Information card for entry 7102568

Structure parameters

• Common name: (2,6-dimethylphenylimido)(bis(trimethylphosphine))(chloro) ((2,6-dimethylphenyl)(chloromethylsilyl)amido)molybdenum (IV)
• Chemical name: (2,6-dimethylphenylimido)(bis(trimethylphosphine))(chloro) ((2,6-dimethylphenyl)(chloromethylsilyl)amido)molybdenum (IV)
• Formula: C26 H47 Cl2 Mo N2 P2 Si
• Calculated formula: C26 H47 Cl2 Mo N2 P2 Si
• Title of publication: Unexpected features of stretched Si-H...Mo beta-agostic interactions.
• Authors of publication: Ignatov, Stanislav K; Rees, Nicholas H; Dubberley, Stuart R; Razuvaev, Alexei G; Mountford, Philip; Nikonov, Georgii I
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2004
• Journal issue: 8
• Pages of publication: 952 - 953
• a: 18.403 ± 0.004 Å
• b: 9.92 ± 0.002 Å
• c: 18.548 ± 0.004 Å
• α: 90°
• β: 105.78 ± 0.03°
• γ: 90°
• Cell volume: 3258.4 ± 1.1 ų
• Cell temperature: 180 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1175
• Residual factor for significantly intense reflections: 0.0569
• Weighted residual factors for significantly intense reflections: 0.1174
• Weighted residual factors for all reflections included in the refinement: 0.1327
• Goodness-of-fit parameter for all reflections included in the refinement: 1.041
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No