.700913 0.316879 0.086 Uiso 1 1 calc GR . . . .
C62 C 1.0223(5) 0.1322(4) 0.5891(3) 0.0820(15) Uani 1 1 d . . . . .
H62A H 1.028672 0.065434 0.569811 0.123 Uiso 1 1 calc GR . . . .
H62B H 0.940644 0.122067 0.599330 0.123 Uiso 1 1 calc GR . . . .
H62C H 1.083882 0.164593 0.636266 0.123 Uiso 1 1 calc GR . . . .
C60 C 1.1574(3) 0.1116(3) 0.3746(2) 0.0486(8) Uani 1 1 d . . . . .
H60A H 1.215665 0.165254 0.356075 0.073 Uiso 1 1 calc GR . . . .
H60B H 1.194245 0.059932 0.388151 0.073 Uiso 1 1 calc GR . . . .
H60C H 1.136203 0.142679 0.419495 0.073 Uiso 1 1 calc GR . . . .
C61 C 0.3763(5) -0.0813(4) 0.4248(3) 0.0827(15) Uani 1 1 d . . . . .
H61A H 0.425663 -0.014111 0.416348 0.124 Uiso 1 1 calc GR . . . .
H61B H 0.423976 -0.128104 0.424709 0.124 Uiso 1 1 calc GR . . . .
H61C H 0.353138 -0.072797 0.474041 0.124 Uiso 1 1 calc GR . . . .
P2 P 0.54208(6) 0.17173(5) 0.24772(4) 0.02705(15) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Rh1 P1 90.58(6) . . ?
O5 Rh1 O2 91.71(8) . . ?
O5 Rh1 N1 170.32(8) . . ?
O5 Rh1 N2 79.92(8) . . ?
O5 Rh1 P2 87.26(6) . . ?
O2 Rh1 P1 87.98(6) . . ?
O2 Rh1 N1 79.74(8) . . ?
O2 Rh1 N2 170.56(8) . . ?
O2 Rh1 P2 91.86(6) . . ?
N1 Rh1 P1 93.62(6) . . ?
N1 Rh1 P2 88.48(6) . . ?
N2 Rh1 P1 87.75(6) . . ?
N2 Rh1 N1 108.94(9) . . ?
N2 Rh1 P2 92.09(6) . . ?
P2 Rh1 P1 177.83(2) . . ?
C7 P1 Rh1 115.03(9) . . ?
C7 P1 C13 99.89(13) . . ?
C1 P1 Rh1 112.99(9) . . ?
C1 P1 C7 106.50(13) . . ?
C1 P1 C13 106.29(13) . . ?
C13 P1 Rh1 114.91(9) . . ?
C59 O5 Rh1 113.04(17) . . ?
C40 O1 C37 106.0(2) . . ?
C47 O2 Rh1 113.07(16) . . ?
C43 O3 C48 117.9(2) . . ?
C52 O4 C49 106.1(2) . . ?
C55 O6 C60 119.3(2) . . ?
C41 N1 Rh1 111.47(17) . . ?
C40 N1 Rh1 134.01(18) . . ?
C40 N1 C41 114.3(2) . . ?
C52 N2 Rh1 133.69(18) . . ?
C52 N2 C53 114.3(2) . . ?
C53 N2 Rh1 111.89(18) . . ?
C63 O9 H9A 109.5 . . ?
C62 O8 H8A 109.5 . . ?
C7 C12 H12 120.3 . . ?
C7 C12 C11 119.4(3) . . ?
C11 C12 H12 120.3 . . ?
C12 C7 P1 121.6(2) . . ?
C12 C7 C8 119.6(3) . . ?
C8 C7 P1 118.7(2) . . ?
C36 C31 C32 119.6(3) . . ?
C36 C31 P2 122.5(2) . . ?
C32 C31 P2 117.9(2) . . ?
C1 C6 H6 119.7 . . ?
C5 C6 H6 119.7 . . ?
C5 C6 C1 120.6(3) . . ?
C61 O7 H7 109.5 . . ?
C31 C36 H36 120.3 . . ?
C31 C36 C35 119.4(3) . . ?
C35 C36 H36 120.3 . . ?
N1 C41 C42 123.4(2) . . ?
N1 C41 C47 114.6(2) . . ?
C42 C41 C47 121.6(2) . . ?
C12 C11 H11 119.7 . . ?
C10 C11 C12 120.7(3) . . ?
C10 C11 H11 119.7 . . ?
C6 C1 P1 118.7(2) . . ?
C6 C1 C2 119.5(3) . . ?
C2 C1 P1 121.6(2) . . ?
O1 C40 C39 110.9(2) . . ?
N1 C40 O1 121.5(2) . . ?
N1 C40 C39 127.6(2) . . ?
O1 C37 H37 124.1 . . ?
C38 C37 O1 111.7(3) . . ?
C38 C37 H37 124.1 . . ?
C31 C32 H32 119.9 . . ?
C33 C32 C31 120.2(3) . . ?
C33 C32 H32 119.9 . . ?
C26 C25 C30 119.5(3) . . ?
C26 C25 P2 120.6(2) . . ?
C30 C25 P2 119.6(2) . . ?
C59 C58 H58 120.1 . . ?
C59 C58 C57 119.8(3) . . ?
C57 C58 H58 120.1 . . ?
O5 C59 C58 123.7(3) . . ?
O5 C59 C53 118.1(2) . . ?
C58 C59 C53 118.1(3) . . ?
C52 C51 C50 104.2(2) . . ?
C55 C51 C52 116.8(3) . . ?
C55 C51 C50 139.0(3) . . ?
C41 C42 C43 118.8(2) . . ?
C41 C42 C44 117.8(3) . . ?
C43 C42 C44 123.2(3) . . ?
C24 C23 H23 119.7 . . ?
C22 C23 H23 119.7 . . ?
C22 C23 C24 120.6(3) . . ?
C23 C24 H24 120.0 . . ?
C23 C24 C19 119.9(3) . . ?
C19 C24 H24 120.0 . . ?
O4 C52 C51 110.9(2) . . ?
N2 C52 O4 121.4(2) . . ?
N2 C52 C51 127.8(3) . . ?
O3 C43 C42 115.8(2) . . ?
O3 C43 C39 125.7(3) . . ?
C39 C43 C42 118.5(2) . . ?
C11 C10 H10 120.0 . . ?
C9 C10 C11 120.0(3) . . ?
C9 C10 H10 120.0 . . ?
C25 C26 H26 119.9 . . ?
C27 C26 C25 120.3(3) . . ?
C27 C26 H26 119.9 . . ?
C47 C46 H46 120.1 . . ?
C47 C46 C45 119.8(3) . . ?
C45 C46 H46 120.1 . . ?
C24 C19 P2 124.8(2) . . ?
C20 C19 C24 119.0(3) . . ?
C20 C19 P2 116.2(2) . . ?
C36 C35 H35 119.8 . . ?
C34 C35 C36 120.5(3) . . ?
C34 C35 H35 119.8 . . ?
N2 C53 C59 114.6(2) . . ?
N2 C53 C54 123.3(3) . . ?
C54 C53 C59 122.0(3) . . ?
O3 C48 H48A 109.5 . . ?
O3 C48 H48B 109.5 . . ?
O3 C48 H48C 109.5 . . ?
H48A C48 H48B 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
C42 C44 H44 120.2 . . ?
C45 C44 C42 119.7(3) . . ?
C45 C44 H44 120.2 . . ?
C35 C34 H34 119.9 . . ?
C33 C34 C35 120.2(3) . . ?
C33 C34 H34 119.9 . . ?
C32 C33 H33 119.9 . . ?
C34 C33 C32 120.2(3) . . ?
C34 C33 H33 119.9 . . ?
C37 C38 H38 126.3 . . ?
C37 C38 C39 107.3(3) . . ?
C39 C38 H38 126.3 . . ?
C40 C39 C38 104.0(2) . . ?
C43 C39 C40 116.9(3) . . ?
C43 C39 C38 139.1(3) . . ?
C20 C21 H21 119.8 . . ?
C22 C21 H21 119.8 . . ?
C22 C21 C20 120.4(3) . . ?
C7 C8 H8 119.8 . . ?
C9 C8 C7 120.4(3) . . ?
C9 C8 H8 119.8 . . ?
C51 C50 H50 126.5 . . ?
C49 C50 C51 107.0(3) . . ?
C49 C50 H50 126.5 . . ?
O4 C49 H49 124.1 . . ?
C50 C49 O4 111.9(3) . . ?
C50 C49 H49 124.1 . . ?
C18 C13 P1 116.7(2) . . ?
C14 C13 P1 124.3(2) . . ?
C14 C13 C18 118.9(3) . . ?
C6 C5 H5 120.5 . . ?
C4 C5 C6 119.0(3) . . ?
C4 C5 H5 120.5 . . ?
C13 C18 H18 119.6 . . ?
C17 C18 C13 120.8(3) . . ?
C17 C18 H18 119.6 . . ?
C25 C30 H30 120.0 . . ?
C29 C30 C25 119.9(3) . . ?
C29 C30 H30 120.0 . . ?
C26 C27 H27 120.3 . . ?
C26 C27 C28 119.4(3) . . ?
C28 C27 H27 120.3 . . ?
C58 C57 H57 118.9 . . ?
C56 C57 C58 122.3(3) . . ?
C56 C57 H57 118.9 . . ?
C19 C20 H20 119.7 . . ?
C21 C20 C19 120.5(3) . . ?
C21 C20 H20 119.7 . . ?
O6 C55 C51 127.2(3) . . ?
O6 C55 C54 114.9(3) . . ?
C51 C55 C54 117.9(3) . . ?
O2 C47 C41 117.6(2) . . ?
O2 C47 C46 123.8(3) . . ?
C46 C47 C41 118.5(2) . . ?
C1 C2 H2 120.2 . . ?
C3 C2 C1 119.6(3) . . ?
C3 C2 H2 120.2 . . ?
C10 C9 C8 119.9(3) . . ?
C10 C9 H9 120.1 . . ?
C8 C9 H9 120.1 . . ?
C46 C45 H45 118.9 . . ?
C44 C45 C46 122.1(3) . . ?
C44 C45 H45 118.9 . . ?
C27 C28 H28 119.7 . . ?
C29 C28 C27 120.6(3) . . ?
C29 C28 H28 119.7 . . ?
C23 C22 C21 119.6(3) . . ?
C23 C22 H22 120.2 . . ?
C21 C22 H22 120.2 . . ?
C13 C14 H14 120.0 . . ?
C15 C14 C13 120.0(3) . . ?
C15 C14 H14 120.0 . . ?
C18 C17 H17 120.0 . . ?
C18 C17 C16 119.9(3) . . ?
C16 C17 H17 120.0 . . ?
C57 C56 H56 120.0 . . ?
C57 C56 C54 119.9(3) . . ?
C54 C56 H56 120.0 . . ?
C30 C29 H29 119.9 . . ?
C28 C29 C30 120.2(3) . . ?
C28 C29 H29 119.9 . . ?
C53 C54 C55 119.2(3) . . ?
C53 C54 C56 117.7(3) . . ?
C56 C54 C55 123.1(3) . . ?
C17 C16 H16 120.1 . . ?
C15 C16 C17 119.8(3) . . ?
C15 C16 H16 120.1 . . ?
C5 C4 H4 119.6 . . ?
C3 C4 C5 120.7(3) . . ?
C3 C4 H4 119.6 . . ?
C14 C15 H15 119.7 . . ?
C16 C15 C14 120.6(3) . . ?
C16 C15 H15 119.7 . . ?
C2 C3 H3 119.8 . . ?
C4 C3 C2 120.5(3) . . ?
C4 C3 H3 119.8 . . ?
O9 C63 H63A 109.5 . . ?
O9 C63 H63B 109.5 . . ?
O9 C63 H63C 109.5 . . ?
H63A C63 H63B 109.5 . . ?
H63A C63 H63C 109.5 . . ?
H63B C63 H63C 109.5 . . ?
O8 C62 H62A 109.5 . . ?
O8 C62 H62B 109.5 . . ?
O8 C62 H62C 109.5 . . ?
H62A C62 H62B 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
O6 C60 H60A 109.5 . . ?
O6 C60 H60B 109.5 . . ?
O6 C60 H60C 109.5 . . ?
H60A C60 H60B 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
O7 C61 H61A 109.5 . . ?
O7 C61 H61B 109.5 . . ?
O7 C61 H61C 109.5 . . ?
H61A C61 H61B 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
C31 P2 Rh1 116.18(10) . . ?
C31 P2 C19 101.54(13) . . ?
C25 P2 Rh1 111.69(9) . . ?
C25 P2 C31 105.22(13) . . ?
C25 P2 C19 107.72(13) . . ?
C19 P2 Rh1 113.57(9) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 P1 2.3988(7) . ?
Rh1 O5 2.0217(19) . ?
Rh1 O2 2.0228(19) . ?
Rh1 N1 2.071(2) . ?
Rh1 N2 2.063(2) . ?
Rh1 P2 2.3875(7) . ?
P1 C7 1.826(3) . ?
P1 C1 1.824(3) . ?
P1 C13 1.832(3) . ?
O5 C59 1.328(3) . ?
O1 C40 1.350(3) . ?
O1 C37 1.395(3) . ?
O2 C47 1.333(3) . ?
O3 C43 1.345(3) . ?
O3 C48 1.441(4) . ?
O4 C52 1.348(3) . ?
O4 C49 1.393(4) . ?
O6 C55 1.337(3) . ?
O6 C60 1.442(4) . ?
N1 C41 1.389(3) . ?
N1 C40 1.312(4) . ?
N2 C52 1.314(4) . ?
N2 C53 1.378(3) . ?
O9 H9A 0.8400 . ?
O9 C63 1.407(4) . ?
O8 H8A 0.8400 . ?
O8 C62 1.412(5) . ?
C12 H12 0.9500 . ?
C12 C7 1.383(4) . ?
C12 C11 1.390(4) . ?
C7 C8 1.398(4) . ?
C31 C36 1.387(4) . ?
C31 C32 1.392(4) . ?
C31 P2 1.824(3) . ?
C6 H6 0.9500 . ?
C6 C1 1.395(4) . ?
C6 C5 1.392(4) . ?
O7 H7 0.8400 . ?
O7 C61 1.400(6) . ?
C36 H36 0.9500 . ?
C36 C35 1.394(4) . ?
C41 C42 1.403(4) . ?
C41 C47 1.425(4) . ?
C11 H11 0.9500 . ?
C11 C10 1.381(4) . ?
C1 C2 1.397(4) . ?
C40 C39 1.421(4) . ?
C37 H37 0.9500 . ?
C37 C38 1.332(4) . ?
C32 H32 0.9500 . ?
C32 C33 1.384(4) . ?
C25 C26 1.392(4) . ?
C25 C30 1.395(4) . ?
C25 P2 1.820(3) . ?
C58 H58 0.9500 . ?
C58 C59 1.388(4) . ?
C58 C57 1.405(5) . ?
C59 C53 1.423(4) . ?
C51 C52 1.418(4) . ?
C51 C50 1.452(4) . ?
C51 C55 1.389(4) . ?
C42 C43 1.418(4) . ?
C42 C44 1.427(4) . ?
C23 H23 0.9500 . ?
C23 C24 1.390(4) . ?
C23 C22 1.380(4) . ?
C24 H24 0.9500 . ?
C24 C19 1.394(4) . ?
C43 C39 1.387(4) . ?
C10 H10 0.9500 . ?
C10 C9 1.379(5) . ?
C26 H26 0.9500 . ?
C26 C27 1.391(4) . ?
C46 H46 0.9500 . ?
C46 C47 1.376(4) . ?
C46 C45 1.410(4) . ?
C19 C20 1.390(4) . ?
C19 P2 1.825(3) . ?
C35 H35 0.9500 . ?
C35 C34 1.378(5) . ?
C53 C54 1.406(4) . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
C44 H44 0.9500 . ?
C44 C45 1.365(4) . ?
C34 H34 0.9500 . ?
C34 C33 1.371(5) . ?
C33 H33 0.9500 . ?
C38 H38 0.9500 . ?
C38 C39 1.450(4) . ?
C21 H21 0.9500 . ?
C21 C20 1.383(4) . ?
C21 C22 1.381(5) . ?
C8 H8 0.9500 . ?
C8 C9 1.381(4) . ?
C50 H50 0.9500 . ?
C50 C49 1.333(4) . ?
C49 H49 0.9500 . ?
C13 C18 1.393(4) . ?
C13 C14 1.390(4) . ?
C5 H5 0.9500 . ?
C5 C4 1.392(5) . ?
C18 H18 0.9500 . ?
C18 C17 1.381(4) . ?
C30 H30 0.9500 . ?
C30 C29 1.388(4) . ?
C27 H27 0.9500 . ?
C27 C28 1.391(5) . ?
C57 H57 0.9500 . ?
C57 C56 1.364(5) . ?
C20 H20 0.9500 . ?
C55 C54 1.424(4) . ?
C2 H2 0.9500 . ?
C2 C3 1.388(4) . ?
C9 H9 0.9500 . ?
C45 H45 0.9500 . ?
C28 H28 0.9500 . ?
C28 C29 1.374(5) . ?
C22 H22 0.9500 . ?
C14 H14 0.9500 . ?
C14 C15 1.389(4) . ?
C17 H17 0.9500 . ?
C17 C16 1.383(5) . ?
C56 H56 0.9500 . ?
C56 C54 1.420(4) . ?
C29 H29 0.9500 . ?
C16 H16 0.9500 . ?
C16 C15 1.381(5) . ?
C4 H4 0.9500 . ?
C4 C3 1.377(5) . ?
C15 H15 0.9500 . ?
C3 H3 0.9500 . ?
C63 H63A 0.9800 . ?
C63 H63B 0.9800 . ?
C63 H63C 0.9800 . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C61 H61A 0.9800 . ?
C61 H61B 0.9800 . ?
C61 H61C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1 P1 C7 C12 8.7(3) . . . . ?
Rh1 P1 C7 C8 -167.7(2) . . . . ?
Rh1 P1 C1 C6 59.1(2) . . . . ?
Rh1 P1 C1 C2 -116.7(2) . . . . ?
Rh1 P1 C13 C18 64.9(2) . . . . ?
Rh1 P1 C13 C14 -117.3(2) . . . . ?
Rh1 O5 C59 C58 170.1(2) . . . . ?
Rh1 O5 C59 C53 -13.3(3) . . . . ?
Rh1 O2 C47 C41 -16.9(3) . . . . ?
Rh1 O2 C47 C46 166.5(2) . . . . ?
Rh1 N1 C41 C42 -176.3(2) . . . . ?
Rh1 N1 C41 C47 9.6(3) . . . . ?
Rh1 N1 C40 O1 -2.1(4) . . . . ?
Rh1 N1 C40 C39 -179.8(2) . . . . ?
Rh1 N2 C52 O4 -5.1(4) . . . . ?
Rh1 N2 C52 C51 175.1(2) . . . . ?
Rh1 N2 C53 C59 9.4(3) . . . . ?
Rh1 N2 C53 C54 -174.6(2) . . . . ?
P1 C7 C8 C9 175.8(2) . . . . ?
P1 C1 C2 C3 175.8(2) . . . . ?
P1 C13 C18 C17 178.1(2) . . . . ?
P1 C13 C14 C15 -176.8(2) . . . . ?
O5 C59 C53 N2 2.5(4) . . . . ?
O5 C59 C53 C54 -173.6(3) . . . . ?
O1 C40 C39 C43 -177.1(2) . . . . ?
O1 C40 C39 C38 2.0(3) . . . . ?
O1 C37 C38 C39 0.4(4) . . . . ?
O3 C43 C39 C40 178.4(3) . . . . ?
O3 C43 C39 C38 -0.3(6) . . . . ?
O6 C55 C54 C53 177.8(3) . . . . ?
O6 C55 C54 C56 -3.8(4) . . . . ?
N1 C41 C42 C43 -6.2(4) . . . . ?
N1 C41 C42 C44 178.4(3) . . . . ?
N1 C41 C47 O2 4.6(4) . . . . ?
N1 C41 C47 C46 -178.6(2) . . . . ?
N1 C40 C39 C43 0.8(4) . . . . ?
N1 C40 C39 C38 180.0(3) . . . . ?
N2 C53 C54 C55 -2.2(4) . . . . ?
N2 C53 C54 C56 179.3(3) . . . . ?
C12 C7 C8 C9 -0.7(4) . . . . ?
C12 C11 C10 C9 -0.7(5) . . . . ?
C7 P1 C1 C6 -173.6(2) . . . . ?
C7 P1 C1 C2 10.5(3) . . . . ?
C7 P1 C13 C18 -58.8(2) . . . . ?
C7 P1 C13 C14 119.1(3) . . . . ?
C7 C12 C11 C10 0.0(5) . . . . ?
C7 C8 C9 C10 0.0(5) . . . . ?
C31 C36 C35 C34 -0.7(5) . . . . ?
C31 C32 C33 C34 -0.7(5) . . . . ?
C6 C1 C2 C3 0.0(4) . . . . ?
C6 C5 C4 C3 -0.1(5) . . . . ?
C36 C31 C32 C33 0.4(5) . . . . ?
C36 C31 P2 Rh1 -0.3(3) . . . . ?
C36 C31 P2 C25 -124.4(3) . . . . ?
C36 C31 P2 C19 123.5(3) . . . . ?
C36 C35 C34 C33 0.4(6) . . . . ?
C41 N1 C40 O1 172.4(2) . . . . ?
C41 N1 C40 C39 -5.3(4) . . . . ?
C41 C42 C43 O3 -176.1(2) . . . . ?
C41 C42 C43 C39 1.2(4) . . . . ?
C41 C42 C44 C45 3.5(4) . . . . ?
C11 C12 C7 P1 -175.7(2) . . . . ?
C11 C12 C7 C8 0.7(4) . . . . ?
C11 C10 C9 C8 0.7(5) . . . . ?
C1 P1 C7 C12 -117.3(2) . . . . ?
C1 P1 C7 C8 66.3(2) . . . . ?
C1 P1 C13 C18 -169.4(2) . . . . ?
C1 P1 C13 C14 8.5(3) . . . . ?
C1 C6 C5 C4 0.2(5) . . . . ?
C1 C2 C3 C4 0.1(5) . . . . ?
C40 O1 C37 C38 0.9(3) . . . . ?
C40 N1 C41 C42 8.0(4) . . . . ?
C40 N1 C41 C47 -166.1(2) . . . . ?
C37 O1 C40 N1 -179.9(2) . . . . ?
C37 O1 C40 C39 -1.8(3) . . . . ?
C37 C38 C39 C40 -1.4(3) . . . . ?
C37 C38 C39 C43 177.4(3) . . . . ?
C32 C31 C36 C35 0.3(5) . . . . ?
C32 C31 P2 Rh1 -178.5(2) . . . . ?
C32 C31 P2 C25 57.4(3) . . . . ?
C32 C31 P2 C19 -54.8(3) . . . . ?
C25 C26 C27 C28 1.5(5) . . . . ?
C25 C30 C29 C28 0.3(5) . . . . ?
C58 C59 C53 N2 179.2(2) . . . . ?
C58 C59 C53 C54 3.2(4) . . . . ?
C58 C57 C56 C54 -0.1(5) . . . . ?
C59 C58 C57 C56 -1.8(5) . . . . ?
C59 C53 C54 C55 173.5(3) . . . . ?
C59 C53 C54 C56 -5.0(4) . . . . ?
C51 C50 C49 O4 1.1(4) . . . . ?
C51 C55 C54 C53 -4.2(4) . . . . ?
C51 C55 C54 C56 174.2(3) . . . . ?
C42 C41 C47 O2 -169.6(2) . . . . ?
C42 C41 C47 C46 7.1(4) . . . . ?
C42 C43 C39 C40 1.4(4) . . . . ?
C42 C43 C39 C38 -177.3(3) . . . . ?
C42 C44 C45 C46 1.5(5) . . . . ?
C23 C24 C19 C20 -1.9(4) . . . . ?
C23 C24 C19 P2 174.4(2) . . . . ?
C24 C23 C22 C21 1.1(5) . . . . ?
C24 C19 C20 C21 1.3(4) . . . . ?
C24 C19 P2 Rh1 -110.6(2) . . . . ?
C24 C19 P2 C31 123.9(3) . . . . ?
C24 C19 P2 C25 13.6(3) . . . . ?
C52 O4 C49 C50 -0.1(3) . . . . ?
C52 N2 C53 C59 -167.9(2) . . . . ?
C52 N2 C53 C54 8.2(4) . . . . ?
C52 C51 C50 C49 -1.6(3) . . . . ?
C52 C51 C55 O6 -178.2(3) . . . . ?
C52 C51 C55 C54 4.2(4) . . . . ?
C43 C42 C44 C45 -171.6(3) . . . . ?
C26 C25 C30 C29 1.8(4) . . . . ?
C26 C25 P2 Rh1 66.7(2) . . . . ?
C26 C25 P2 C31 -166.4(2) . . . . ?
C26 C25 P2 C19 -58.7(3) . . . . ?
C26 C27 C28 C29 0.6(5) . . . . ?
C35 C34 C33 C32 0.4(5) . . . . ?
C53 N2 C52 O4 171.3(2) . . . . ?
C53 N2 C52 C51 -8.5(4) . . . . ?
C48 O3 C43 C42 153.5(3) . . . . ?
C48 O3 C43 C39 -23.6(4) . . . . ?
C44 C42 C43 O3 -1.0(4) . . . . ?
C44 C42 C43 C39 176.3(3) . . . . ?
C50 C51 C52 O4 1.6(3) . . . . ?
C50 C51 C52 N2 -178.5(3) . . . . ?
C50 C51 C55 O6 3.4(6) . . . . ?
C50 C51 C55 C54 -174.3(3) . . . . ?
C49 O4 C52 N2 179.1(3) . . . . ?
C49 O4 C52 C51 -1.0(3) . . . . ?
C13 P1 C7 C12 132.3(2) . . . . ?
C13 P1 C7 C8 -44.1(2) . . . . ?
C13 P1 C1 C6 -67.8(2) . . . . ?
C13 P1 C1 C2 116.3(2) . . . . ?
C13 C18 C17 C16 -1.4(5) . . . . ?
C13 C14 C15 C16 -1.0(5) . . . . ?
C5 C6 C1 P1 -176.1(2) . . . . ?
C5 C6 C1 C2 -0.1(4) . . . . ?
C5 C4 C3 C2 -0.1(5) . . . . ?
C18 C13 C14 C15 1.0(4) . . . . ?
C18 C17 C16 C15 1.4(5) . . . . ?
C30 C25 C26 C27 -2.7(4) . . . . ?
C30 C25 P2 Rh1 -106.0(2) . . . . ?
C30 C25 P2 C31 20.9(3) . . . . ?
C30 C25 P2 C19 128.6(2) . . . . ?
C27 C28 C29 C30 -1.5(5) . . . . ?
C57 C58 C59 O5 176.8(3) . . . . ?
C57 C58 C59 C53 0.3(4) . . . . ?
C57 C56 C54 C53 3.4(5) . . . . ?
C57 C56 C54 C55 -175.0(3) . . . . ?
C20 C19 P2 Rh1 65.8(2) . . . . ?
C20 C19 P2 C31 -59.7(2) . . . . ?
C20 C19 P2 C25 -170.0(2) . . . . ?
C20 C21 C22 C23 -1.6(5) . . . . ?
C55 C51 C52 O4 -177.3(2) . . . . ?
C55 C51 C52 N2 2.5(4) . . . . ?
C55 C51 C50 C49 177.0(4) . . . . ?
C47 C41 C42 C43 167.5(3) . . . . ?
C47 C41 C42 C44 -7.8(4) . . . . ?
C47 C46 C45 C44 -2.3(5) . . . . ?
C45 C46 C47 O2 174.6(3) . . . . ?
C45 C46 C47 C41 -1.9(4) . . . . ?
C22 C23 C24 C19 0.7(5) . . . . ?
C22 C21 C20 C19 0.4(5) . . . . ?
C14 C13 C18 C17 0.1(4) . . . . ?
C17 C16 C15 C14 -0.3(5) . . . . ?
C60 O6 C55 C51 0.7(5) . . . . ?
C60 O6 C55 C54 178.4(3) . . . . ?
P2 C31 C36 C35 -177.9(3) . . . . ?
P2 C31 C32 C33 178.7(2) . . . . ?
P2 C25 C26 C27 -175.4(2) . . . . ?
P2 C25 C30 C29 174.6(2) . . . . ?
P2 C19 C20 C21 -175.3(2) . . . . ?
