Information card for entry 7102472

Structure parameters

• Common name: W complex
• Formula: C51 H80 Ge O6 Si6 W
• Calculated formula: C51 H80 Ge O6 Si6 W
• SMILES: [Ge]1(c2ccccc2C(O1)=[W](C#[O])(C#[O])(C#[O])(C#[O])C#[O])(c1c(cc(cc1C([Si](C)(C)C)[Si](C)(C)C)C([Si](C)(C)C)[Si](C)(C)C)C([Si](C)(C)C)[Si](C)(C)C)c1c(cccc1C(C)C)C(C)C
• Title of publication: Thermal reactions of an overcrowded germacyclopropabenzene with group 6 metal hexacarbonyl complexes [M(CO)6](M = Cr, Mo, and W): a novel mode of CO insertion leading to the formation of cyclic germoxycarbene metal complexes.
• Authors of publication: Tajima, Tomoyuki; Sasaki, Takayo; Sasamori, Takahiro; Takeda, Nobuhiro; Tokitoh, Norihiro
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2004
• Journal issue: 4
• Pages of publication: 402 - 403
• a: 11.907 ± 0.003 Å
• b: 13.8 ± 0.004 Å
• c: 19.771 ± 0.005 Å
• α: 77.242 ± 0.008°
• β: 71.489 ± 0.007°
• γ: 84.456 ± 0.009°
• Cell volume: 3003.4 ± 1.3 ų
• Cell temperature: 93 ± 2 K
• Ambient diffraction temperature: 93 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0465
• Residual factor for significantly intense reflections: 0.0405
• Weighted residual factors for significantly intense reflections: 0.0858
• Weighted residual factors for all reflections included in the refinement: 0.0884
• Goodness-of-fit parameter for all reflections included in the refinement: 1.075
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No