Information card for entry 7101394

Structure parameters

• Formula: H278 N29 Na7 Np6 O315 Sb6 W61.06
• Calculated formula: N29 Na7 Np6 O243.5 Sb6 W61.06
• SMILES: [NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[Na+].[Na+].O1[W]2345O[Np]678(=O)(O[W]9%10%11(O[W]%12%13%14([O]%159[Sb]9[O]%16%17[W]%18%19%20(O[W]%21%22(O5)(O[W]5%23(O4)(O[W]4(O3)(O%21)(O[W]3%21%24([O]%25%26[Sb]%27[O]%28%29[W]%30%31%32(O[Np]%331(=O)(O[W]%25(O%30)(=O)(O%21)O[W]1%26(O[W]%21%29(=O)(O[W]%25%26([O]%29%27[W](O3)(O%25)(O[W]%29(O7)(O%26)(=O)O[W]%28(O8)(=O)(O%21)O%32)(=O)O4)(O1)=O)O%31)(=O)O%24)(O[W]134(O[W]78(O5)(O[W]5%21(O%23)(O[W]%23%24%25(O[W]%26%27%28(O[W]%29(O%33)(=O)(O1)[O]1%28[Sb]([O]37[W](O%27)(O4)(O%24)(O8)=O)[O]5%23[W]3(O[Np]4(O2)(=O)(O[W]1(O%26)(O3)(O%29)=O)(O[W]%16(O[W]%15(O4)(O%10)(O%14)=O)(O%18)(=O)O[W]%17(O[W]12([O]39[W](O6)(=O)(O%11)(O1)O[W]3(O%22)(O%19)(O2)=O)(O%12)=O)(O%13)(O%20)=O)=O)(O%25)(O%21)=O)=O)=O)=O)=O)=O)=O)=O)=O)=O)=O)=O)=O)=O)=O)=O.[Na+].[Na+].O.O.O.O.O
• Title of publication: Oxoneptunium(V) as part of the framework of a polyoxometalate
• Authors of publication: Copping, Roy; Gaunt, Andrew J.; May, Iain; Sharrad, Clint A.; Collison, David; Helliwell, Madeleine; Fox, O. Danny; Jones, Chris J.
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2006
• Journal issue: 36
• Pages of publication: 3788 - 3790
• a: 22.3826 ± 0.0013 Å
• b: 27.3954 ± 0.0016 Å
• c: 30.0087 ± 0.0017 Å
• α: 69.305 ± 0.001°
• β: 80.488 ± 0.001°
• γ: 66.416 ± 0.001°
• Cell volume: 15769.6 ± 1.6 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1582
• Residual factor for significantly intense reflections: 0.0739
• Weighted residual factors for significantly intense reflections: 0.1637
• Weighted residual factors for all reflections included in the refinement: 0.1816
• Goodness-of-fit parameter for all reflections included in the refinement: 0.925
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No