Information card for entry 7103030

Structure parameters

• Formula: C34 H40 Cl Eu F6 N8 O6 S2
• Calculated formula: C34 H40 Cl Eu F6 N8 O6 S2
• SMILES: [N]123CC[N]45[Eu]6781(Cl)([n]1ccccc1C[N]7(CC3)CC[N]8(Cc1[n]6cccc1)CC5)([n]1ccccc1C4)[n]1ccccc1C2.O=S(=O)([O-])C(F)(F)F.FC(F)(F)S(=O)(=O)[O-]
• Title of publication: Modification of the luminescence spectra of chloro(tetrapyridylcyclotetramine)europium complexes by fine tuning of the Eu-Cl distance with outer-sphere counterions in the solid state, in a polymer matrix and in solution.
• Authors of publication: Wada, Atsushi; Watanabe, Masayuki; Yamanoi, Yoshinori; Nishihara, Hiroshi
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2008
• Journal issue: 14
• Pages of publication: 1671 - 1673
• a: 8.346 ± 0.002 Å
• b: 11.116 ± 0.003 Å
• c: 21.206 ± 0.005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 1967.2 ± 0.8 ų
• Cell temperature: 113 ± 2 K
• Number of distinct elements: 8
• Space group number: 18
• Hermann-Mauguin space group symbol: P 2 21 21
• Hall space group symbol: P 2bc 2
• Residual factor for significantly intense reflections: 0.0547
• Weighted residual factors for all reflections included in the refinement: 0.1361
• Goodness-of-fit parameter for all reflections included in the refinement: 1.106
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No