Information card for entry 7101238

Structure parameters

• Formula: C25 H34 Mn2 N3 O8 P
• Calculated formula: C25 H34 Mn2 N3 O8 P
• SMILES: [Mn]1([Mn]([P]1(N(C(C)C)C(C)C)c1[n+](cn(c1)C(C)(C)C)C(C)(C)C)(C#[O])(C#[O])(C#[O])C#[O])(C#[O])(C#[O])(C#[O])C#[O]
• Title of publication: Reactivity of Electrophilic m-Phosphinidene Complexes with N-Heterocyclic Carbenes: Formation of the First Main Group Element Adducts of 'Abnormal Carbene' Ligands.
• Authors of publication: A. Carty; Todd Graham; Konstantin A. Udachin
• Journal of publication: Chemical Communications
• Year of publication: 2006
• Journal issue: 25
• a: 10.9513 ± 0.0016 Å
• b: 15.968 ± 0.002 Å
• c: 16.925 ± 0.002 Å
• α: 90°
• β: 100.384 ± 0.002°
• γ: 90°
• Cell volume: 2911.1 ± 0.7 ų
• Cell temperature: 125 ± 2 K
• Ambient diffraction temperature: 125 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.035
• Residual factor for significantly intense reflections: 0.0268
• Weighted residual factors for significantly intense reflections: 0.0671
• Weighted residual factors for all reflections included in the refinement: 0.0712
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No