Information card for entry 7103032

Structure parameters

• Formula: C32 H40 Cl Eu F12 N8 P2
• Calculated formula: C32 H40 Cl Eu F12 N8 P2
• SMILES: c12C[N]34CC[N]56[Eu]7893([n]2cccc1)([n]1ccccc1C[N]8(CC6)CC[N]9(Cc1[n]7cccc1)CC4)([n]1ccccc1C5)Cl.[P](F)(F)(F)(F)(F)[F-].[P](F)(F)(F)(F)(F)[F-]
• Title of publication: Modification of the luminescence spectra of chloro(tetrapyridylcyclotetramine)europium complexes by fine tuning of the Eu-Cl distance with outer-sphere counterions in the solid state, in a polymer matrix and in solution.
• Authors of publication: Wada, Atsushi; Watanabe, Masayuki; Yamanoi, Yoshinori; Nishihara, Hiroshi
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2008
• Journal issue: 14
• Pages of publication: 1671 - 1673
• a: 7.8902 ± 0.0005 Å
• b: 11.1217 ± 0.0007 Å
• c: 20.804 ± 0.002 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 1825.6 ± 0.2 ų
• Cell temperature: 113 ± 2 K
• Number of distinct elements: 7
• Space group number: 18
• Hermann-Mauguin space group symbol: P 2 21 21
• Hall space group symbol: P 2bc 2
• Residual factor for significantly intense reflections: 0.0591
• Weighted residual factors for all reflections included in the refinement: 0.1528
• Goodness-of-fit parameter for all reflections included in the refinement: 1.085
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No